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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations

Rayan Chakraborty, David B. Mitzi

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Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium CationsOriginalRole of positional isomerism in A-site organic cation: structural variation driven photophysical and ferroelectric responses in centrosymmetric layered perovskites2Tuning exciton transport rate in two-dimensional perovskites via modulating the intra-octahedral distortion0Local Symmetry Breaking in 3D Hybrid Perovskites with 3-Hydroxyazetidinium1Reducing the symmetry of organic cations and reconfiguring hydrogen bond networks to construct polar lead-free hybrid perovskite1Phase-Transition-Enabled Switching of Chiroptical Properties in 2D Hybrid Perovskites1Hidden Spin-Valley-Locking Extends Room Temperature Spin Lifetime in 2D Perovskite Semiconductors0Dual‐Color Tunable Circularly Polarized Luminescence With Anti‐Thermal‐Quenching Enabled by Asymmetric Hydrogen‐Bonding Networks in Hybrid Manganese Halides3Dual tuning of second-harmonic generation and Rashba-Dresselhaus spin-splitting in chiral hybrid perovskites via halogen-site engineering1Coordination-Constraint-Driven Enhanced Chirality Induction in Perovskite Quantum Dot Solids1Hidden spin-valley locking stabilizes nanosecond spin polarization in 2D perovskites2Kinetic Trapping of Pressure‐Induced Symmetry Breaking in Hybrid Metal Halides via Fluorine‐Mediated Molecular Locking0Kinetic Trapping of Pressure‐Induced Symmetry Breaking in Hybrid Metal Halides via Fluorine‐Mediated Molecular Locking02D Tin Halide Perovskite Semiconductors: Fundamentals, Applications, and Future Perspectives0Melting Point Depression and Glass-Forming Abilities in Pb- and Sn-Based Hybrid Perovskites with a Nonprimary Ammonium Cation0

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  1. Role of positional isomerism in A-site organic cation: structural variation driven photophysical and ferroelectric responses in centrosymmetric layered perovskites

    Journal of Materials Chemistry C · 2026-01-01

    Vishal Singh, Poonam Moar, Dirtha Sanyal, Sourabh Barua, Joydeep Dhar

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  2. Tuning exciton transport rate in two-dimensional perovskites via modulating the intra-octahedral distortion

    Inorganic Chemistry Frontiers · 2026-01-01

    Shihui He, Minjie Li, Yumo Han, Haotian Bai, Yan Wan

    Read original paper ↗ ·

  3. Local Symmetry Breaking in 3D Hybrid Perovskites with 3-Hydroxyazetidinium

    Journal of the American Chemical Society · 2026-02-24

    Rayan Chakraborty, Benjamin G. Bobay, Xixi Qin, Volker Blüm, David B. Mitzi

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  4. Reducing the symmetry of organic cations and reconfiguring hydrogen bond networks to construct polar lead-free hybrid perovskite

    Chinese Chemical Letters · 2026-03-01

    Lin Pan, Shufang Wu, Xiaorong Mao, Ruifang Zhao, Qi Wang, Yueyue He, Dongying Fu

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  5. Phase-Transition-Enabled Switching of Chiroptical Properties in 2D Hybrid Perovskites

    Journal of the American Chemical Society · 2026-03-04

    Perry W. Martin, Seth R. Jackson, Jolene N. Keller, Thy D. U. Phan, Kevin Liebetrau, Rae Hunter, Connor G. Bischak

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  6. Hidden Spin-Valley-Locking Extends Room Temperature Spin Lifetime in 2D Perovskite Semiconductors

    Research Square · 2026-04-20

    David B. Mitzi, Volker Blüm, Matthew C. Beard, Yifan Dong, Rayan Chakraborty, Leo Romanetz, Kelsey Garden, Jacob Shelton, Matthew P. Hautzinger

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  7. Dual‐Color Tunable Circularly Polarized Luminescence With Anti‐Thermal‐Quenching Enabled by Asymmetric Hydrogen‐Bonding Networks in Hybrid Manganese Halides

    Advanced Materials · 2026-05-06

    Tianxin Bai, Pengfei Cheng, Zhen Chi, Bo Zhang, J ZHU, Jianyong Liu, Kaifeng Wu

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  8. Dual tuning of second-harmonic generation and Rashba-Dresselhaus spin-splitting in chiral hybrid perovskites via halogen-site engineering

    npj Computational Materials · 2026-06-15

    Qian Xu, Xuli Cheng, Xiyue Cheng, Xiyue Cheng, Xiyue Cheng, Lorenzo Malavasi, Marta Morana, Juan J. Aucar, Muskan Nabi, Gustavo A. Aucar, Shuiquan Deng, Lingyan Feng, Wei Li Ren, Alessandro Stroppa

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  9. Coordination-Constraint-Driven Enhanced Chirality Induction in Perovskite Quantum Dot Solids

    Journal of the American Chemical Society · 2026-07-03

    Cong Geng, Ruiyang Yin, Wenda Sun, Linyue Gao, Zijin Ding, Xue Han, Keyu Wei, Changjiu Sun, Yicheng Sui, Yimu Chen, Xiyan Li, Thamraa M. Alshahrani, Wen‐Di Li, Xiaoye Wang, Yuanzhi Jiang, Mingjian Yuan

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  10. Hidden spin-valley locking stabilizes nanosecond spin polarization in 2D perovskites

    Nature Nanotechnology · 2026-07-27

    Rayan Chakraborty, Yifan Dong, Jacob L. Shelton, Kelsey Garden, Leo Romanetz, Matthew P. Hautzinger, Matthew C. Beard, Volker Blüm, David B. Mitzi

    Read original paper ↗ ·

  11. Kinetic Trapping of Pressure‐Induced Symmetry Breaking in Hybrid Metal Halides via Fluorine‐Mediated Molecular Locking

    Angewandte Chemie International Edition · 2026-07-29

    Congcong Chen, Huanwei Fu, Mengke Zhang, Songhao Guo, Jun Luo, Hongli Xuan, Kejun Bu, Yang Liu, Zhikai Zhu, Chunhua Chen, Meng‐Qiu Cai, Xujie Lü, Lingling Mao

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  12. Kinetic Trapping of Pressure‐Induced Symmetry Breaking in Hybrid Metal Halides via Fluorine‐Mediated Molecular Locking

    Angewandte Chemie · 2026-07-29

    Congcong Chen, Huanwei Fu, Mengke Zhang, Songhao Guo, Jun Luo, Hongli Xuan, Kejun Bu, Yang Liu, Zhikai Zhu, Chunhua Chen, Meng‐Qiu Cai, Xujie Lü, Lingling Mao

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  13. 2D Tin Halide Perovskite Semiconductors: Fundamentals, Applications, and Future Perspectives

    Advanced Functional Materials · 2026-08-06

    Aqiang Liu, Guohang Ba, Haoran Wang, Bosen Zou, Hong Lian, Shuanglong Wang

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  14. Melting Point Depression and Glass-Forming Abilities in Pb- and Sn-Based Hybrid Perovskites with a Nonprimary Ammonium Cation

    Chemistry of Materials · 2026-09-30

    Yi Xie, Rayan Chakraborty, Akash Singh, Timothy M. McWhorter, Milinda Abeykoon, Daniel Olds, Volker Blüm, David B. Mitzi

    Read original paper ↗ ·
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