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RESEARCH PAPER · Dalton Transactions · 2016

Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]

Sheng‐Ping Guo, Yang Chi, Bin‐Wen Liu, Guo‐Cong Guo

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Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]OriginalRecent achievements on middle and far-infrared second-order nonlinear optical materials433A series of pentanary inorganic supramolecular sulfides (A 3 X)[MB 12 (MS 4 ) 3 ] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B 12 S 12 clusters54Band gap tuning from an indirect EuGa 2 S 4 to a direct EuZnGeS 4 semiconductor: syntheses, crystal and electronic structures, and optical properties20Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Crystal Chemistry and Photocatalytic Properties of RE 4 S 4 Te 3 (RE = Gd, Ho, Er, Tm): Experimental and Theoretical Investigations29SnI 4 ⋅(S 8 ) 2 : A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal184SnI4⋅(S8)2: A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal45Second-order nonlinear optical crystals with mixed anions250Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations4Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses25Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A new type of novel salt-inclusion chalcogenide with ultralow thermal conductivity14Salt-inclusion chalcogenides: an emerging class of IR nonlinear optical materials54Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit75KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19“Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth36Salt-Inclusion Chalcogenide [Ba4Cl2][ZnGa4S10]: Rational Design of an IR Nonlinear Optical Material with Superior Comprehensive Performance Derived from AgGaS2134Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect25Sn4−δB12Se12[Qx], Q = Se, Te, a B12 Cluster Tunnel Framework Hosting Neutral Chalcogen Chains8Superior Infrared Nonlinear Optical Performance Achieved by Synergetic Functional Motif and Vacancy Site Modulations48KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring10KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units9Optimizing the Nonlinear Optical Performance of an A-N-M-Q (A: Alkali Metal; N: d10 Metal; M: Main Group Metal; Q: Chalcogen) System44A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28Molecular boron clusters2Trade-Off for Better Balanced Nonlinear Optical Performance with Disordered Si in ZnGeP217Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation12Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials12[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46Exploring the Optoelectronic Potential of M2SnX3F2 (M = Sr, Ba; X = S, Se) Compounds Through First-Principles Analysis of Structural, Electronic, and Optical Properties15A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs18Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material2Diamond-Like HgIn2Q4 (Q = Se, Te) Synthesized by Flux-Assisted Boron-Chalcogen Method Exhibit Noteworthy Nonlinear Optical Properties Contributed by Three Types of Tetrahedral Motifs8Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates7Alkali Metal Substitution-Induced Structural Transformation for RbREP2Se6 (RE = Gd, Tb, Dy) with Second-Harmonic Generation Responses6Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5Birefringence and Photocurrent Response of A Series of Rare-Earth Selenophosphates Cs4RE2(PSe4)2(P2Se6) (RE = La–Nd, Sm, Gd, Tb) Synthesized by the Metal Oxide–Boron–Chalcogen (MOBQ) Method0Eu5ZnGa6S15, Eu5Zn3Ga2Sn2S15, and Pb5HgGa6S15: Crystal Chemistry and Nonlinear Optical Properties0

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  1. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  2. A series of pentanary inorganic supramolecular sulfides (A 3 X)[MB 12 (MS 4 ) 3 ] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B 12 S 12 clusters

    Inorganic Chemistry Frontiers · 2017-01-01

    Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  3. Band gap tuning from an indirect EuGa 2 S 4 to a direct EuZnGeS 4 semiconductor: syntheses, crystal and electronic structures, and optical properties

    RSC Advances · 2017-01-01

    Yang Chi, Sheng‐Ping Guo, Huaiguo Xue

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  4. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

    Pengfei Liu, Yanyan Li, Yujun Zheng, Ju‐Song Yu, Ruihuan Duan, Hong Chen, Hua Lin, Ling Chen, Li‐Ming Wu

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  5. Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties

    Dalton Transactions · 2018-01-01

    Fangfang He, Lei Wang, Cuifang Hu, Jing Wen Zhou, Qian Li, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  6. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

