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RESEARCH PAPER · Journal of the American Chemical Society · 2019

Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides

Jian Fei Zhao, Tongjin Zhang, Xi‐Yan Dong, Meng‐En Sun, Chong Zhang, Xinlei Li, Yong Sheng Zhao, Shuang‐Quan Zang

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Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese HalidesOriginalAxially Chiral TADF‐Active Enantiomers Designed for Efficient Blue Circularly Polarized Electroluminescence67Axially Chiral TADF‐Active Enantiomers Designed for Efficient Blue Circularly Polarized Electroluminescence276Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning101Proton Conductive Luminescent Thermometer Based on Near-Infrared Emissive {YbCo2} Molecular Nanomagnets162A Lead‐Free All‐Inorganic Metal Halide with Near‐Unity Green Luminescence89Organic heterostructures composed of one- and two-dimensional polymorphs for photonic applications56Micromanipulation of Mechanically Compliant Organic Single‐Crystal Optical Microwaveguides185Micromanipulation of Mechanically Compliant Organic Single‐Crystal Optical Microwaveguides42Luminescent manganese(II) complexes: Synthesis, properties and optoelectronic applications253Electric‐Field‐Regulated Energy Transfer in Chiral Liquid Crystals for Enhancing Upconverted Circularly Polarized Luminescence through Steering the Photonic Bandgap233Three‐Dimensional Cuprous Lead Bromide Framework with Highly Efficient and Stable Blue Photoluminescence Emission93Three‐Dimensional Cuprous Lead Bromide Framework with Highly Efficient and Stable Blue Photoluminescence Emission8Supramolecular Approach for Fine-Tuning of the Bright Luminescence from Zero-Dimensional Antimony(III) Halides179Organic solvent-free lyophilization assisted recrystallization synthesis of high-purity green emissive Cs3MnX5 (X = I, Br)36Chiral Platinum‐Based Metallomesogens with Highly Efficient Circularly Polarized Electroluminescence in Solution‐Processed Organic Light‐Emitting Diodes98Beyond Chiral Organic (p-Block) Chromophores for Circularly Polarized Luminescence: The Success of d-Block and f-Block Chiral Complexes127Enantiomeric MOF Crystals Using Helical Channels as Palettes with Bright White Circularly Polarized Luminescence219Phosphorescent Manganese(II) Complexes and Their Emerging Applications155Molecular- and Structural-Level Organic Heterostructures for Multicolor Photon Transportation31Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids289Generation of Circularly Polarized Luminescence by Symmetry Breaking35Designing Ultraflexible Perovskite X‐Ray Detectors through Interface Engineering87Adaptive Chirality of an Achiral Cage: Chirality Transfer, Induction, and Circularly Polarized Luminescence through Aqueous Host–Guest Complexation83A family of Mn( ii ) complexes exhibiting strong photo- and triboluminescence as well as polymorphic luminescence52Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design94Manganese( ii ) bromo- and iodo-complexes with phosphoramidate and phosphonate ligands: synthesis, characterization and photoluminescence25Photo- and triboluminescent robust 1D polymers made of Mn( ii ) halides and meta -carborane based bis(phosphine oxide)45SHG-active NIR-emissive molecular nanomagnets generated in layered neodymium( iii )–octacyanidometallate( iv ) frameworks31The moisture-responsive structural transformation of manganochlorine for water-soluble luminescent switching ink26Tuning the dynamic magnetic behaviour and proton conductivity via water-induced reversible single-crystal to single-crystal structural transformation31Two pairs of chiral lanthanide–oxo clusters Ln 14 induced by amino acid derivatives5Handedness-inverted polymorphic helical assembly and circularly polarized luminescence of chiral platinum complexes71Chiral halide perovskite crystals for optoelectronic applications237Efficient Circularly Polarized Electroluminescence from Chiral Thermally Activated Delayed Fluorescence Emitters Featuring Symmetrical and Rigid Coplanar Acceptors72Biased Symmetry Breaking and Chiral Control by Self‐Replicating in Achiral Tetradentate Platinum (II) Complexes53Biased