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RESEARCH PAPER · Nature Materials · 2016

Optical activity from racemates

Romain Gautier, Jordan M. Klingsporn, Richard P. Van Duyne, Kenneth Reinhard Poeppelmeier

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Optical activity from racematesOriginalPacking of Helices: Is Chirality the Highest Crystallographic Symmetry?8From Sponges to Nanotubes: A Change of Nanocrystal Morphology for Acute‐Angle Bent‐Core Molecules22From Sponges to Nanotubes: A Change of Nanocrystal Morphology for Acute‐Angle Bent‐Core Molecules7The Curious Case of 2-Propyl-1H-benzimidazole in the Solid State: An Experimental and Theoretical Study20Environment effects on chiral recognition : a spectroscopic study0On the chiroptical properties of racemic crystals17Chiroptical Activity from an Achiral Biological Metal–Organic Framework64Uncovering and tailoring hidden Rashba spin–orbit splitting in centrosymmetric crystals89Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides206A solid-state chemist’s eye for the development of materials science in China5Emergence of chirality and structural complexity in single crystals at the molecular and morphological levels64Solid‐state synthesis of cyclo LD‐diphenylalanine: A chiral phase built from achiral subunits26Absolute Structure from Scanning Electron Microscopy46Machine-Learning-Assisted Synthesis of Polar Racemates33Symmetry-Assisted Protection and Compensation of Hidden Spin Polarization in Centrosymmetric Systems20Molecular Crystal Forms of Antitubercular Ethionamide with Dicarboxylic Acids: Solid-State Properties and a Combined Structural and Spectroscopic Study19Chiral halide perovskite crystals for optoelectronic applications237Circularly polarized luminescence of agglomerate emitters174Circular Polarization of Luminescence as a Tool To Study Molecular Dynamical Processes53Recent topics on circularly polarized luminescence generated by inorganic materials9Advances in single crystals and thin films of chiral hybrid metal halides38Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point Groups61Chiral Metal–Organic Frameworks583Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals85Synthesis, Mesomorphic Properties and Application of (R,S)-1-Methylpentyl 4′-Hydroxybiphenyl-4-carboxylate Derivatives5Chiroptical Activity of An Achiral Emissive Eu Metal–Organic Framework6Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites35Role of Hidden Spin Polarization in Nonreciprocal Transport of Antiferromagnets48Research Progress of Circularly Polarized Thermally Activated Delayed Fluorescence Materials and Devices8Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals93Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF38Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF6Enhanced Circular Dichroism and Polarized Emission in an Achiral, Low Band Gap Bismuth Iodide Perovskite Derivative14Strategies for the enhancement of CPL properties63Enantiomorph conversion in single crystals of the Weyl semimetal CoSi2Nanocrystalline Porous Materials for Chiral Separation: Synthesis, Mechanisms, and Applications21Chiral Templating in a Hybrid Chromium Chloride Hydrate2Atomically precise inorganic helices with a programmable irrational twist16Superlattice Assembly for Empowering Metal Nanoclusters47Unveiling the Racemization in Ferroelectrics with Coupled Ferroelectricity and Optical Activity2Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions11Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions2Natural Circular Dichroism beyond Chirality1Symmetry‐Breaking Directed Assembly in Achiral Point Groups for Circularly Polarized Room‐Temperature Phosphorescence9Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations14Hidden chiral topological superconductivity in two-dimensional centrosymmetric materials and Majorana mode braiding0Inch-sized achiral perovskite ferroelectric single crystals for multiaxial passive circularly polarized light response0Simultaneously Achieving Efficient Narrow‐Band Emission and Large Emission Dissymmetry Factor in an Achiral Hybrid Indium Chloride2Electrically Switchable Circularly Polarized Light Detection in Optically Active Ferroelectric0Electrically Switchable Circularly Polarized Light Detection in Optically Active Ferroelectric0

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  1. Packing of Helices: Is Chirality the Highest Crystallographic Symmetry?

