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RESEARCH PAPER · Inorganic Chemistry · 2023

Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

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Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical MaterialsOriginal[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups13Stereochemically Active Lone Pair Leads to Birefringence in the Vacancy Ordered Cs3Sb2Cl9 Perovskite Single Crystals13Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7A novel sodium manganese fluorooxalate crystal Na2Mn2(C2O4)2.5F·2H2O: Synthesis, structure, optical and thermal properties2Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O3Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System7Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials150Enhanced second harmonic generation in a Fdd 2 polymorph of C 12 H 8 N 2 O 4 Zn for UV nonlinear optical applications1Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties11SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence51Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals5Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy1Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  2. From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Cheng Chen, Danyang Dou, Yunjie Bai, Bingbing Zhang, Ying Wang

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  3. Stereochemically Active Lone Pair Leads to Birefringence in the Vacancy Ordered Cs3Sb2Cl9 Perovskite Single Crystals

    The Journal of Physical Chemistry Letters · 2024-03-11

    Shramana Guha, Amit Dalui, Piyush Kanti Sarkar, Sima Roy, Atanu Paul, Sujit Kamilya, Abhishake Mondal, Indra Dasgupta, D. D. Sarma, Somobrata Acharya

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  4. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  5. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  6. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  7. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

    Inorganic Chemistry · 2024-07-11

    Dan Wang, Han Luo, Tingyu Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  8. A novel sodium manganese fluorooxalate crystal Na2Mn2(C2O4)2.5F·2H2O: Synthesis, structure, optical and thermal properties

    Journal of Solid State Chemistry · 2024-09-27

    Sen Ji, Lei Kang, Yanyang Han, Shanshan Liu, Ye Liu, Ye Liu, Xin Yang, Kai Feng

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  9. Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O

    Journal of Solid State Chemistry · 2024-11-01

    Sen Ji, Bo Xiao, Yanyang Han, Shanshan Liu, Ye Liu, Ye Liu, Xin Yang, Kai Feng

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  10. Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System

    Inorganic Chemistry · 2024-11-12

    Qingwen Zhu, Yong Tao, Can Yang, Jie Gou, Yaolong Zhu, Xuefei Wang, Qi Wu

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  11. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

    Accounts of Chemical Research · 2024-12-12

    Xuehua Dong, Ling Huang, Guohong Zou

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  12. Enhanced second harmonic generation in a Fdd 2 polymorph of C 12 H 8 N 2 O 4 Zn for UV nonlinear optical applications

    Dalton Transactions · 2025-01-01

    Jie Gou, Can Yang, YunJie Wang, Yaolong Zhu, Qingwen Zhu, Xin Su, Qi Wu

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  13. Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain

    Inorganic Chemistry Frontiers · 2025-01-01

    Xiande Peng, Xiangyuan Li, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  14. Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties

    Chemistry of Materials · 2025-01-20

    Yunseung Kuk, Zhiyong Bai, Yang Li, Kang Min Ok

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  15. SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-23

    Xinyue Shi, Xueqing Liu, Chunxiao Nie, Yangkai Zhang, Degao Zhong, Bing Teng, Zhoubin Lin, Yisheng Huang, Shijia Sun

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  16. Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals

    Inorganic Chemistry · 2025-08-05

    Tingyu Wang, Dan Wang, Bailiang Li, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  17. Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy

    Science China Chemistry · 2025-08-08

    Yan-Zhen Xie, Hua Huang, Qingran Ding, Jian Lei, Yu-Ling Wang, Qing‐Yan Liu

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  18. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

    European Journal of Inorganic Chemistry · 2025-08-26

    Xuehua Dong, Ling Huang, Guohong Zou

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  19. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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