Symmetry Breaking and Chiral Control by Self‐Replicating in Achiral Tetradentate Platinum (II) Complexes14Light‐Emitting Metal–Organic Halide 1D and 2D Structures: Near‐Unity Quantum Efficiency, Low‐Loss Optical Waveguide and Highly Polarized Emission74Light‐Emitting Metal–Organic Halide 1D and 2D Structures: Near‐Unity Quantum Efficiency, Low‐Loss Optical Waveguide and Highly Polarized Emission14Full‐Color and White Circularly Polarized Luminescence of Hydrogen‐Bonded Ionic Organic Microcrystals109Full‐Color and White Circularly Polarized Luminescence of Hydrogen‐Bonded Ionic Organic Microcrystals22Circularly polarized luminescence of agglomerate emitters172Low-Dimensional Organic Metal Halide Hybrids with Excitation-Dependent Optical Waveguides from Visible to Near-Infrared Emission42Structural Dimensionality Modulation toward Enhanced Photoluminescence Efficiencies of Hybrid Lead‐Free Antimony Halides164Photochemically Switchable Interconnected Microcavities for All‐Organic Optical Logic Gate37Photoluminescence Behavior of Zero-Dimensional Manganese Halide Tetrahedra Embedded in Conjugated Organic Matrices89Chiral Chromium(III) Complexes as Promising Candidates for Circularly Polarized Luminescence41Amplified circularly polarized luminescence promoted by hierarchical self-assembly involving Pt···Pt interactions21Dipole-Orientation-Dependent Förster Resonance Energy Transfer from Aromatic Head Groups to MnBr42– Blocks in Organic–Inorganic Hybrids40Syntheses and structure characterization of seven inorganic-organic hybrids based on N-Brønsted bases and perhalometallates1Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications608Ultraviolet Light Detectable Circularly Polarized Room Temperature Phosphorescence in Chiral Naphthalimide Self-Assemblies82Local Structure Engineering in Lanthanide-Doped Nanocrystals for Tunable Upconversion Emissions175Zero-Dimensional Lead-Free Halide with Indirect Optical Gap and Enhanced Photoluminescence by Sb Doping76Air-grown hybrid copper( i ) halide single crystals: structural transformations and ultraviolet-pumped photoluminescence applications36An enantiomeric pair of 2D organic–inorganic hybrid perovskites with circularly polarized luminescence and photoelectric effects29Manganese halide hybrids with a reversible luminous color and their application for a white light-emitting diode8Recent topics on circularly polarized luminescence generated by inorganic materials9Advances in single crystals and thin films of chiral hybrid metal halides38Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full‐Color and White Phosphorescence and Anisotropic Photon Transport34Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full‐Color and White Phosphorescence and Anisotropic Photon Transport1Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point Groups61Dual emission from Mn(II) complexes with carbazolyl-substituted phosphoramides18Dysprosium(III) Metal–Organic Framework Demonstrating Ratiometric Luminescent Detection of pH, Magnetism, and Proton Conduction68Environmental-friendly lead-free chiral Mn-based metal halides with efficient circularly polarized photoluminescence at room temperature49Zero-Dimensional Zinc Halide Organic Hybrids with Excellent Optical Waveguide Properties29All‐Inorganic Manganese‐Based CsMnCl 3 Nanocrystals for X‐Ray Imaging113Structural Origin of Enhanced Circularly Polarized Luminescence in Hybrid Manganese Bromides113Structural Origin of Enhanced Circularly Polarized Luminescence in Hybrid Manganese Bromides16Enantiomorphic Single Crystals of Linear Lead(II) Bromide Perovskitoids with White Circularly Polarized Emission64Enantiomorphic Single Crystals of Linear Lead(II) Bromide Perovskitoids with White Circularly Polarized Emission9Recent progress of triplet state emission in organic-inorganic hybrid metal halides28Chiral Metal–Organic Cluster Induced High Circularly Polarized Luminescence of Metal–Organic Framework Thin Film67Boosting Circularly Polarized Luminescence Performance by a Double π-Helix and Heteroannulation133Organo-Metal Halide Scintillator with Weak Thermal Quenching Up to 200 °C46New Approach toward Dual-Emissive Organic–Inorganic Hybrids by Integrating