    Crystals · 2016-08-30

    Romain Gautier, Kenneth Reinhard Poeppelmeier

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  2. From Sponges to Nanotubes: A Change of Nanocrystal Morphology for Acute‐Angle Bent‐Core Molecules

    Angewandte Chemie International Edition · 2016-09-05

    Ewa Górecka, Nataša Vaupotič, Anna Zep, Damian Pociecha

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  3. From Sponges to Nanotubes: A Change of Nanocrystal Morphology for Acute‐Angle Bent‐Core Molecules

    Angewandte Chemie · 2016-09-05

    Ewa Górecka, Nataša Vaupotič, Anna Zep, Damian Pociecha

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  4. The Curious Case of 2-Propyl-1H-benzimidazole in the Solid State: An Experimental and Theoretical Study

    The Journal of Physical Chemistry A · 2017-07-12

    María Mar Quesada‐Moreno, Aurora J. Cruz Cabeza, Juan Ramón Avilés‐Moreno, Pilar Cabildo, Rosa M. Claramunt, Ibón Alkorta, José Elguero, Fco. Javier Zúñiga, Juan Jesús López González

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  5. Environment effects on chiral recognition : a spectroscopic study

    Unknown journal · 2017-12-01

    Ariel Pérez‐Mellor

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  6. On the chiroptical properties of racemic crystals

    Chirality · 2018-02-08

    Bart E. Kahr, Alexander T. Martin, Karl‐Heinz Ernst

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  7. Chiroptical Activity from an Achiral Biological Metal–Organic Framework

    Journal of the American Chemical Society · 2018-08-24

    Lili Xu, Hai‐Feng Zhang, Mian Li, Seik Weng Ng, Jiang-He Feng, Jiang‐Gao Mao, Dan Li

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  8. Uncovering and tailoring hidden Rashba spin–orbit splitting in centrosymmetric crystals

    Nature Communications · 2019-02-22

    Lin‐Ding Yuan, Qihang Liu, Xiuwen Zhang, Jun‐Wei Luo, Shu‐Shen Li, Alex Zunger

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  9. Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides

    Journal of the American Chemical Society · 2019-09-17

    Jian Fei Zhao, Tongjin Zhang, Xi‐Yan Dong, Meng‐En Sun, Chong Zhang, Xinlei Li, Yong Sheng Zhao, Shuang‐Quan Zang

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  10. A solid-state chemist’s eye for the development of materials science in China

    Science China Materials · 2019-09-26

    Yadong Li

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  11. Emergence of chirality and structural complexity in single crystals at the molecular and morphological levels

    Nature Communications · 2020-01-20

    Maria Chiara di Gregorio, Linda J. W. Shimon, Vlad Brumfeld, Lothar Houben, Michal Lahav, Milko E. van der Boom

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  12. Solid‐state synthesis of cyclo LD‐diphenylalanine: A chiral phase built from achiral subunits

    Chirality · 2020-02-20

    Ariel Pérez‐Mellor, Katia Le Barbu‐Debus, Anne Zehnacker

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  13. Absolute Structure from Scanning Electron Microscopy

    Scientific Reports · 2020-03-04

    Ulrich Burkhardt, Horst Borrmann, Philip J. W. Moll, Marcus Peter Schmidt, Yuri Grin, Aimo Winkelmann

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  14. Machine-Learning-Assisted Synthesis of Polar Racemates

    Journal of the American Chemical Society · 2020-04-01

    Matthew Lander Nisbet, Ian M. Pendleton, Gene M. Nolis, Kent J. Griffith, Joshua Schrier, Jordi Cabana, Alexander J. Norquist, Kenneth Reinhard Poeppelmeier

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  15. Symmetry-Assisted Protection and Compensation of Hidden Spin Polarization in Centrosymmetric Systems

    Chinese Physics Letters · 2020-08-01

    Yingjie Zhang, Pengfei Liu, Hongyi Sun, Shixuan Zhao, Hu Xu, Qihang Liu

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  16. Molecular Crystal Forms of Antitubercular Ethionamide with Dicarboxylic Acids: Solid-State Properties and a Combined Structural and Spectroscopic Study

    Pharmaceutics · 2020-08-28

    Simone Bordignon, Paolo Cerreia Vioglio, Elena Amadio, Federica Rossi, Emanuele Priola, Dario Voinovich, Roberto Gobetto, Michele R. Chierotti

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  17. Chiral halide perovskite crystals for optoelectronic applications

    Matter · 2021-01-18

    Yangyang Dang, Xiaolong Liu, Bingqiang Cao, Xutang Tao

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  18. Circularly polarized luminescence of agglomerate emitters

    Aggregate · 2021-05-03

    Chong Zhang, Si Li, Xi‐Yan Dong, Shuang‐Quan Zang

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  19. Circular Polarization of Luminescence as a Tool To Study Molecular Dynamical Processes

    ChemPhotoChem · 2021-09-08

    Stefan C. J. Meskers

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  20. Recent topics on circularly polarized luminescence generated by inorganic materials

    Chemical Synthesis · 2022-01-01

    Xinling Liu, Ren-Hua Jin

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  21. Advances in single crystals and thin films of chiral hybrid metal halides

