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RESEARCH PAPER · Crystal Growth & Design · 2019

Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

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Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical MaterialsOriginalHybrid Metal Halides with Multiple Photoluminescence Centers233Hybrid Metal Halides with Multiple Photoluminescence Centers27Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Alkali-earth metal lead( ii ) oxyhalide Ba 27 Pb 8 O 8 Cl 54 exhibiting interesting [Pb 4 Ba 4 O 4 ] 8+ species8Salt-inclusion chalcogenides: an emerging class of IR nonlinear optical materials54Structure of the water-splitting photocatalyst oxysulfide α-LaOInS 2 and ab initio prediction of new polymorphs28Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement96KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure145Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Partial Isovalent Anion Substitution to Access Remarkable Second-Harmonic Generation Response: A Generic and Effective Strategy for Design of Infrared Nonlinear Optical Materials114The second-order NLO property of a photoswitchable heteroditpioc ion-pair receptor based on 2-pyridyl acylhydrazone linking with 2,6-pyridine bisamide: The impacts of metal cations and anions3Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides113Evaluation of nonlinear optical properties of quaternary chalcogenide halides Ba4Si3Se9Br2 and Ba4Ge3Se9Br222Lattice Anharmonicity of Stereochemically Active Lone Pairs Controls Thermochromic Band Gap Reduction of PbVO3Cl28Optoelectronic and charge transport properties of D-n-A type 1,3,5-triazine derivatives: A combined experimental and DFT study17Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response67Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53A review on the recently developed promising infrared nonlinear optical materials103A series of M 3 PS 4 (M = Ag, Cu and Ag/Cu) thiophosphates with diamond-like structures exhibiting large second harmonic generation responses and moderate ion conductivities28A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors31First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties24From thiophosphate to chalcohalide: mixed-anion AgS x Cl y ligands concurrently enhancing nonlinear optical effects and laser-damage threshold10M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28Recent progress in oxychalcogenides as IR nonlinear optical materials79Quaternary Chalcohalides CdSnSX2 (X = Cl or Br) with Neutral Layers: Syntheses, Structures, and Photocatalytic Properties18Confinement fluorescence effect (CFE): Lighting up life by enhancing the absorbed photon energy utilization efficiency of fluorophores37AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds34A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates21Symmetry and the Role of the Anion Sublattice in Aurivillius Oxyfluoride Bi2TiO4F218The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks36Nonlinear optical behavior of non‐centrosymmetric biferrocenyl Schiff‐base derivatives and their DNA binding potential supported by DFT and electrochemical investigations6Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Highly polarized [GeOTe 3 ] motif-driven structural order promotion and an enhanced second harmonic generation response in the new nonlinear optical oxytelluride Ba 3 Ge 2 O 4 Te 334Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties8Complex coordinated functional groups: A great genes for nonlinear optical materials64Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses11From oxides to oxysulfides: the mixed-anion GeS 3 O unit induces huge improvement in the nonlinear optical effect and optical anisotropy for potential nonlinear optical materials19HgBrI: a possible tecton for NLO molecular materials?4KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif47Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Two Nonlinear Optical Thiophosphates Cu 5 Hg 0.5 P 2 S 8 and AgHg 3 PS 6 Activated by Their Tetrahedra-Stacking Architecture12From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22First principles investigations of the structural, electronic, mechanical, linear and nonlinear optical properties of RbIO2F21Structural diversity among multinary pnictide oxides: a minireview focused on semiconducting and superconducting heteroanionic materials18Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups78Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups7Multianion induced out-of-plane proper polarization in oxyfluoride Aurivillius Bi2TiO4F28[C4H4O4]⋅[C6H13N] as a nonlinear optical co-crystal with spike-like dielectric anomalies0Precursor Engineering for the Synthesis of Mixed Anionic Metal (Cu, Mn) Chalcogenide Nanomaterials via Solvent-Less Synthesis7RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution80Mixed Anion Semiconductor In8S2.82Te6.18(Te2)33Coordination metal effect on the nonlinear optical properties and biological activity of double selenates8First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Heteroanionic Control of Exemplary Second-Harmonic Generation and Phase Matchability in 1D LiAsS2–xSex43[Ba2F2][Ge2O3S2]: An Unprecedented Heteroanionic Infrared Nonlinear Optical Material Containing Three Typical