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RESEARCH PAPER · Inorganic Chemistry · 2021

A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect

Shanshan Han, Wen‐Dong Yao, Su‐Xin Yu, Yueling Sun, Anhua Gong, Sheng‐Ping Guo

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A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling EffectOriginalIonothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation4KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring10KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units9A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9Molecular boron clusters2AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds19[Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters21Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation12Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials12Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs22Halide-Induced Band Gap Enhancement from Ba2SnSe4 to KBa2SnSe4Cl2A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations25Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70KREP 2 S 6 (RE = Sm, Gd, Tb, Dy): A Series of Polar Rare-Earth Thiophosphates with High Laser-Induced Damage Thresholds and Moderate Nonlinear-Optical Responses Synergistically Contributed by Isolated P 2 S 6 Units and {[RE 2 S 15 ] 24– } ∞ Layers8Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs18Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material2Non-centrosymmetric structures designed rationally via a “dimensionality addition” strategy toward the promising nonlinear optical family [A–X][In–Se] (A = K/Ba and Rb/Ba; X = Cl and Br)13From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance19Research progress and future prospect of chalcogenides with large optical anisotropy46From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide5Transition‐Metal Azo Schiff Base Complexes: Nonlinear Optics Across Solutions, Thin Films and Nanocomposites9

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  1. Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation

    Journal of Cluster Science · 2021-04-29

    Gang Yang, Chao Wu, Jinfang Zhang, Chi Zhang

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  2. KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※

    化学学报 · 2022-01-01

    Jin-Xu Zhao, Mingshu Zhang, Wen‐Fa Chen, Xiao‐Ming Jiang, Binwen Liu, Guo‐Cong Guo

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  3. KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring

    Dalton Transactions · 2022-01-01

    Shanshan Han, Qian-Ting Xu, Wenlong Liu, Sheng‐Ping Guo

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  4. KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units

    Inorganic Chemistry Frontiers · 2022-01-01

    Shanshan Han, Su‐Xin Yu, Wenlong Liu, Sheng‐Ping Guo

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  5. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

    European Journal of Inorganic Chemistry · 2022-10-05

    Jun Li, Shanshan Han, Sheng‐Ping Guo

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  7. Three polar indium phosphites exhibiting diverse structural networks and SHG-activity

    Journal of Solid State Chemistry · 2022-10-10

    Gang-Xiang Liu, Yu-Long Wei, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  8. Molecular boron clusters

    Elsevier eBooks · 2022-10-12

    Igor B. Sivaev

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  9. AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds

    Inorganic Chemistry Frontiers · 2022-12-19

    Ming‐Shu Zhang, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  10. [Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters

    Journal of Materials Chemistry C · 2023-01-01

    Chenyao Zhao, Kui Wu, Yan Xiao, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  11. Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation

    Chemistry of Materials · 2023-01-23

    Anna A. Berseneva, Lakshani W. Masachchi, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  12. Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-07

    Chao-Hong Xie, Bin‐Wen Liu, Guo‐Cong Guo

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  13. Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs

    Small · 2023-07-18

    Xian‐Dan Chai, Mingze Li, Shujuan Lin, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  14. Halide-Induced Band Gap Enhancement from Ba2SnSe4 to KBa2SnSe4Cl

    Crystal Growth & Design · 2023-07-20

    Xianghe Meng, Jinlong Shi, Mengran Sun, Jiyong Yao

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  15. A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties

    Journal of Solid State Chemistry · 2023-08-18

    Yun Xie, Da-Li Chen, Yu-Long Wei, Nan Zhang, Wen‐Dong Yao, Sheng‐Ping Guo

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  16. A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations

    Small · 2023-11-27

    Jiazheng Zhou, Ketian Hou, Yu Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  17. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  18. KREP 2 S 6 (RE = Sm, Gd, Tb, Dy): A Series of Polar Rare-Earth Thiophosphates with High Laser-Induced Damage Thresholds and Moderate Nonlinear-Optical Responses Synergistically Contributed by Isolated P 2 S 6 Units and {[RE 2 S 15 ] 24– } ∞ Layers

    Inorganic Chemistry · 2024-02-17

    Chen‐Yi Zhao, Wen‐Dong Yao, Mingyang Li, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  19. Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs

    Chemistry of Materials · 2024-04-24

    Yan Guo, Wen‐Fa Chen, Mingxin Li, Fan Wu, Qiu-Pei Qin, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  20. Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material

    Dalton Transactions · 2024-12-09

    Gopabandhu Panigrahi, Hunter B. Tisdale, Gregory W. Morrison, Hans‐Conrad zur Loye

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  21. Non-centrosymmetric structures designed rationally via a “dimensionality addition” strategy toward the promising nonlinear optical family [A–X][In–Se] (A = K/Ba and Rb/Ba; X = Cl and Br)

    Materials Horizons · 2025-01-01

    Shao‐Min Pei, Fan Wu, Ming‐Shu Zhang, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  22. From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance

    Inorganic Chemistry · 2025-02-13

    Die-Xue Yang, Yi‐Lei Lv, Jiandong Guo, Wen-Ye Gao, Wenlong Liu, Ru‐Ling Tang

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  23. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  24. From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide

    Inorganic Chemistry · 2025-07-09

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Chunlan Tang, Wenwen Jiang, Sheng‐Ping Guo, Wenlong Yin

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  25. Transition‐Metal Azo Schiff Base Complexes: Nonlinear Optics Across Solutions, Thin Films and Nanocomposites

    Advanced Optical Materials · 2025-09-04

    K. Waszkowska, Mark Busch, Siham Slassi, Amina Amine, Abdelkrim El‐Ghayoury, Janusz Strzelecki, Anna M. Zawadzka, Andriy V. Kityk, Patrick Huber, B. Sahraoui

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