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RESEARCH PAPER · Angewandte Chemie International Edition · 2023

Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF

Yang Dong Hu, Su‐Kao Peng, Ji Min Zheng, Dong Luo, Mo Xie, Yong‐Liang Huang, Xuan Cai, Jizhuang Wang, Xiao‐Ping Zhou, Dan Li

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Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADFOriginalLuminescent heterobimetallic Au(I)/Ag(I) complex stabilized by a unique acetylide fragment: A spectroscopic and computational study of aurophilic ‒ argentophilic interactions2Visible-light excitable thermally activated delayed fluorescence from hydrogen-bonded D-A aromatic N-heterocycle/polymer material and the application for anti-counterfeiting6A fluorescence–phosphorescence dual-emissive Cu 3 (pyrazolate) 3 complex with highly tunable emission colours for anticounterfeiting and temperature sensing18Site-Recognition-Induced Structural and Photoluminescent Evolution of the Gold–Pincer Nanocluster48Advances in near-infrared circularly polarized luminescence with organometallic and small organic molecules44Dynamic Near‐Infrared Circularly Polarized Luminescence Encoded by Transient Supramolecular Chiral Assemblies70Dynamic Near‐Infrared Circularly Polarized Luminescence Encoded by Transient Supramolecular Chiral Assemblies10Chlorella filled poly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blend bio-composites compatible with additive manufacturing processes: Fluorescent and anti-counterfeiting QR codes applications7Three-Component Construction of Mesoporous Metal–Organic Frameworks and Their Incorporation into Solid Polymer Electrolytes for Li-Ion Conduction11Recent advances of organic near-infrared circularly polarized luminescent materials0Rational Design of 3D Space Connected Donor–Acceptor System in Covalent Organic Frameworks for Enhanced Photocatalytic Performance104Circularly Polarized Luminescent Liquid Crystal Copolymers Constructed by Triplet–Singlet Förster‐Resonance Energy Transfer: Achieving Large Glum Values, Long Lifetime, and High Photoluminescence Quantum Yield10Concentration‐Switchable Assembly of Carbon Dots for Circularly Polarized Luminescent Amplification in Chiral Logic Gates and Deep‐Red Light‐Emitting Diodes79Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption47Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption5Ligand-to-ligand charge transfer in anthracene-based cyclic trinuclear complexes for enhancing photocatalytic deprotection of Weinreb amides4Photo-responsive near-infrared circularly polarized luminescent liquid crystal copolymers2Aurophilic interaction-based aggregation of gem-digold(I) aryls towards high spin-orbit coupling and strong phosphorescence15High-temperature RGB ultralong afterglow carbon dots based on cavity encapsulated by cyclodextrins for anti-counterfeiting and information encryption18Thermally Activated Delayed Fluorescence-Based Near-Infrared-II Luminescence and Controlled Size Growth of Silver Nanoclusters39Tunable Circularly Polarized Luminescence from Polyether‐Based Liquid Crystalline Polymer1Recoverable and Sensitive Pressure-Induced Mechanochromic Photoluminescence of a Au-P Complex1Assembling Octahedral Pt 2 Ag 4 Clusters for High‐Efficiency Circularly Polarized Luminescence22Effective Near-Infrared Triplet Emitter Based on Hetero-Metal–Metal Interaction13Structure and chiroptical properties of platinum(II) complexes with chiral BINOL ligands0Circularly Polarized Luminescence in Chiral Materials: Navigating Trade‐Offs between Luminescence Dissymmetry Factor and Photoluminescence Quantum Yield37Mechanochemically Induced Circularly Polarized Luminescence from Polymers12[n]Helicenes with Red to Near‐Infrared (NIR) Emissions and Circularly Polarized Luminescence6Chiral Bisammonium-Directed Living Crystallization-Driven Self-Assembly Toward the Preparation of Nanostructures with Controlled Dimensions and Tunable Chiroptical Properties5Harnessing metal-metal interaction for NIR phosphorescence2Solvent-mediated chirality inversion in orthogonal hierarchical assembly of achiral carbene-anchored gold cluster1A chiral dinuclear Pt( ii ) double-helical macrocycle: circularly polarized phosphorescence in polymer matrices0Simultaneously Achieving Efficient Narrow‐Band Emission and Large Emission Dissymmetry Factor in an Achiral Hybrid Indium Chloride2Homochiral Indium‐Oxo Clusters With Multichromatic Circularly Polarized Luminescence1Dual-mode dynamic phosphorescence modulation in bifunctional ligand-stabilized copper clusters for information encryption1Stoichiometry-Driven Polymorphism of ( Au 3 Pz 3 ) 2 Ag Sandwich Clusters Enables Packing-Controlled Photoluminescence0Thermally Activated Delayed Fluorescence (TADF) in Coinage Metal Nanoclusters: Bridging Molecular and Nanoscopic Photophysics0

