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RESEARCH PAPER · Science China Materials · 2019

Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis

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Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesisOriginalSyntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges18α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance15MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)22BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap39Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Structure, Photoluminescence Emissions, and Photocatalytic Activity of Ag2SeO3: A Joint Experimental and Theoretical Investigation23Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity55Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency20Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response5Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Dual-Ligand-Oriented Design of Noncentrosymmetric Complexes with Nonlinear-Optical Activity11A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co 3 (SeO 3 )(SeO 4 )(OH) 2 with kagomé-like Co 2+ ion layer arrangements: the importance of identifying a correct spin lattice4From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties26Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20A survey of stereoactive oxysalts for linear and nonlinear optical applications40Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence6Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation2RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Unprecedented v-shaped [SeO2E] units stabilized in KM[Se2O5]2[SeO2] (M= Al and Ga) constructed by nanoconfinement strategy6Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap18La3ZrGa5O14: Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap1LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides5Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate6Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Heterovalent Coexistence‐Driven Symmetry Breaking and Dimensional Evolution: Designing Polar Heart‐Shaped Channels for Exceptional MFIR Nonlinear Optics5

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  1. Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges

    Science China Materials · 2019-12-20

    Hongping Wu, Shiwei Liu, Shichao Cheng, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  2. α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance

    Science China Materials · 2020-01-20

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  3. MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

    Journal of Solid State Chemistry · 2020-02-29

    Pengfei Li, Fang Kong, Jiang‐Gao Mao

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  4. Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)

    Journal of Solid State Chemistry · 2020-03-02

    Meng Shang, P. Shiv Halasyamani

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  5. BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution

    Inorganic Chemistry · 2020-05-09

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  6. LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap

    Science China Materials · 2020-07-22

    Jin Chen, Chun‐Li Hu, Jiang‐Gao Mao

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  7. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  8. Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response

    Chemistry of Materials · 2020-11-04

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  9. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  10. Structure, Photoluminescence Emissions, and Photocatalytic Activity of Ag2SeO3: A Joint Experimental and Theoretical Investigation

    Inorganic Chemistry · 2021-03-26

    Ivo Mateus Pinatti, Aline B. Trench, Ana C. M. Tello, Paula F. S. Pereira, Josiane Carneiro Souza, Marcio Daldin Teodoro, Ieda L. V. Rosa, Juán Andrés, E. Longo, Alexandre Zirpoli Simoes

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  11. Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity

    Inorganic Chemistry · 2021-07-21

    Qi Wei, Kui Wang, Chao He, Li Wei, Xiaofei Li, Shuo Zhang, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  12. Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency

    Science China Materials · 2021-11-10

    Jiahao Jiao, Abudukadi Tudi, Min Zhang, Wenbing Cai, Junjie Li, Zhihua Yang, Shilie Pan

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  13. Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response

    Crystal Growth & Design · 2021-12-21

    Shanyue Wei, Mingxue Yang, Tao Zuo, Lingyi Meng, Jing Chen, Ting Hu, Can‐Zhong Lu, Yiming Xie

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  14. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

    Materials Chemistry Frontiers · 2022-01-01

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  15. Dual-Ligand-Oriented Design of Noncentrosymmetric Complexes with Nonlinear-Optical Activity

    Inorganic Chemistry · 2022-09-30

    Jinhua Li, Xiao‐Fan Jiang, Qi Wei, Zhen‐Zhen Xue, Guo‐Ming Wang, Guo‐Yu Yang

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  16. A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co 3 (SeO 3 )(SeO 4 )(OH) 2 with kagomé-like Co 2+ ion layer arrangements: the importance of identifying a correct spin lattice

    Dalton Transactions · 2023-01-01

    Alisher F. Murtazoev, Peter S. Berdonosov, Konstantin Alexandrovich Lyssenko, В. А. Долгих, Michael Y. Geidorf, О. С. Волкова, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Alexander N. Vasiliev

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  17. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  18. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  19. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  20. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

    Inorganic Chemistry · 2024-02-16

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao, Fang Kong

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  21. MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence

    Journal of Solid State Chemistry · 2024-05-12

    Yueling Sun, Lei Huai, An-Hua Gong

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  22. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  23. First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation

    Solid State Sciences · 2024-09-20

    Alisher F. Murtazoev, Konstantin Alexandrovich Lyssenko, Alexey N. Kuznetsov∥, В. А. Долгих, Peter S. Berdonosov

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  24. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

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    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  25. From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions

    Chinese Chemical Letters · 2024-11-03

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  26. Unprecedented v-shaped [SeO2E] units stabilized in KM[Se2O5]2[SeO2] (M= Al and Ga) constructed by nanoconfinement strategy

    The Innovation Materials · 2025-01-01

    Yi Zheng, Qian Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  27. Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence

    Inorganic Chemistry · 2025-01-27

    Jiang Wu, Jiahao Jiao, Mayinuer Maimaiti, Ke Li, Jugong Zheng, Min Zhang

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  28. La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap

    Angewandte Chemie International Edition · 2025-03-11

    Dazhi Lu, Yuzhou Wang, Xiaoheng Li, Fei Liang, Kui Wu, Haohai Yu, Huaijin Zhang

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  29. La3ZrGa5O14: Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap

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    Dazhi Lu, Yuzhou Wang, Xiaoheng Li, Fei Liang, Kui Wu, Haohai Yu, Huaijin Zhang

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  30. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  31. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  32. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

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  33. The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides

    Science China Chemistry · 2026-01-04

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  34. Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate

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  35. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

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  36. Heterovalent Coexistence‐Driven Symmetry Breaking and Dimensional Evolution: Designing Polar Heart‐Shaped Channels for Exceptional MFIR Nonlinear Optics

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