    Dalton Transactions · 2018-01-01

    Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  7. Crystal Chemistry and Photocatalytic Properties of RE 4 S 4 Te 3 (RE = Gd, Ho, Er, Tm): Experimental and Theoretical Investigations

    Inorganic Chemistry · 2018-04-25

    Yang Chi, Liang-Zhen Rong, Nian‐Tzu Suen, Huaiguo Xue, Sheng‐Ping Guo

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  8. SnI 4 ⋅(S 8 ) 2 : A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2018-05-06

    Sheng‐Ping Guo, Yang Chi, Huaiguo Xue

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  9. SnI4⋅(S8)2: A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal

    Angewandte Chemie · 2018-05-07

    Sheng‐Ping Guo, Yang Chi, Huaiguo Xue

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  10. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  11. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2018-08-23

    Sheng‐Ping Guo, Zongdong Sun, Yang Chi, Huaiguo Xue

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  12. Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations

    Solid State Sciences · 2018-09-07

    Zongdong Sun, Yang Chi, Sheng‐Ping Guo

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  13. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

    Fangfang He, Qian Wang, Cuifang Hu, Wen Jun He, Xueying Luo, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  14. Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses

    Inorganic Chemistry · 2019-03-01

    Yang Chi, Tengfei Jiang, Huaiguo Xue, Sheng‐Ping Guo

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  15. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2019-06-07

    Yanyan Li, Wenjing Wang, Hui Wang, Hua Lin, Li‐Ming Wu

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  16. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  17. A new type of novel salt-inclusion chalcogenide with ultralow thermal conductivity

    Chemical Communications · 2020-01-01

    Hong Chen, Pengfei Liu, Hua Lin, Xin‐Tao Wu

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  18. Salt-inclusion chalcogenides: an emerging class of IR nonlinear optical materials

    Dalton Transactions · 2020-01-01

    Qing-Gang Yue, Wenbo Wei, Hong Chen, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  19. Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit

    ACS Applied Materials & Interfaces · 2020-03-30

    Yang Chi, Zongdong Sun, Qian-Ting Xu, Huaiguo Xue, Sheng‐Ping Guo

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  20. KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units

    Inorganic Chemistry · 2020-04-21

    Xiaohui Li, Yiting Chen, Huaiguo Xue, Sheng‐Ping Guo

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  21. “Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth

    Frontiers in Chemistry · 2020-06-26

    Vladislav V. Klepov, Christian A. Juillerat, Kristen A. Pace, Gregory W. Morrison, Hans‐Conrad zur Loye

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  22. Salt-Inclusion Chalcogenide [Ba4Cl2][ZnGa4S10]: Rational Design of an IR Nonlinear Optical Material with Superior Comprehensive Performance Derived from AgGaS2

    Chemistry of Materials · 2020-08-14

    Hong Chen, Yanyan Li, Bingxuan Li, Pengfei Liu, Hua Lin, Qi‐Long Zhu, Xintao Wu

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  23. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

    Mei Yan, Huaiguo Xue, Sheng‐Ping Guo

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  24. A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect

    Inorganic Chemistry · 2021-02-09

    Shanshan Han, Wen‐Dong Yao, Su‐Xin Yu, Yueling Sun, Anhua Gong, Sheng‐Ping Guo

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  25. Sn4−δB12Se12[Qx], Q = Se, Te, a B12 Cluster Tunnel Framework Hosting Neutral Chalcogen Chains

    Chemistry of Materials · 2021-02-25

    Daniel G. Chica, Ioannis Spanopoulos, Shiqiang Hao, Chris M. Wolverton, Mercouri G. Kanatzidis

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  26. Superior Infrared Nonlinear Optical Performance Achieved by Synergetic Functional Motif and Vacancy Site Modulations

    Chemistry of Materials · 2021-11-03

    Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Ya-Qian Zou, Wen‐Fa Chen, Qiu-Nan Yan, Guo‐Cong Guo

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  27. KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring

    Dalton Transactions · 2022-01-01

    Shanshan Han, Qian-Ting Xu, Wenlong Liu, Sheng‐Ping Guo

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  28. KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units

