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RESEARCH PAPER · Accounts of Chemical Research · 2024

Superlattice Assembly for Empowering Metal Nanoclusters

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Superlattice Assembly for Empowering Metal NanoclustersOriginalHelical self-assemblies of molecule-like coinage metal nanoclusters and their emerging applications13Atomically precise large-sized Au n (SR) m nanoclusters and scaling relationships among size, bandgap and excited-state lifetime8Designing atomically precise gold nanocluster architectures with DNA-guided self-assembly and biofunctionalization approaches6Synthesis of Au 13 -based building block clusters for programmed dimer formation and Au 13 cluster dimer photoexcitation properties3Synthesis planning for atomically precise metal nanoclusters8Ligand‐Mediated Highly Ordered Aggregation of 5‐Mercapto‐2‐Nitrobenzoic Acid Protected Atomically Precise Silver Nanocluster8One-Step Solvothermal Synthesis of Carbon Dots for Rapid and Accurate Determination of Hemin Content8Confining metal nanoparticles and nanoclusters in covalent organic frameworks for biosensing and biomedicine13Surface Structural Symmetry Breaking of Highly Symmetrical Ag29 Nanoclusters0Nanocluster-based aggregates: Assembled forms, driving forces, and structure-related properties25All‐ N ‐Heterocyclic‐Carbene Protected Superatomic Ag 8 Cluster5All‐ N ‐Heterocyclic‐Carbene Protected Superatomic Ag 8 Cluster0A Phosphorescent Silver-Copper Nanocluster with a Saddle-Like Stabilizing Surface0Self-Assembled siRNA-Gold Supraclusters Detected at the Single-Molecule Level in the NIR-II Window0Cross-scale construction of photothermal synergistic catalytic systems: Mechanistic insights from single atoms, clusters to nanoparticles and energy conversion applications35Synthesis and Properties of Iron Clusters and Their Practical Applications in Carbon Nanotube Growth1Crystallization-induced emission enhancement of copper iodide cluster for efficient X‑ray scintillation and dynamic imaging7Chiral Tin‐Oxo Cluster Matrices with Fluorophore Embedment for Multichromatic Circularly Polarized Luminescence3Chiral Tin‐Oxo Cluster Matrices with Fluorophore Embedment for Multichromatic Circularly Polarized Luminescence7Tuning the Electrical Properties through Metal-Ion-Mediated Assembly in Au25 Nanocluster-Based Frameworks9Precise Surface Engineering of Metal Nanoclusters: Ligand Programming for Functionality Design65High-Yield Synthesis of Cu29 Nanoclusters and Their Applications in Photothermal Conversion and Catalysis12Recent advances in targeted fluorescence regulation of metal nanoclusters for food hazard analysis: Hybridization strategies, theoretical insights, and applications1Self‐Assembled Small Interfering RNA‐Gold Supraclusters Detected at the Single‐Molecule Level in the Near‐Infrared‐II Window3Chiral assembly of atomically precise metal nanoclusters11Mortise-and-tenon joints enable isomorphic nanocluster superstructures: Ethyl groups as locking pins for benchmark photocatalytic H 2 O 2 production3Organic-Modulated Inorganic Catalysts: Interactions, Structures, and Applications in Heterogeneous Catalytic Reactions2Aggregation-induced structural clamping drives NIR photoluminescence switching in Au 2 Cu 6 nanoclusters by suppressing El-Sayed-allowed intersystem crossing0Cluster-based materials: design and applications5Hierarchical graphene quantum dot–copper nanocluster superstructures: synergistic assembly for optical limiting applications0Stepwise assembly of rhombic Cu 2 building blocks enables the construction of dimension-tunable luminescent copper nanoclusters0Inverse palladocenes2Molecular-Level Decoding of Electron Transfer Dynamics in Metal Nanoclusters16Plasmonic resonance coupling in a heterogeneous ML-MoS₂/Au nanoarray for ultrasensitive SERS-based glucose detection1Ion Mobility–Mass Spectrometry: A Powerful Platform for Structural Characterization of Metal Nanoclusters0Structurally Resolved Water-Soluble Copper Nanoclusters with NIR TADF Exhibiting Multifunctional Catalytic Activity1Solvent- and Cation-Controlled Aggregation-Induced Emission of Thiolate-Protected Cu Nanoclusters0Lighting up Metal Nanoclusters as Promising Molecular Emitters1Synthesis of Luminescent Metal Nanoclusters with Atomically Precise Structures and High Quantum Yields0Metal Nanoclusters: Structure Design, Enzymatic Activity, and Biomedical Applications0Ion-Mediated Configuration Regulation and Chiralization in Cu(I) Cluster-Based Metallic Cages0Thermally Activated Delayed Fluorescence (TADF) in Coinage Metal Nanoclusters: Bridging Molecular and Nanoscopic Photophysics0Hydrogen-Bonding Assembly of Monolayer Metallic Silver Nanocluster Superlattices Improving Guest Fluorescence0High-energy-density copper nanoclusters enabled by synergistic carborane and pyrazolate ligands0Conducting Flexible Single Crystalline Silver Nanocluster Chain0Heavier Counterparts for Phosphine-Protected Gold Clusters. Electronic, Bonding, and Optical Properties of Au13Cl2(L5) and Au13(L6) Superatoms0

