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RESEARCH PAPER · Chinese Journal of Structural Chemistry · 2023

From Cs8Sb4Nb5O5F35 to Cs6Sb4Mo3O5F26: The first noncentrosymmetric fluoroantimonite with d0 transition metal

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From Cs8Sb4Nb5O5F35 to Cs6Sb4Mo3O5F26: The first noncentrosymmetric fluoroantimonite with d0 transition metalOriginalFrom CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap21A survey of stereoactive oxysalts for linear and nonlinear optical applications40Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size83Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect30[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect601D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials9[C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence17HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1(C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group13Stabilization of the Polar 0D Cs4Nb2–xTaxS11 with Phase-Matched Second-Harmonic Generation and High Laser-Induced Damage Threshold4Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization6Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges6Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate6V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides2Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF60Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit6Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection6Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Ferroic Phase Transition‐Triggered Large Anisotropic Actuation in 1D Chiral Hybrid Metal Halides0

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  1. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

    Inorganic Chemistry Frontiers · 2023-01-01

    Pengfei Li, Chun‐Li Hu, Bing-Xuan Li, Jiang‐Gao Mao, Fang Kong

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  2. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  3. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  4. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

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  5. AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2023-05-24

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  6. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  7. Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size

    Journal of the American Chemical Society · 2023-10-26

    Jia-Hang Wu, Chun‐Li Hu, Ting-Kun Jiang, Jiang‐Gao Mao, Fang Kong

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  8. Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect

    Small · 2023-12-05

    Ru‐Ling Tang, Wei Xu, Xin Lian, Yue‐Qi Wei, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  9. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  10. 1D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence

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  11. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  12. Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)

    Inorganic Chemistry Frontiers · 2024-01-01

    Jin Chen, Huai-Yu Wu, Miao‐Bin Xu, Mingchang Wang, Qianqian Chen, Bingxuan Li, Chun‐Li Hu, Ke‐Zhao Du

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  13. Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials

    Chemical Communications · 2024-01-01

    Xin Deng, Lin Zhou, Xin Yan, Yanjuan Wang, Wen-Li Yang, Hui‐Peng Lv, Yuan‐Yuan Tang

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  14. [C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence

    Inorganic Chemistry · 2024-02-13

    Meng-Han Lv, Shu‐Fang Li, Meng-Meng Ren, Jiaxin Wang, Ru‐Ling Tang, Jin Chen, Hongbo Huang, Bingbing Zhang, Dong Yan

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  15. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  16. (C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group

    Inorganic Chemistry · 2024-05-31

    Meng-Han Lv, Shu‐Fang Li, Jing Wang, Jiaxin Wang, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Dong Yan

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  17. Stabilization of the Polar 0D Cs4Nb2–xTaxS11 with Phase-Matched Second-Harmonic Generation and High Laser-Induced Damage Threshold

    Chemistry of Materials · 2025-06-24

    Thomas S. Ie, Sihyung Kang, Jinseong Kim, Abishek K. Iyer, Michael J. Waters, James M. Rondinelli, Joon Ik Jang, Mercouri G. Kanatzidis

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  18. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

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  19. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

    European Journal of Inorganic Chemistry · 2025-08-26

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  20. From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization

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    Shiyi Wang, Yingzi Zhang, Yu Yan, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  21. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

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  22. Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges

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  23. Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate

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  24. V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides

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  26. Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF6

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  28. Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection

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  29. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

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  30. Ferroic Phase Transition‐Triggered Large Anisotropic Actuation in 1D Chiral Hybrid Metal Halides

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