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  1. Luminescent heterobimetallic Au(I)/Ag(I) complex stabilized by a unique acetylide fragment: A spectroscopic and computational study of aurophilic ‒ argentophilic interactions

    Journal of Molecular Structure · 2023-10-09

    Rais Ahmad Khan, Mohammed Jaafar, Hadi D. Arman, Ali Alsalme

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  2. Visible-light excitable thermally activated delayed fluorescence from hydrogen-bonded D-A aromatic N-heterocycle/polymer material and the application for anti-counterfeiting

    Dyes and Pigments · 2023-12-28

    Jiamei Zhang, Wei Zhou, Yang Li, Wenwen Qu, Yimei Yao, Taiping Lu, Shaolin Lu, Xudong Chen

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  3. A fluorescence–phosphorescence dual-emissive Cu 3 (pyrazolate) 3 complex with highly tunable emission colours for anticounterfeiting and temperature sensing

    Inorganic Chemistry Frontiers · 2024-01-01

    Ze-Miao Xiao, Jing-Xuan Yang, Xu Chen, Wen-Jing Tang, Su‐Kao Peng, De‐Bo Hao, Ze-Peng Zhao, Ji Min Zheng, Dan Li

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  4. Site-Recognition-Induced Structural and Photoluminescent Evolution of the Gold–Pincer Nanocluster

    Journal of the American Chemical Society · 2024-03-26

    Ying Zhang, Wei Zhang, Tai-Song Zhang, Chao Ge, Yang Tao, Wenwen Fei, Weigang Fan, Meng Ran Zhou, Man‐Bo Li

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  5. Advances in near-infrared circularly polarized luminescence with organometallic and small organic molecules

    Materials Today · 2024-05-09

    Ning Liang, Cong Cao, Zeling Xie, Jianxun Liu, Yansong Feng, Chang‐Jiang Yao

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  6. Dynamic Near‐Infrared Circularly Polarized Luminescence Encoded by Transient Supramolecular Chiral Assemblies

    Angewandte Chemie International Edition · 2024-05-13

    Qian Wang, Hanren Xu, Zhen Qi, Ju Mei, Ju Mei, He Tian, Da‐Hui Qu

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  7. Dynamic Near‐Infrared Circularly Polarized Luminescence Encoded by Transient Supramolecular Chiral Assemblies

    Angewandte Chemie · 2024-05-13

    Qian Wang, Hanren Xu, Zhen Qi, Ju Mei, He Tian, Da‐Hui Qu

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  8. Chlorella filled poly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blend bio-composites compatible with additive manufacturing processes: Fluorescent and anti-counterfeiting QR codes applications

    International Journal of Biological Macromolecules · 2024-05-15

    Xinshu Xia, Yan Li, Zhen Liu, Songwei Yang, Changlin Cao, Weiming Zhou, Qinghua Chen, Liren Xiao, Qingrong Qian

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  9. Three-Component Construction of Mesoporous Metal–Organic Frameworks and Their Incorporation into Solid Polymer Electrolytes for Li-Ion Conduction

    Inorganic Chemistry · 2024-05-27

    Qingqing Li, Qingqing Li, Yu Yan, Zhongwen Jiang, Tianhao Chen, Qiaowei Li, Qiaowei Li

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  10. Recent advances of organic near-infrared circularly polarized luminescent materials

    Scientia Sinica Chimica · 2024-07-25

    Jianxun Liu, Ning Liang, Yansong Feng, Chang‐Jiang Yao

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  11. Rational Design of 3D Space Connected Donor–Acceptor System in Covalent Organic Frameworks for Enhanced Photocatalytic Performance

    Advanced Functional Materials · 2024-08-27

    Yinghui Xie, Fengyi Mao, Qiuyu Rong, Xiaolu Liu, Mengjie Hao, Zhongshan Chen, Hui Ying Yang, Geoffrey I. N. Waterhouse, Shengqian Ma, Xiangke Wang

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  12. Circularly Polarized Luminescent Liquid Crystal Copolymers Constructed by Triplet–Singlet Förster‐Resonance Energy Transfer: Achieving Large Glum Values, Long Lifetime, and High Photoluminescence Quantum Yield

    Advanced Optical Materials · 2024-08-28

    Mengdie Zhou, Peng Lu, Zhipeng Xu, Yuyi Wang, Yongjie Yuan, Yongyang Gong, Hailiang Zhang

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  13. Concentration‐Switchable Assembly of Carbon Dots for Circularly Polarized Luminescent Amplification in Chiral Logic Gates and Deep‐Red Light‐Emitting Diodes

    Advanced Materials · 2024-10-03

    Lin Ai, Haolin Wang, Boyang Wang, S.Y Liu, Haoqiang Song, Siyu Lu

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  14. Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption

    Angewandte Chemie International Edition · 2024-10-07

    Bowen Yang, Xuefeng Yang, Yonghong Shi, Xue Jin, Tiesheng Li, Minghua Liu, Pengfei Duan

