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RESEARCH PAPER · Dalton Transactions · 2018

The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studiesOriginalCu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses25Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages11Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral5Bridging oxygen atoms in trigonal prism units driven strong second-harmonic-generation efficiency in Sr 3 Ge 2 O 4 Te 318Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties28Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)97RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks11Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap65Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32A review of structures and physical properties of rare earth chalcophosphates78Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626Synthesis and Complete Characterisation of new Oxide Materials by full and Congruent Crystallisation from Glass or the Molten liquid0The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior26Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters7Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 464From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials9From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials50Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Nonlinear Optical Effects in Europium Melilite Eu2MgSi2O70Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Optimization of inorganic rare-earth afterglow materials and their optoelectronic applications0

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29 direct citing papers saved.

  1. Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination

    Journal of Solid State Chemistry · 2018-09-25

    Zongdong Sun, Yang Chi, Sheng‐Ping Guo

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  2. Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses

    Inorganic Chemistry · 2019-03-01

    Yang Chi, Tengfei Jiang, Huaiguo Xue, Sheng‐Ping Guo

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  3. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie International Edition · 2019-08-26

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  4. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie · 2019-08-29

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  5. CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages

    Journal of Solid State Chemistry · 2021-09-27

    Mei Yan, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  6. Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral

    Journal of Alloys and Compounds · 2021-10-04

    Mingjun Xia, Lei Kang

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  7. Bridging oxygen atoms in trigonal prism units driven strong second-harmonic-generation efficiency in Sr 3 Ge 2 O 4 Te 3

    Chemical Communications · 2022-01-01

    Mengran Sun, Wenhao Xing, Ming‐Hsien Lee, Jiyong Yao

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  8. Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties

    Dalton Transactions · 2022-01-01

    Jiajing Wu, Yue Guo, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  9. Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)

    Chemistry of Materials · 2022-04-07

    Mao‐Yin Ran, Shenghua Zhou, Bingxuan Li, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks

    Journal of Solid State Chemistry · 2022-05-09

    Yu-Long Wei, Gang-Xiang Liu, Da-Li Chen, Wen‐Dong Yao, Xin Lian, Wenlong Liu, Ru‐Ling Tang

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  11. Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap

    ACS Applied Materials & Interfaces · 2022-05-11

    Ruiqi Wang, Fei Liang, Xin Liu, Yi Xiao, Qianqian Liu, Xian Zhang, Li‐Ming Wu, Ling Chen, Fuqiang Huang

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  12. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  13. Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O3

    Journal of Solid State Chemistry · 2022-10-06

    Lei Huai, Lunan Zhang, Beibei Zhang, Guangan Jia, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang

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  14. A review of structures and physical properties of rare earth chalcophosphates

    Coordination Chemistry Reviews · 2022-10-11

    Zi‐Xia Chen, Wenlong Liu, Sheng‐Ping Guo

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  15. Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS6

    Inorganic Chemistry · 2022-10-20

    Nan Zhang, Qian-Ting Xu, Zhi‐Hui Shi, Mei Yang, Sheng‐Ping Guo

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  16. Synthesis and Complete Characterisation of new Oxide Materials by full and Congruent Crystallisation from Glass or the Molten liquid

    Unknown journal · 2022-11-18

    Haytem Bazzaoui

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  17. The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior

    Chemical Communications · 2023-01-01

    Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  18. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  19. Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters

    Inorganic Chemistry · 2023-05-06

    Nan Zhang, Shanshan Han, Yun Xie, Da-Li Chen, Wen‐Dong Yao, Xiao Fen Huang, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  20. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

    Inorganic Chemistry · 2023-09-28

    Nan Zhang, Xiao Fen Huang, Wen‐Dong Yao, Yao Chen, Zheng-Rui Pan, Bingxuan Li, Wenlong Liu, Sheng‐Ping Guo

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  21. Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 4

    Journal of the American Chemical Society · 2023-10-09

    Yuanyu Yang, Yan Xiao, Bingxuan Li, Yi-Gang Chen, Penghui Guo, Bingbing Zhang, Xian‐Ming Zhang

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  22. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  23. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  24. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  25. Nonlinear Optical Effects in Europium Melilite Eu2MgSi2O7

    physica status solidi (b) · 2024-07-08

    K. M. Tsysar, Д. И. Бажанов, Karine Karlenovna Abgaryan, N. N. Kiselyova

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  26. Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials

    Inorganic Chemistry · 2024-11-06

    Fang-Xu Tian, Nan Zhang, Wen‐Dong Yao, Mingyang Li, Haiping Xu, Wenlong Liu, Jing Zhu, Sheng‐Ping Guo

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  27. La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior

    Dalton Transactions · 2025-01-01

    Jingjing Xu, Yan Xiao, Xiaowen Wu, Bingbing Zhang, Kui Wu

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  28. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

    Small · 2025-07-10

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  29. Optimization of inorganic rare-earth afterglow materials and their optoelectronic applications

    Review of Materials Research · 2026-08-01

    Fangnan Shen, Zihao Chen, Shoushun Wang, Meifang Yang, Yu–Xin Chen, Wen-Guang Li, Tian Tian

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