    Progress in Quantum Electronics · 2022-01-11

    Zhihang Guo, Junzi Li, Rui Chen, Tingchao He

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  22. Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point Groups

    Journal of the American Chemical Society · 2022-02-15

    Hao Li, Fei Song, Desheng Zhu, Yongbo Song, Chuanjun Zhou, Feng Ke, Liang Lü, Xi Kang, Manzhou Zhu

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  23. Chiral Metal–Organic Frameworks

    Chemical Reviews · 2022-03-28

    Wei Gong, Zhijie Chen, Jinqiao Dong, Yan Liu, Yong Cui

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  24. Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals

    Journal of the American Chemical Society · 2022-08-01

    Xiaoqi Li, Fafa Wu, Yunpeng Yao, Wentao Wu, Chengmin Ji, Lina Li, Zhihua Sun, Junhua Luo, Xitao Liu

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  25. Synthesis, Mesomorphic Properties and Application of (R,S)-1-Methylpentyl 4′-Hydroxybiphenyl-4-carboxylate Derivatives

    Crystals · 2022-11-25

    Magdalena Urbańska, Mateusz Szala

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  26. Chiroptical Activity of An Achiral Emissive Eu Metal–Organic Framework

    Chemistry - A European Journal · 2022-12-08

    Yuan Li, Xiaojie Ma, Xiaojun Xu, Yuqing Ye, Bo Wang

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  27. Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites

    Nature Communications · 2022-12-13

    Tingting Zhu, Jie Bie, Chengmin Ji, Xinyuan Zhang, Lina Li, Xitao Liu, Xiao‐Ying Huang, Wei Fa, Shuang Chen, Junhua Luo

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  28. Role of Hidden Spin Polarization in Nonreciprocal Transport of Antiferromagnets

    Physical Review Letters · 2022-12-28

    Weizhao Chen, Mingqiang Gu, Jiayu Li, Panshuo Wang, Qihang Liu

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  29. Research Progress of Circularly Polarized Thermally Activated Delayed Fluorescence Materials and Devices

    Chinese Journal of Organic Chemistry · 2023-01-01

    Xiaodong Yang, Xiao-Kang Zheng, Hailiang Dong, Jing Sun, Hua Wang

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  30. Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals

    Nature Chemistry · 2023-08-07

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  31. Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF

    Angewandte Chemie International Edition · 2023-08-28

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  32. Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF

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  33. Enhanced Circular Dichroism and Polarized Emission in an Achiral, Low Band Gap Bismuth Iodide Perovskite Derivative

    Journal of the American Chemical Society · 2023-10-05

    Jakob Möbs, Philip Klement, Gina Stuhrmann, Lukas Gümbel, Marius J. Müller, Sangam Chatterjee, Johanna Heine

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  34. Strategies for the enhancement of CPL properties

    Coordination Chemistry Reviews · 2023-11-24

    Madiha Saqlain, Hafiz Muhammad Zohaib, Samina Qamar, Hinna Malik, Hui Li

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  35. Enantiomorph conversion in single crystals of the Weyl semimetal CoSi

    Communications Materials · 2023-12-19

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  36. Nanocrystalline Porous Materials for Chiral Separation: Synthesis, Mechanisms, and Applications

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  37. Chiral Templating in a Hybrid Chromium Chloride Hydrate

    Inorganic Chemistry · 2024-07-04

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  38. Atomically precise inorganic helices with a programmable irrational twist

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  39. Superlattice Assembly for Empowering Metal Nanoclusters

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  40. Unveiling the Racemization in Ferroelectrics with Coupled Ferroelectricity and Optical Activity

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  41. Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions

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  42. Chiral Communication between Enantiomeric Sergeants and Achiral Soldiers in Racemic Triblock Copolymers with Heterochiral Cores for Triggering Multiple Helicity Inversions

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  43. Natural Circular Dichroism beyond Chirality

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  44. Symmetry‐Breaking Directed Assembly in Achiral Point Groups for Circularly Polarized Room‐Temperature Phosphorescence

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  45. Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations

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  46. Hidden chiral topological superconductivity in two-dimensional centrosymmetric materials and Majorana mode braiding

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  47. Inch-sized achiral perovskite ferroelectric single crystals for multiaxial passive circularly polarized light response

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  48. Simultaneously Achieving Efficient Narrow‐Band Emission and Large Emission Dissymmetry Factor in an Achiral Hybrid Indium Chloride

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  49. Electrically Switchable Circularly Polarized Light Detection in Optically Active Ferroelectric

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