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RESEARCH PAPER · Chemistry of Materials · 2024

Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs

Yan Guo, Wen‐Fa Chen, Mingxin Li, Fan Wu, Qiu-Pei Qin, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic MotifsOriginalLanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1Chalcophosphates: A plentiful source of infrared nonlinear optical materials42Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations4Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations29P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions6Halogen-Driven Structural Engineering in Tellurium Oxyhalides: Enhanced SHG Response and Broad Optical Transparency6Ba 10 Zn 7 Ga 6 S 26 : Promising Infrared Nonlinear Optical Crystal Exhibiting a High Laser Damage Threshold0Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation6Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation3高性能硫属化物红外非线性光学材料构效关系（特邀）0Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates4Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates0Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS60Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides7Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0[La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window0

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  1. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  2. Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-01-04

    Meihui Chen, Wei Wei, Jiawei Zhao, Juanjuan Lu, Donghai An, Yanna Chen

    Read original paper ↗ ·

  3. Chalcophosphates: A plentiful source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2025-02-26

    Yingying Kong, Guansong Zheng, Yi Du, Junjie Li, Shilie Pan

    Read original paper ↗ ·

  4. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie · 2025-03-18

    Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  5. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie International Edition · 2025-03-18

    Shao‐Min Pei, Xiaoming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  6. P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions

    Advanced Optical Materials · 2025-04-11

    Wei Wu, Yi‐Bing Huang, Si‐Fan Lu, Jia Gao, Yan Guo, Wei‐Qi Huang, Meng‐Na Jing, Xiao‐Ming Jiang, Guo‐Cong Guo

    Read original paper ↗ ·

  7. Halogen-Driven Structural Engineering in Tellurium Oxyhalides: Enhanced SHG Response and Broad Optical Transparency

    Inorganic Chemistry · 2025-04-21

    Gen Li, Wei Zeng, Gangji Yi, Xuan Zou, Xize Zhan, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  8. Ba 10 Zn 7 Ga 6 S 26 : Promising Infrared Nonlinear Optical Crystal Exhibiting a High Laser Damage Threshold

    Zeitschrift für anorganische und allgemeine Chemie · 2025-09-04

    Li‐Wen Fan, Rui‐Xi Wang, Mengyue Li, Ling Chen, Li‐Ming Wu

    Read original paper ↗ ·

  9. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

    Read original paper ↗ ·

  10. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

    Read original paper ↗ ·

  11. 高性能硫属化物红外非线性光学材料构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    张成龙 Zhang Chenglong, 王硕 Wang Shuo, Ailijiang Abudurusuli, 黄君本 Huang Junben

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  12. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

    Angewandte Chemie International Edition · 2026-02-17

    Jin Li, Deshuai Xiao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Ning Ye

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  13. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

    Angewandte Chemie · 2026-02-17

    Jin Li, Deshuai Xiao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Ning Ye

    Read original paper ↗ ·

  14. Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS6

    Journal of Solid State Chemistry · 2026-04-02

    Ya Yang, Yan Xiao, Ying Zhang, Weiping Guo, Ziwei Li, Bingbing Zhang, Guoqiang Wang, Naifeng Zhuang, Zhong‐Zhen Luo, Zhigang Zou

    Read original paper ↗ ·

  15. Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides

    Journal of the American Chemical Society · 2026-06-08

    Shao‐Min Pei, Jun-Long Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  16. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

    Angewandte Chemie · 2026-08-26

    Qichao Zhao, Bingxuan Li, Guang Peng, Ning Ye, Jindong Chen

    Read original paper ↗ ·

  17. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

    Angewandte Chemie International Edition · 2026-08-26

    Qichao Zhao, Bingxuan Li, Guang Peng, Ning Ye, Jindong Chen

    Read original paper ↗ ·

  18. [La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window

    Crystal Growth & Design · 2026-10-10

    Cuier Deng, Yuhan Hu, Ruixi Wang, Jingyu Guo

    Read original paper ↗ ·
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