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  1. Helical self-assemblies of molecule-like coinage metal nanoclusters and their emerging applications

    Coordination Chemistry Reviews · 2024-11-25

    Subrat Kumar Barik, M. Sreejit Kumar Rao, Bigyan Ranjan Jali, Jean‐François Halet, Himanshu Sekhar Jena

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  2. Atomically precise large-sized Au n (SR) m nanoclusters and scaling relationships among size, bandgap and excited-state lifetime

    Nanoscale · 2025-01-01

    Xiang‐Sha Du, Tatsuya Higaki, Hedi Ma, Xinwen Zhang, Gangli Wang, He Wang, Rongchao M. Jin

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  3. Designing atomically precise gold nanocluster architectures with DNA-guided self-assembly and biofunctionalization approaches

    Nanoscale · 2025-01-01

    Abdallah Alhalabi, Christine Saint‐Pierre, Elisabetta Boeri Erba, Pierre‐Henri Elchinger, Harinderbir Kaur, Didier Gasparutto, Xavier Le Guével

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  4. Synthesis of Au 13 -based building block clusters for programmed dimer formation and Au 13 cluster dimer photoexcitation properties

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    Taiga Kosaka, Yoshiki Niihori, Tokuhisa Kawawaki, Yuichi Negishi

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  5. Synthesis planning for atomically precise metal nanoclusters

    Nanoscale Horizons · 2025-01-01

    Jingkuan Lyu, Jing Qian, Zhucheng Yang, Jianping Xie

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  6. Ligand‐Mediated Highly Ordered Aggregation of 5‐Mercapto‐2‐Nitrobenzoic Acid Protected Atomically Precise Silver Nanocluster

    Small · 2025-02-07

    Soumyadip Roy, Vikas Tiwari, Tarak Karmakar, Indranath Chakraborty

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  7. One-Step Solvothermal Synthesis of Carbon Dots for Rapid and Accurate Determination of Hemin Content

    Molecules · 2025-03-17

    Yiaobo Zhang, Lin Liu, Jiahui He, Chengzhi Huang, Lei Zhan, Chun Mei Li

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  8. Confining metal nanoparticles and nanoclusters in covalent organic frameworks for biosensing and biomedicine

    Biosensors and Bioelectronics · 2025-04-08

    Jianxin Ma, Zhongjie Cai, Faisal Ahmad, Ye-Lan Xiao, Tong Shu, Xueji Zhang

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  9. Surface Structural Symmetry Breaking of Highly Symmetrical Ag29 Nanoclusters

    The Journal of Physical Chemistry Letters · 2025-04-17

    Wenqiang Duan, Chen X. Zhu, Xi Kang, Manzhou Zhu

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  10. Nanocluster-based aggregates: Assembled forms, driving forces, and structure-related properties

    Coordination Chemistry Reviews · 2025-04-30

    Hao Li, Xi Kang, Manzhou Zhu

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  11. All‐ N ‐Heterocyclic‐Carbene Protected Superatomic Ag 8 Cluster

    Angewandte Chemie International Edition · 2025-05-27

    Li‐Ying Sun, Fang Wang, Yuan Shui, Tao Yang, Ying‐Feng Han

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  12. All‐ N ‐Heterocyclic‐Carbene Protected Superatomic Ag 8 Cluster

    Angewandte Chemie · 2025-05-27

    Li‐Ying Sun, Wang Fang, Yuan Shui, Tao Yang, Ying-Feng Han

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  13. A Phosphorescent Silver-Copper Nanocluster with a Saddle-Like Stabilizing Surface