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  15. Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption

    Angewandte Chemie · 2024-10-07

    Bowen Yang, Xuefeng Yang, Yonghong Shi, Xue Jin, Tiesheng Li, Minghua Liu, Pengfei Duan

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  16. Ligand-to-ligand charge transfer in anthracene-based cyclic trinuclear complexes for enhancing photocatalytic deprotection of Weinreb amides

    Inorganic Chemistry Frontiers · 2025-01-01

    Yun-Zhou Guo, Hui-Zhi Wei, Xu-Hang Zhong, Cui-Zhou Luan, Rui Zhou, Bingzhe Wang, Ji Min Zheng, Shang‐Fu Yuan, Tao Wu, Dan Li

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  17. Photo-responsive near-infrared circularly polarized luminescent liquid crystal copolymers

    Journal of Materials Chemistry C · 2025-01-01

    Yongjie Hu, Mengdie Zhou, Xincan Wang, Qin Gui, Yongjie Yuan, Hailiang Zhang

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  18. Aurophilic interaction-based aggregation of gem-digold(I) aryls towards high spin-orbit coupling and strong phosphorescence

    Nature Communications · 2025-01-06

    Xiaoyi Zhai, Liang Zhao

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  19. High-temperature RGB ultralong afterglow carbon dots based on cavity encapsulated by cyclodextrins for anti-counterfeiting and information encryption

    Journal of Colloid and Interface Science · 2025-02-07

    Bingyan Han, Chunyang Guo, Fengdi Wang, Jiao Wang, Haiyan Liu, Gaohong He

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  20. Thermally Activated Delayed Fluorescence-Based Near-Infrared-II Luminescence and Controlled Size Growth of Silver Nanoclusters

    ACS Nano · 2025-02-12

    Wenhui Jiang, Xiang-Ming Zeng, Minjian Wu, Qin Lin, Liao‐Yuan Yao, Guo‐Yu Yang

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  21. Tunable Circularly Polarized Luminescence from Polyether‐Based Liquid Crystalline Polymer

    Macromolecular Chemistry and Physics · 2025-04-14

    Yi Chen, Zhizhuang Li, Yan Guan, Jiang Huang, Jie Li, Jiawei Qi, Mengwei Wu, Heng Li, He‐Lou Xie

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  22. Recoverable and Sensitive Pressure-Induced Mechanochromic Photoluminescence of a Au-P Complex

    Molecules · 2025-04-30

    Ningwen Yang, Yijia Chang, Jiangyue Wang, David James Young, Hong‐Xi Li, Yuxin Lu, Zhi‐Gang Ren

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  23. Assembling Octahedral Pt 2 Ag 4 Clusters for High‐Efficiency Circularly Polarized Luminescence

    Advanced Materials · 2025-05-06

    Miao‐Miao Zhang, Ran Zhang, Shi‐Yu Yang, Xi‐Yan Dong, Chong Zhang, Yubing Si, Teng Jia, Zhen Han, Shuang‐Quan Zang, Thomas C. W. Mak

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  24. Effective Near-Infrared Triplet Emitter Based on Hetero-Metal–Metal Interaction

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  25. Structure and chiroptical properties of platinum(II) complexes with chiral BINOL ligands

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  26. Circularly Polarized Luminescence in Chiral Materials: Navigating Trade‐Offs between Luminescence Dissymmetry Factor and Photoluminescence Quantum Yield

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  27. Mechanochemically Induced Circularly Polarized Luminescence from Polymers

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  28. [n]Helicenes with Red to Near‐Infrared (NIR) Emissions and Circularly Polarized Luminescence

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  29. Chiral Bisammonium-Directed Living Crystallization-Driven Self-Assembly Toward the Preparation of Nanostructures with Controlled Dimensions and Tunable Chiroptical Properties

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  30. Harnessing metal-metal interaction for NIR phosphorescence

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  31. Solvent-mediated chirality inversion in orthogonal hierarchical assembly of achiral carbene-anchored gold cluster

    Nature Communications · 2025-11-26

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  32. A chiral dinuclear Pt( ii ) double-helical macrocycle: circularly polarized phosphorescence in polymer matrices

    Journal of Materials Chemistry C · 2026-01-01

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  33. Simultaneously Achieving Efficient Narrow‐Band Emission and Large Emission Dissymmetry Factor in an Achiral Hybrid Indium Chloride

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  34. Homochiral Indium‐Oxo Clusters With Multichromatic Circularly Polarized Luminescence

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  35. Dual-mode dynamic phosphorescence modulation in bifunctional ligand-stabilized copper clusters for information encryption

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  36. Stoichiometry-Driven Polymorphism of ( Au 3 Pz 3 ) 2 Ag Sandwich Clusters Enables Packing-Controlled Photoluminescence

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