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RESEARCH PAPER · Inorganic Chemistry · 2018

Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

Sheng‐Ping Guo, Zongdong Sun, Yang Chi, Huaiguo Xue

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Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage ThresholdOriginalSecond-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations4Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties24Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses25Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Recent Advances in Iridium-Catalysed Transfer Hydrogenation Reactions6KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt392D Inorganic Bimolecular Crystals with Strong In‐Plane Anisotropy for Second‐Order Nonlinear Optics57Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides114Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold42Investigation of the second-order nonlinear optical property of Sr6Sb6S173Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold17CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties8Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response5Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties146Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra12Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization6The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor24Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material27Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response44Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28Recent Advances in Infrared Nonlinear Optical Crystal7AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response4Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts39Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts1SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation5Recent Advances in Growth, Properties and Applications of 2D Inorganic Molecular Crystals†8Adduct‐Type Compounds for Nonlinear Optical Crystals0Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)26Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances157[C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence18Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13Intermolecular Metal-Involving Pnictogen Bonding: The Case of σ-(Sb III )-Hole···d z 2 [Pt II ] Interaction22Quantifying Structural Polarization by Continuous Regulation of Lone-Pair Electron Expression in Molecular Crystals52Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 94Enhanced Second‐Harmonic Generation in Quadratically Nonlinear Weyl Semimetal NbAs for Broadband Photodetection Applications10Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy16Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy8Ternary resistive switching memory of copper–organic complex/iodocuprate/sulfur hybrid enabled by π–π interactions and S 8 relaxation6Lone Pair Electron Manipulation: A Promising Avenue for Tuning Properties in Functional Materials3Cd 7 I 12 Q·As 4 Q n (Q = S, Se; n = 3, 4): In Situ Alteration of Functional Molecules in Polar Metal Inorganic Framework Tailoring High‐Performance Infrared Nonlinear Optical Crystals9Research progress and future prospect of chalcogenides with large optical anisotropy46Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)2Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29As 2 O 3 as an inorganic molecular crystal: a DFT study for nanoelectronics0Coexistence of magnetism and ferroelectricity in the 2D inorganic molecular crystal SbI3•(S7N)30[Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution0Unlocking Structural Anisotropy by Guest-Symmetry Modulation Strategy to Achieve Giant Birefringence in Molecular Crystals0

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  1. Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations

    Solid State Sciences · 2018-09-07

    Zongdong Sun, Yang Chi, Sheng‐Ping Guo

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  2. Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination

    Journal of Solid State Chemistry · 2018-09-25

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  3. Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties

    Inorganic Chemistry · 2019-02-13

    Qi Wei, Chao He, Bang‐Di Ge, Meng-Xin Wan, Li Wei, Guo‐Ming Wang

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  4. Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses

    Inorganic Chemistry · 2019-03-01

    Yang Chi, Tengfei Jiang, Huaiguo Xue, Sheng‐Ping Guo

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  5. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  6. KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active

    Crystal Growth & Design · 2019-06-06

    Zeng-Hao Yue, Zhen‐Tao Lu, Huaiguo Xue, Sheng‐Ping Guo

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  7. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2019-06-07

    Yanyan Li, Wenjing Wang, Hui Wang, Hua Lin, Li‐Ming Wu

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  8. Recent Advances in Iridium-Catalysed Transfer Hydrogenation Reactions

    Topics in organometallic chemistry · 2020-01-01

    M.P. Lamata, Vincenzo Passarelli, Daniel Carmona

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  9. KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units

    Inorganic Chemistry · 2020-04-21

    Xiaohui Li, Yi-Ting Chen, Huaiguo Xue, Sheng‐Ping Guo

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  10. Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se20

    Journal of Solid State Chemistry · 2020-05-08

    Sihan Yang, Xiaohui Li, Wen‐Dong Yao, Qian-Ting Xu, Sheng‐Ping Guo

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  11. Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt

    Inorganic Chemistry · 2020-05-29

    Zhen‐Tao Lu, Wenjing Fan, Zhiqian Wang, Ning Gu, Zeng-Hao Yue, Huaiguo Xue, Sheng‐Ping Guo

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  12. 2D Inorganic Bimolecular Crystals with Strong In‐Plane Anisotropy for Second‐Order Nonlinear Optics

    Advanced Materials · 2020-06-26

    Xinliang Feng, Zongdong Sun, Ke Pei, Wei Han, Fakun Wang, Peng Luo, Jianwei Su, Nian Zuo, Guiheng Liu, Huiqiao Li, Tianyou Zhai

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  13. Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides

    Coordination Chemistry Reviews · 2020-07-13

    Le Gao, Junben Huang, Siru Guo, Zhihua Yang, Shilie Pan

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  14. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  15. KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2020-12-15

    Xin Lian, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  16. Investigation of the second-order nonlinear optical property of Sr6Sb6S17

    Journal of Solid State Chemistry · 2020-12-19

    Qian-Ting Xu, Wen‐Dong Yao, Xiaohui Li, Sheng‐Ping Guo

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  17. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

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  18. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

    Journal of Materials Chemistry C · 2021-01-01

    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  19. Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold

    Journal of Alloys and Compounds · 2021-11-13

    Wenfeng Zhou, Zhi‐Hui Shi, Wenlong Liu, Sheng‐Ping Guo

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  20. CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 4

    Inorganic Chemistry Frontiers · 2021-12-01

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  21. Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties

    Inorganic Chemistry · 2021-12-02

    Qi Wu, Can Yang, Jie Ma, Xian Liu, Yanjun Li

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  22. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

    Inorganic Chemistry · 2021-12-15

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  23. Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response

    Crystal Growth & Design · 2021-12-21

    Shanyue Wei, Mingxue Yang, Tao Zuo, Lingyi Meng, Jing Chen, Ting Hu, Can‐Zhong Lu, Yiming Xie

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  24. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie · 2021-12-24

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  25. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

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  26. Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra

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  27. Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization

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  28. The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor

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  29. Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material

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  30. Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response

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  31. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

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  32. Recent Advances in Infrared Nonlinear Optical Crystal

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  33. AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response

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  34. Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts

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  35. Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts

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  36. SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

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  37. Recent Advances in Growth, Properties and Applications of 2D Inorganic Molecular Crystals†

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  38. Adduct‐Type Compounds for Nonlinear Optical Crystals

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  39. Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)

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  40. Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances

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  41. [C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence

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  42. Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties

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  43. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units

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  44. Intermolecular Metal-Involving Pnictogen Bonding: The Case of σ-(Sb III )-Hole···d z 2 [Pt II ] Interaction

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  45. Quantifying Structural Polarization by Continuous Regulation of Lone-Pair Electron Expression in Molecular Crystals

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  46. Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 9

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  47. Enhanced Second‐Harmonic Generation in Quadratically Nonlinear Weyl Semimetal NbAs for Broadband Photodetection Applications

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  48. Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy

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  49. Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy

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  50. Ternary resistive switching memory of copper–organic complex/iodocuprate/sulfur hybrid enabled by π–π interactions and S 8 relaxation

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