Mn(II) and Cu(I) Emission Centers in Ionic Crystals34Highly Luminescent Zero-Dimensional Organic Copper Halide with Low-Loss Optical Waveguides and Highly Polarized Emission63Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging99Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging29Efficient Narrow-Band Green Light-Emitting Hybrid Halides for Wide Color Gamut Display46Supramolecular chiral polymeric aggregates: Construction and applications144Tuning the Circularly Polarized Luminescence of Supramolecules via Self-Assembly Morphology Control22Aggregation‐Dependent Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence from Chiral Carbene‐CuI‐Amide Enantiomers62Aggregation‐Dependent Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence from Chiral Carbene‐CuI‐Amide Enantiomers0Helical Stacking Assembly of Orderly Silicon Nanowire Multilayers for Ultrastrong Dissymmetrical Amplification of Circularly Polarized Light16Ultrasensitive Optical Thermometry via Inhibiting the Energy Transfer in Zero-Dimensional Lead-Free Metal Halide Single Crystals28Molecular Cocrystals with Hydrogen-Bonded Polymeric Structures and Polarized Luminescence6Manganese(II) Bromide Compound with Diprotonated 1-Hydroxy-2-(pyridin-2-yl)-4,5,6,7-tetrahydrobenzimidazole: Dual Emission and the Effect of Proton Transfers13Chiroptical Activity of An Achiral Emissive Eu Metal–Organic Framework6Highly Luminescent Earth‐Benign Organometallic Manganese Halide Crystals with Ultrahigh Thermal Stability of Emission from 4 to 623 K26Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites35Micrometer‐Scale Optical Web Made of Spider Dragline Fibers with Optical Gate Operations10Circularly polarized luminescence of lanthanide complexes: From isolated individuals, discrete oligomers, to hierarchical assemblies75A supramolecular assembly-based strategy towards the generation and amplification of photon up-conversion and circularly polarized luminescence17Birefringence and polarized luminescence of a manganese( ii ) chloride–triphenylphosphine oxide compound: application in LEDs and photolithography13Dynamic CPL switching realized in chiral Mn-based metal halides with reversible thermochromism51Flexible Crystal Heterojunctions of Low-Dimensional Organic Metal Halides Enabling Color-Tunable Space-Resolved Optical Waveguides62Modulating anthracene excimer through guest engineering in two-dimensional lead bromide hybrids13Recent advances in ultralong room-temperature phosphorescence materials based on metal–organic halides31Host molecule enhanced aggregation induced emission of chiral silver nanoclusters for achieving highly efficient circularly polarized electroluminescence24Elucidating Structure–Property Correlation in Perovskitoid and Antiperovskite Piperidinium Manganese Chloride23Highly Emissive Chiral Mn(II) Bromide Hybrids for UV‐Pumped Circularly Polarized LEDs and Scintillator Image Applications73Two Organic–Inorganic Manganese(II) Halide Hybrids Showing Compelling Photo- and Mechanoluminescence as well as Rewritable Anticounterfeiting Printing32Mixed-cation chiral perovskites displaying warm-white circularly polarized luminescence24Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications155Strong Magnetically‐Responsive Circularly Polarized Phosphorescence and X‐Ray Scintillation in Ultrarobust Mn(II)–Organic Helical Chains81Integrating Achiral and Chiral Organic Ligands in Zero‐Dimensional Hybrid Metal Halides to Boost Circularly Polarized Luminescence81Integrating Achiral and Chiral Organic Ligands in Zero‐Dimensional Hybrid Metal Halides to Boost Circularly Polarized Luminescence8Ligand-protected metal nanoclusters as low-loss, highly polarized emitters for optical waveguides294Satellite Red Emission from a Single Green-Emissive MnBr42– Tetrahedron in Soft Hybrid Single Crystals22Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF37Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF6Circularly polarized phosphorescence and photon transport of micro/nanocrystals of ruthenium and iridium complexes with chiral anions43Luminescence‐Based Infrared Thermal Sensors: Comprehensive Insights26Pseudo‐2D Layered Organic‐Inorganic Manganese Bromide