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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2025

Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

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Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gapsOriginalREV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer0Layered RbLnGeS4 (ln = Ce, Pr, Nd, Sm, Gd): crystal structures, Rb-site disorder–order transition, and structure–property correlations0Research advances in rare-earth nonlinear optical crystalline materials in 20250

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  1. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  2. Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies

    Inorganic Chemistry · 2026-06-30

    Gopabandhu Panigrahi, Rachita Panigrahi, P. S. S. Dabare, Hope Eden Catalano, Hans‐Conrad zur Loye

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  3. A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer

    Inorganic Chemistry · 2026-07-01

    Zi-Nan Chen, Zong-Ze Li, Ning Wang, Jian Cheng, Zhen‐Cheng Wu, Feng Qiu, Mao‐Yin Ran, Sheng‐Ping Guo

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  4. Layered RbLnGeS4 (ln = Ce, Pr, Nd, Sm, Gd): crystal structures, Rb-site disorder–order transition, and structure–property correlations

    Journal of Solid State Chemistry · 2026-07-20

    Alexander A. Sapov, М.С. Тарасенко, Natalia V. Kuratieva, Mikhail M. Syrokvashin, Alexey A. Ryadun, Dmitry Yu. Troitskii, Irina V. Yushina, Н.Г. Наумов

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  5. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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