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RESEARCH PAPER · Coordination Chemistry Reviews · 2022

A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

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A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applicationsOriginalHg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy22Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif47Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs5Ga9S16 with excellent infrared nonlinear optical performance29DOUBLE YTTRIUM THIOSILICATES AYSiS4 (A = Rb, Cs): SYNTHESIS, STRUCTURE, OPTICAL PROPERTIES4Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25An overview of Mg-based IR nonlinear optical materials22From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties26Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution30Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319Phase Stability, Band Gap Tuning, and Rashba Splitting in Selenium-Alloyed Bournonite: CuPbSb(S1–xSex)38LnLiSiS4 (Ln = La and Ce): Promising infrared nonlinear optical materials designed by aliovalent substitution from SrCdSiS437Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64Y3Fe0.5SiSe7: A new cation-deficient quaternary mixed transition metal chalcogenide with extremely low thermal conductivity3[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Fabrication and Description of Amorphous Ge33Se47Sn20 Films for Optical Applications8Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution4Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family4Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance56KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System17A survey of stereoactive oxysalts for linear and nonlinear optical applications40Structure, Second-, and Third-Harmonic Generation of Li4P2S6: A Wide Gap Material with a High Laser-Induced Damage Threshold14Ca2Ln(BS3)(SiS4) (Ln = La, Ce, and Gd): Mixed Metal Thioborate‐Thiosilicates as Well‐Performed Infrared Nonlinear Optical Materials29NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application49Rb2Sn4Q9 (Q = S and Se): Low-Dimensional Noncentrosymmetric Chalcogenides with High Laser-Induced Damage Threshold10A Machine Learning Study on High Thermal Conductivity Assisted to Discover Chalcogenides with Balanced Infrared Nonlinear Optical Performance58Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy10Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy26Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation23Syntheses, crystal structures and photocurrent responses of Cs 2 Ag 2 Sb 2 S 5 and CsAgSb 4 S 7 with thiourea as a mineralizer4Alkyne-Functionalized Platinum Chalcogenide (S, Se) Nanoparticles2Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical Crystals6Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical Crystals34Cs 3 In(In 4 Se 7 )(P 2 Se 6 ): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting55Cs3In(In4Se7)(P2Se6): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting2A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6Design of Pentanary Mixed-Chalcogenides Ag2In2SiS6–xSex (x = 1, 2) Based on the Bucket Effect: Local Structural Difference and High-Performance Nonlinear-Optical Properties Realized by Partial Congener Substitution5The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution28Investigation into the physical characteristics of the compounds XBiSe2 (X = Li, Na or K)3Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Ag 2 GeS 3 : A Diamond‐Like Chalcogenide as an IR Nonlinear Optical Material with Outstanding Second‐Harmonic Generation Response28[Cs14Cl][Tm71Se110]: An unusual salt-inclusion chalcogenide containing different valent Tm centers and ultralow thermal conductivity10K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Lithium‐Ion Batteries2Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 94Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26Stabilization and Surface Functionalization of Palladium Disulfide Nanoparticles with Acetylene Derivatives1Crystal Growth and Property Characterization of a Novel Long-Wave Infrared Nonlinear Optical Crystal BaHgGeSe 49Deep‐Ultraviolet Transparent Nonlinear Optical Phosphates: A New Alternative to Conventional Borates9High-pressure chemistry of functional materials17Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5Ca 2 La(MS 4 )(BS 3 ) (M = Ge/Si and Sn/Si): high-performance infrared nonlinear optical materials designed using an atomic site co-occupancy strategy9Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units18Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Structural diversity and photocurrent responses of multi-component chalcogenidometalates8Thermal conductivity and balanced performance in infrared nonlinear optical multicomponent chalcogenides Li x Ag 1− x Ga y In 1− y Se 23AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties8Prediction and Evaluation of Li 2 ZnS 2 Crystals as Mid‐Infrared Nonlinear Optical Material with High Thermal Conductivity7Ionothermal syntheses, structures, and photocurrent responses of two-dimensional layered thiostannates1Two-in-one: assembling hybrid supertetrahedra chromophores and achieving high-performance “hexagonal warriors” in nonlinear optical crystals6Mild solvothermal syntheses, crystal structures, characterizations and properties of four ternary alkaline earth metal sulfides1Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials10Pressure optimized 2D-IV monochalcogenide for enhanced photovoltaic performance in skyscraper-integrated solar cell: A computational insight2Recent progress in structural design strategies of high-birefringence optical crystals54Alkali Metal Substitution-Induced Structural Transformation for RbREP2Se6 (RE = Gd, Tb, Dy) with Second-Harmonic Generation Responses6Recent progress in metal chalcogenide-MXene and MOF-derived composites for supercapacitors: synthesis, challenges, and future solutions36Impedance spectroscopy of multicomponent Se-Te-Sn-In chalcogenide glass ceramics5Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)2Syntheses, Structures, and Characterizations of Two Superatom-Based Cubic Perovskites0Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0Synthesis of functional chalcogenide materials for memory/sensing devices and their integration into artificial sensory systems2A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons12Self-Powered Photodetection in AgBiS 2 Nanocrystals Synthesized from AgBi-Mixed-Metal Thiolate1Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0ABCQ4型硫属化物红外非线性光学材料的构效关系(特邀)0Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components2Tailoring linear and nonlinear optical properties of 2D Sc 2 C MXenes via surface termination modulation0van der Waals layered CuInP 2 S 6 as infrared nonlinear optical material1Solvothermal Syntheses, Characterization, and Properties of Five Quaternary Thioarsenates and Thioantimonates0[Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution0Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation2Structure and transport properties of indium selenide thin films grown by sputtering: effect of post-deposition annealing0Circumventing the Eg–SHG trade-off in selenides: Salt-inclusion [X4Br2][MGa4Se10] with concurrent large band gap and strong nonlinear optical response1Heterovalent Coexistence‐Driven Symmetry Breaking and Dimensional Evolution: Designing Polar Heart‐Shaped Channels for Exceptional MFIR Nonlinear Optics5Synthesis, Structure, and Thermoelectric Properties of Quaternary Selenides M 2 In 5 Sb 9 Se 23 (M = Sn, Pb) with NaCl-Type Ribbon Motifs0Gravity‐Field Self‐Regulatory Engineering Enables PbIn 6 Te 10 Nonlinear Optical Crystals Boosting Laser‐Induced Damage Threshold1Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study0Compact High-Energy High-Beam-Quality Long-Wave Infrared BGSe-OPO0d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides0Engineering multi-metallic chalcogenides for advanced supercapacitors: Recent progress, challenges, and perspectives0From AgGaSe2 to MIIGa2Se4 (MII = Zn, Cd): Heterovalent Substitution Creates Ordered Vacancies for Balanced IR-NLO Performance0Directing Cluster Nuclearity in Semiconducting Lead Thioborates Built from Adamantane and Superadamantane Boron–Sulfur Clusters0Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals0