with a Near‐Unity Photoluminescence Quantum Yield for White Light‐Emitting Diode and X‐Ray Scintillator143Pseudo‐2D Layered Organic‐Inorganic Manganese Bromide with a Near‐Unity Photoluminescence Quantum Yield for White Light‐Emitting Diode and X‐Ray Scintillator33Exciton Chirality Transfer Empowers Self‐Triggered Spin‐Polarized Amplified Spontaneous Emission from 1D‐Anchoring‐3D Perovskites23Enhanced Circular Dichroism and Polarized Emission in an Achiral, Low Band Gap Bismuth Iodide Perovskite Derivative14Antimony-Triggered Tunable White Light Emission in Lead-Free Zero-Dimensional Indium Halide with Ultrastable CCT of White Light Emitting Diodes19Strategies for the enhancement of CPL properties62Review—Photoluminescence Spectroscopy of Mn2+-Activated Phosphors: Part II. Some Representative Phosphors7Color Tunable Phosphorescent Neutral Manganese(II) Complexes Through Steric Hindrance Driven Bond Angle Distortion28A universal supramolecular assembly strategy for achieving efficient tunable white emission and anti-counterfeiting in antimony doped tin( iv )-based vacancy-ordered double perovskites10Circularly polarized luminescence in quantum dot-based materials42Enantioselective assembly of tetrahedral Zr 4 (embonate) 6 cages in zeolitic frameworks for synergetic circularly polarized luminescence1Highly efficient circularly polarized electroluminescence based on chiral manganese( ii ) complexes33Multi-stimuli-responsive luminescence enabled by crown ether anchored chiral antimony halide phosphors54Recent strategies for triplet-state emission regulation toward non-lead organic–inorganic metal halides17Supramolecular crystals of Mn(15-crown-5)(MnCl 4 )(DMF) with dielectric phase transition, high quantum yield and phase transition-induced luminescence enhancement behavior3Variable energy transfer in one-dimensional chiral Mn/Cd-based halides and strong stereo-selective fluorescence for chiral recognition5Inch‐Size Achiral Perovskite Single Crystals for Distinguishing Circularly Polarized Light with A Large Asymmetry Factor13Bright Circularly Polarized Mechanoluminescence from 0D Hybrid Manganese Halides99Ligand Chirality Transfer from Solution State to the Crystalline Self‐Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems45Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead‐free Hybrid Metal Halides7Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead‐free Hybrid Metal Halides63Regulating photoluminescence through single-crystal-to-single-crystal transformation of solvent-containing zero-dimensional hybrid metal halide isomers32Magnetic coupling interaction-related photoluminescence behaviors in all-inorganic manganese chloride perovskites13Homochiral Tetraphenylethene-Based Metal–Organic Frameworks with Circularly Polarized Luminescence for Enantioselective Recognition4Ultrafast Visual Detection of a Trace Amount of Water by Highly Efficient Hybrid Manganese Halides18Evaluation of Point Group Symmetry in Lanthanide(III) Complexes: A New Implementation of a Continuous Symmetry Operation Measure with Autonomous Assignment of the Principal Axis20Unlocking the Potential of Organic‐Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications169Highly Efficient Manganese Bromides with Reversible Luminescence Switching through Amorphous–Crystalline Transition9Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides18Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides2Luminescent Organic Single Crystals for Flexible Optical Fiber Scintillators and X-ray Imaging8Recent progress on photoactive nonprecious transition-metal complexes26Organic Manganese Halides with Near‐Unity Quantum Efficiency for High‐Resolution and Flexible X‐Ray Detection and Imaging17Supramolecular Assembly Enhanced Linear and Nonlinear Chiroptical Properties of Chiral Manganese Halides9Supramolecular Assembly Enhanced Linear and Nonlinear Chiroptical Properties of Chiral Manganese Halides48High resolution X-ray imaging via near unity emission organic–inorganic manganese bromide scintillator films using a suction filtration method8Near-unity and narrow green emission from a manganese( ii ) bromide for efficient WLEDs and 3D X-ray imaging14

