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RESEARCH PAPER · Inorganic Chemistry · 2018

PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units

Yun‐Xiang Ma, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional UnitsOriginalCs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation27Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands9Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization11Nitrate nonlinear optical crystals: A survey on structure-performance relationships146Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency81Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis36Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28Recent progress in selenite and tellurite based SHG materials32Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles146Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57The YMgB 5 O 10 crystal preparation and attractive multi-wavelength emission characteristics of doping Nd 3+ ions34Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)10Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26Growth, Optical, and Spectroscopic Properties of Pure and Nd3+-Doped GdSr3(PO4)3 Crystals with Disordered Structure14Complex coordinated functional groups: A great genes for nonlinear optical materials64Novel layered heterobimetallic fluorides with large optical band gaps3Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40Novel Polarized Crystal BaTeW2O9: Crystal Growth, Characterization, and Wide-Band Polarized Prism15Influence of the coordination metal on the thermal properties of double selenates: Theoretical insights and experimental study2Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence91Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence18From Cs8Sb4Nb5O5F35 to Cs6Sb4Mo3O5F26: The first noncentrosymmetric fluoroantimonite with d0 transition metal30Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20A survey of stereoactive oxysalts for linear and nonlinear optical applications40Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Cadmium Hydroxyl Chloride with Balanced Band Gap and Second-Harmonic-Generation Response2Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5A Review of the Synthesis and Structural Chemistry of Platinum-Group Metal Oxoselenates(IV)0Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0

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  1. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  2. Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation

    Inorganic Chemistry Frontiers · 2019-01-01

    Ya-Ping Gong, Chun‐Li Hu, Yun‐Xiang Ma, Jiang‐Gao Mao, Fang Kong

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  3. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

    Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  4. New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br

    Journal of Solid State Chemistry · 2019-02-27

    Meng Shang, Lili Liu, P. Shiv Halasyamani

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  5. Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands

    Crystal Growth & Design · 2019-05-10

    Belal Ahmed, Hongil Jo, Kang Min Ok

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  6. Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization

    European Journal of Inorganic Chemistry · 2019-06-27

    Belal Ahmed, Hongil Jo, Sung Won Yoon, Kwang‐Yong Choi, Wei‐Tin Chen, F. C. Chou, Kang Min Ok

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  7. Nitrate nonlinear optical crystals: A survey on structure-performance relationships

    Coordination Chemistry Reviews · 2019-09-10

    Xiaomeng Liu, Pifu Gong, Yi Jin Yang, Gaomin Song, Zheshuai Lin

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  8. Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency

    Advanced Science · 2019-09-16

    Xuefei Wang, Fangfang Zhang, Le Gao, Zhihua Yang, Shilie Pan

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  9. Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis

    Science China Materials · 2019-10-22

    Xiaoxue Wang, Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  10. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  11. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

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  12. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

    Dalton Transactions · 2020-01-01

    Huanke Zhao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  13. Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles

    Coordination Chemistry Reviews · 2020-01-10

    Youchao Liu, Yaoguo Shen, Sangen Zhao, Junhua Luo

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  14. Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution

    Chemistry of Materials · 2020-03-16

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  15. BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution

    Inorganic Chemistry · 2020-05-09

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  16. AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses

    Chemistry of Materials · 2020-06-23

    Chao Wu, Xingxing Jiang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  17. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie International Edition · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  18. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  19. The YMgB 5 O 10 crystal preparation and attractive multi-wavelength emission characteristics of doping Nd 3+ ions

    Journal of Materials Chemistry C · 2020-12-23

    Shijia Sun, Qi Wei, Bingxuan Li, Xingjun Shi, Feifei Yuan, Fei Lou, Lizhen Zhang, Zhoubin Lin, Degao Zhong, Yisheng Huang, Bing Teng

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  20. Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)

    Inorganic Chemistry · 2020-12-30

    Lei Geng, Chang‐Yu Meng, Hong‐Yan Lu

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  21. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

    Chemical Communications · 2021-01-01

    Fang Kong, Ting-Kun Jiang, Jiang‐Gao Mao

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  22. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

    Inorganic Chemistry · 2021-04-06

    Yingwei Lu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  23. Growth, Optical, and Spectroscopic Properties of Pure and Nd3+-Doped GdSr3(PO4)3 Crystals with Disordered Structure

    Inorganic Chemistry · 2021-11-30

    Guangda Wu, Linyu Bai, Pingzhang Yu, Mengdi Fan, Li Sun, Yanlu Li, Fapeng Yu, Zhengping Wang, Xian Zhao

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  24. Complex coordinated functional groups: A great genes for nonlinear optical materials

    Chinese Chemical Letters · 2021-12-03

    Weikang Wang, Dajiang Mei, Shaoguo Wen, Jian Wang, Yuandong Wu

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  25. Novel layered heterobimetallic fluorides with large optical band gaps

    Journal of Solid State Chemistry · 2022-02-02

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  26. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  27. Novel Polarized Crystal BaTeW2O9: Crystal Growth, Characterization, and Wide-Band Polarized Prism

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  28. Influence of the coordination metal on the thermal properties of double selenates: Theoretical insights and experimental study

    Journal of Molecular Structure · 2022-10-23

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  29. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

    Angewandte Chemie International Edition · 2022-11-08

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  30. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

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  31. From Cs8Sb4Nb5O5F35 to Cs6Sb4Mo3O5F26: The first noncentrosymmetric fluoroantimonite with d0 transition metal

    Chinese Journal of Structural Chemistry · 2023-01-01

    Jia-Hang Wu, Bo Zhang, Ting-Kun Jiang, Fang Kong, Jiang‐Gao Mao

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  32. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  33. Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 19

    Dalton Transactions · 2023-01-01

    Qiuyuan Feng, Zhixia Gao, Ketian Hou, Jialong Wang, Hong Lei Du, Qun Jing

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  34. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

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  35. Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

    Inorganic Chemistry · 2023-08-02

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  36. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

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  37. Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence

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  38. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

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  39. Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures

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  40. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

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  41. Cadmium Hydroxyl Chloride with Balanced Band Gap and Second-Harmonic-Generation Response

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  42. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

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  43. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

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  44. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

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  45. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

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  46. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

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  47. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-08-15

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  48. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

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  49. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

    Inorganic Chemistry · 2025-09-30

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  50. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

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