Anions47Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs5Ga9S16 with excellent infrared nonlinear optical performance29Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626Influence of the coordination metal on the thermal properties of double selenates: Theoretical insights and experimental study2Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity20Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)5d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response4An overview of Mg-based IR nonlinear optical materials22Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap23Rapid preparation of N,B-codoped carbon quantum dot based films with strong two-photon absorption and optical limiting effect21Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts38Polar Phosphorus Chalcogenide Cage Molecules: Enhancement of Nonlinear Optical Properties in Adducts1Mechanism of Reductive Fluorination by PTFE-Decomposition Fluorocarbon Gases for WO39Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Ba3GeTeS4: A new quaternary heteroanionic chalcogenide semiconductor8Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting1Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting0Synthesis of uranium mixed anion compounds synthesized using the Boron-Chalcogen Mixture method: Ba6Co6U0·91S13·5O0.5 and Ba5·47K0·53Zn6US13·5O0.55Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance56Hole and Electron Doping Outcomes in Bi2YO4Cl9Controlling the Luminescence of Rare-Earth Chalcogenide Iodides RE3(Ge1–xSix)2S8I (RE = La, Ce, and Pr) and Ce3Si2(S1–ySey)8I8Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs21ACd 4 Ga 5 Te 12 (A = K, Rb, Cs): Tellurides with a Strong Nonlinear Optical Response and Purple Emission24Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Ca2Ln(BS3)(SiS4) (Ln = La, Ce, and Gd): Mixed Metal Thioborate‐Thiosilicates as Well‐Performed Infrared Nonlinear Optical Materials29Towards the design of oxychalcogenide materials as candidates for solar water- splitting photocatalysis0Synthesis and characterization of photo-activatable systems0Designing Visible-Light Photoactive Thioapatites Using Thiovanadate Groups: The Ba5(VO4−αSα)3X (X = F, Cl, I) Phases4Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence50Mixed-anion square-pyramid [SbS3I2] units causing strong second-harmonic generation intensity and large birefringence8Tailoring the donor moieties in TPA ‐based organic dyes for efficient photovoltaic, optical and nonlinear optical response properties5Mixed Anionic M(S/X)6 Polyhedra as Symmetry-Breaking Motifs to Enhance the Infrared Nonlinear Optical Response in Y–M–S–X (M = Ga, Ge; X = Cl, Br)5Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4Promising photovoltaic, optoelectronic and p-type thermoelectric Sr4Pn2O (Pn = Sb, Bi) compounds: A first principles study12Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Advancements in Nonlinear Optical Materials: Paving the Way for Future Photonic Devices4[Cs14Cl][Tm71Se110]: An unusual salt-inclusion chalcogenide containing different valent Tm centers and ultralow thermal conductivity10Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media9Ca 2 La(MS 4 )(BS 3 ) (M = Ge/Si and Sn/Si): high-performance infrared nonlinear optical materials designed using an atomic site co-occupancy strategy9Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl1Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Through-space charge transfer enabled design of nonlinear optical chromophores with balanced absorption and efficiency0Wide-ranging predictions of new stable compounds powered by recommendation engines12In Silico Investigation of Physicochemical and Nonlinear Optical Properties of Azobenzene-Based Novel Molecules2Synthesis of cerium oxynitride and oxoguanidinate at high pressures0Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Theoretical investigations on electronic structures and spectroscopic properties of the diatomic lithium bismuthide cation1Growth and Characterization of Novel SrB2O4 Crystals0Two-Photon Absorption Carbon Quantum Dot Composite Films for Optical Limiting Applications2High‐Throughput Discovery of Large Birefringence Materials in Mixed‐N Hf‐O Systems0A new non-stoichiometric orthopyrophosphate Na2.48Cd4.15(P2O7)2(PO4): Crystal structure, defect chemistry and Eu3+-activated luminescence0ABCQ4型硫属化物红外非线性光学材料的构效关系(特邀)0Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 21Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications1Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS60Synthesis, Crystal Structure, and Optical Properties of α-SrHfS31Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold2Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials2Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials2First principles investigation of electronic and optical properties in the thio-apatites series Ba5(VO4−xSx)3X [X=F, Cl, Br, I]: Impact of multiple anionic substitution0Solution-Grown Cs2HgI4 Bulk Crystals: Achieving Strong SHG and High Damage Threshold Synergistically for IR Nonlinear Optics1Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 20From AgGaSe2 to MIIGa2Se4 (MII = Zn, Cd): Heterovalent Substitution Creates Ordered Vacancies for Balanced IR-NLO Performance0

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