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  42. Low-Dimensional Organic Metal Halide Hybrids with Excitation-Dependent Optical Waveguides from Visible to Near-Infrared Emission

    ACS Applied Materials & Interfaces · 2021-05-27

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  43. Structural Dimensionality Modulation toward Enhanced Photoluminescence Efficiencies of Hybrid Lead‐Free Antimony Halides

    Advanced Optical Materials · 2021-06-03

    Jian‐Qiang Zhao, Meng‐Fei Han, Xue‐Jie Zhao, Yue‐Yu Ma, Chang‐Qing Jing, Hong‐Mei Pan, Dongyang Li, Cheng‐Yang Yue, Xiao‐Wu Lei

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  44. Photochemically Switchable Interconnected Microcavities for All‐Organic Optical Logic Gate

    Advanced Functional Materials · 2021-06-19

    Hendra Hendra, Akihide Takeuchi, Hiroshi Yamagishi, Osamu Oki, Masakazu Morimoto, Masahiro Irie, Yohei Y. Yamamoto

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  45. Photoluminescence Behavior of Zero-Dimensional Manganese Halide Tetrahedra Embedded in Conjugated Organic Matrices

    The Journal of Physical Chemistry Letters · 2021-07-30

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  46. Chiral Chromium(III) Complexes as Promising Candidates for Circularly Polarized Luminescence

    ChemPhotoChem · 2021-08-10

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  47. Amplified circularly polarized luminescence promoted by hierarchical self-assembly involving Pt···Pt interactions

    Science China Materials · 2021-08-26

    Gui‐Fei Huo, Qian Tu, Yi‐Xiong Hu, Bo Jiang, Qifeng Zhou, Yanfei Niu, Xiao‐Li Zhao, Hong‐Ming Ding, Jin Wen, Guang‐Qiang Yin, Xueliang Shi, Lin Sen Xu

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  48. Dipole-Orientation-Dependent Förster Resonance Energy Transfer from Aromatic Head Groups to MnBr42– Blocks in Organic–Inorganic Hybrids

    The Journal of Physical Chemistry Letters · 2021-09-02

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  49. Syntheses and structure characterization of seven inorganic-organic hybrids based on N-Brønsted bases and perhalometallates

    Inorganic and Nano-Metal Chemistry · 2021-10-27

    Zhihang Li, Kaikai Hu, Weiqiang Xu, Shouwen Jin, Liqun Bai, Daqi Wang

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  50. Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications

    Science China Chemistry · 2021-11-10

    Zhongliang Gong, Xuefeng Zhu, Zhonghao Zhou, Si‐Wei Zhang, Dong Yang, Biao Zhao, Yi‐Pin Zhang, Jianping Deng, Yixiang Cheng, You‐Xuan Zheng, Shuang‐Quan Zang, Hua Kuang, Pengfei Duan, Mingjian Yuan, Chuan‐Feng Chen, Yong Sheng Zhao, Yu‐Wu Zhong, Ben Zhong Tang, Minghua Liu

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