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  1. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

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  2. Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Chao Zhang, Shenghua Zhou, Yu Xiao, Hua Lin, Yi Liu

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  3. Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif

    Materials Chemistry Frontiers · 2022-01-01

    Yong‐Fang Shi, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  4. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

    Inorganic Chemistry · 2022-09-21

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  5. Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs5Ga9S16 with excellent infrared nonlinear optical performance

    Chinese Chemical Letters · 2022-09-23

    Hong Chen, Mao‐Yin Ran, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. DOUBLE YTTRIUM THIOSILICATES AYSiS4 (A = Rb, Cs): SYNTHESIS, STRUCTURE, OPTICAL PROPERTIES

    Journal of Structural Chemistry · 2022-12-01

    М.С. Тарасенко, R. V. Duritsyn, D. A. Potapov, Natalia V. Kuratieva, Alexey A. Ryadun, Н.Г. Наумов

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  7. Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction

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  8. An overview of Mg-based IR nonlinear optical materials

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  9. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

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    Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  10. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

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  11. Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution

    Inorganic Chemistry Frontiers · 2023-01-01

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  12. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

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  13. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

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  14. Phase Stability, Band Gap Tuning, and Rashba Splitting in Selenium-Alloyed Bournonite: CuPbSb(S1–xSex)3

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  15. LnLiSiS4 (Ln = La and Ce): Promising infrared nonlinear optical materials designed by aliovalent substitution from SrCdSiS4

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  16. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

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  17. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

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  18. Y3Fe0.5SiSe7: A new cation-deficient quaternary mixed transition metal chalcogenide with extremely low thermal conductivity

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  19. [K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

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  20. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

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  21. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

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  22. Fabrication and Description of Amorphous Ge33Se47Sn20 Films for Optical Applications

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  23. Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution

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  25. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

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  26. Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family

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  27. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

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  28. KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System

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  29. A survey of stereoactive oxysalts for linear and nonlinear optical applications

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  30. Structure, Second-, and Third-Harmonic Generation of Li4P2S6: A Wide Gap Material with a High Laser-Induced Damage Threshold

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  31. Ca2Ln(BS3)(SiS4) (Ln = La, Ce, and Gd): Mixed Metal Thioborate‐Thiosilicates as Well‐Performed Infrared Nonlinear Optical Materials

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  32. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

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  33. Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application

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  34. Rb2Sn4Q9 (Q = S and Se): Low-Dimensional Noncentrosymmetric Chalcogenides with High Laser-Induced Damage Threshold

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  35. A Machine Learning Study on High Thermal Conductivity Assisted to Discover Chalcogenides with Balanced Infrared Nonlinear Optical Performance

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  36. Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy

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  37. Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications

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  38. Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy

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  39. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

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  40. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

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  41. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

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  42. RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation

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  43. Syntheses, crystal structures and photocurrent responses of Cs 2 Ag 2 Sb 2 S 5 and CsAgSb 4 S 7 with thiourea as a mineralizer

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  44. Alkyne-Functionalized Platinum Chalcogenide (S, Se) Nanoparticles

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  45. Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical Crystals

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  46. Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical Crystals

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    Xin Lei Zhao, Chensheng Lin, Chao Wang, Haotian Tian, Tao Yan, Bingxuan Li, Ning Ye, Min Luo

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