    Inorganic Chemistry Frontiers · 2022-01-01

    Shanshan Han, Su‐Xin Yu, Wenlong Liu, Sheng‐Ping Guo

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  29. Optimizing the Nonlinear Optical Performance of an A-N-M-Q (A: Alkali Metal; N: d10 Metal; M: Main Group Metal; Q: Chalcogen) System

    ACS Applied Materials & Interfaces · 2022-01-13

    Long‐Qi Yang, Xiao‐Ming Jiang, Shao‐Min Pei, Wen‐Fa Chen, Bin‐Wen Liu, Guo‐Cong Guo

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  30. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  31. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

    European Journal of Inorganic Chemistry · 2022-10-05

    Jun Li, Shanshan Han, Sheng‐Ping Guo

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  32. Molecular boron clusters

    Elsevier eBooks · 2022-10-12

    Igor B. Sivaev

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  33. Trade-Off for Better Balanced Nonlinear Optical Performance with Disordered Si in ZnGeP2

    Chemistry of Materials · 2022-12-07

    Shunda Yang, Chensheng Lin, Kaichuang Chen, Huixin Fan, Jindong Chen, Shenghao Fang, Ning Ye, Min Luo

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  34. Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation

    Chemistry of Materials · 2023-01-23

    Anna A. Berseneva, Lakshani W. Masachchi, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  35. Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-07

    Chao-Hong Xie, Bin‐Wen Liu, Guo‐Cong Guo

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  36. [K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

    Advanced Science · 2023-02-27

    Wen‐Fa Chen, Bin‐Wen Liu, Shao‐Min Pei, Xiao‐Ming Jiang, Guo‐Cong Guo

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  37. Exploring the Optoelectronic Potential of M2SnX3F2 (M = Sr, Ba; X = S, Se) Compounds Through First-Principles Analysis of Structural, Electronic, and Optical Properties

    Chemistry Africa · 2023-08-10

    Youssef Ben Smida, Basma Marzougui, Mohamed Driss, Damian Chinedu Onwudiwe, Yarub Al-Douri

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  38. A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties

    Journal of Solid State Chemistry · 2023-08-18

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  39. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

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  40. Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs

    Chemistry of Materials · 2024-04-24

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  41. Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material

    Dalton Transactions · 2024-12-09

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  42. Diamond-Like HgIn2Q4 (Q = Se, Te) Synthesized by Flux-Assisted Boron-Chalcogen Method Exhibit Noteworthy Nonlinear Optical Properties Contributed by Three Types of Tetrahedral Motifs

    Inorganic Chemistry · 2025-06-24

    Jian Ping Cheng, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  43. Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates

    Inorganic Chemistry · 2025-07-18

    Zi-Nan Chen, Hai-Ping Xu, Wen‐Dong Yao, Mingyang Li, Chen‐Yi Zhao, Wenlong Liu, Sheng‐Ping Guo

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  44. Alkali Metal Substitution-Induced Structural Transformation for RbREP2Se6 (RE = Gd, Tb, Dy) with Second-Harmonic Generation Responses

    Inorganic Chemistry · 2025-08-08

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  45. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

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  46. Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

    Inorganic Chemistry Frontiers · 2025-11-05

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  47. Birefringence and Photocurrent Response of A Series of Rare-Earth Selenophosphates Cs4RE2(PSe4)2(P2Se6) (RE = La–Nd, Sm, Gd, Tb) Synthesized by the Metal Oxide–Boron–Chalcogen (MOBQ) Method

    Inorganic Chemistry · 2026-08-10

    Si Yang, Zong-Ze Li, Ning Wang, Xin Lei Zhao, Sheng‐Ping Guo

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  48. Eu5ZnGa6S15, Eu5Zn3Ga2Sn2S15, and Pb5HgGa6S15: Crystal Chemistry and Nonlinear Optical Properties

    Inorganic Chemistry · 2026-08-12

    Xu‐Bin Ni, Qiu-Yang Du, Wen‐Dong Yao, Si Yang, Wen-Rui Zhou, Wenfeng Zhou, Ru‐Ling Tang, Sheng‐Ping Guo

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