    Journal of Cluster Science · 2025-06-02

    Fei Li, Zhu Chen, Luyao Lu, Mingshuai Yu, Xi Kang, Manzhou Zhu

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  14. Self-Assembled siRNA-Gold Supraclusters Detected at the Single-Molecule Level in the NIR-II Window

    bioRxiv (Cold Spring Harbor Laboratory) · 2025-06-03

    Zeineb Ayed, Blanca Martín Muñoz, Catharina I. Vandekerckhove, Virginie Faure, Syed Nafis Shadman Ali, Jean‐Luc Coll, Laurent Cognet, Xavier Le Guével

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  15. Cross-scale construction of photothermal synergistic catalytic systems: Mechanistic insights from single atoms, clusters to nanoparticles and energy conversion applications

    Applied Catalysis B: Environmental · 2025-06-23

    Hongbin He, Yuqi Ren, Shengnan Lan, Hongyang Zhang, Yuan‐Hao Zhu, Ruoxuan Peng, Jiancheng Zhou, Maochang Liu, Yitao Si, Dengwei Jing, Naixu Li

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  16. Synthesis and Properties of Iron Clusters and Their Practical Applications in Carbon Nanotube Growth

    ChemistrySelect · 2025-07-01

    Weiqiang Wei, Ya Xu, Zihan Wang, Chunyang Li, Huifang Li, Changqing Chu, Yan He, Lisheng Zhang

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  17. Crystallization-induced emission enhancement of copper iodide cluster for efficient X‑ray scintillation and dynamic imaging

    Chinese Chemical Letters · 2025-07-03

    Haonan Qin, Hao Xie, Jia‐Wang Yuan, Ren‐Wu Huang, Zhao‐Yang Wang, Shuang‐Quan Zang

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  18. Chiral Tin‐Oxo Cluster Matrices with Fluorophore Embedment for Multichromatic Circularly Polarized Luminescence

    Angewandte Chemie · 2025-07-15

    Gui‐Xin Yan, Er‐Xia Chen, Jin‐Xia Yang, Jian Zhang, Qipu Lin

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  19. Chiral Tin‐Oxo Cluster Matrices with Fluorophore Embedment for Multichromatic Circularly Polarized Luminescence

    Angewandte Chemie International Edition · 2025-07-15

    Gui‐Xin Yan, Er‐Xia Chen, Jin‐Xia Yang, Jian Zhang, Qipu Lin

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  20. Tuning the Electrical Properties through Metal-Ion-Mediated Assembly in Au25 Nanocluster-Based Frameworks

    Journal of the American Chemical Society · 2025-08-12

    Sinhyeop Kim, Hanna Jääskö, Kyoung Chul Park, Sami Malola, Hannu Häkkinen, Sarah S. Park

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  21. Precise Surface Engineering of Metal Nanoclusters: Ligand Programming for Functionality Design

    Advanced Materials · 2025-08-13

    Zhucheng Yang, Yifan Wang, Ruixuan Zhang, Tiankai Chen, Jianping Xie

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  22. High-Yield Synthesis of Cu29 Nanoclusters and Their Applications in Photothermal Conversion and Catalysis

    Inorganic Chemistry · 2025-08-22

    Avirup Sardar, Yitong Wang, Abhrojyoti Mazumder, Guiying He, Christopher G. Gianopoulos, Kristin Kirschbaum, Rongchao M. Jin

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  23. Recent advances in targeted fluorescence regulation of metal nanoclusters for food hazard analysis: Hybridization strategies, theoretical insights, and applications

    Food Chemistry · 2025-08-26

    Xinyue Zhang, Yuandong Lin, Wenhong Gao, Jun‐Hu Cheng

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  24. Self‐Assembled Small Interfering RNA‐Gold Supraclusters Detected at the Single‐Molecule Level in the Near‐Infrared‐II Window

    Small Structures · 2025-09-02

    Zeineb Ayed, Blanca Martín Muñoz, Catharina I. Vandekerckhove, Virginie Faure, Syed Nafis Shadman Ali, Jean‐Luc Coll, Laurent Cognet, Xavier Le Guével

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  25. Chiral assembly of atomically precise metal nanoclusters

    Coordination Chemistry Reviews · 2025-10-09

    Wenjun Du, Lirong Jiang, Shan Jin, Manzhou Zhu

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  26. Mortise-and-tenon joints enable isomorphic nanocluster superstructures: Ethyl groups as locking pins for benchmark photocatalytic H 2 O 2 production

    Nano Research · 2025-11-04

    Yifan Wu, Ruyu Zhang, Shengchang Xiang, Xi Fan, Zhangjing Zhang

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  27. Organic-Modulated Inorganic Catalysts: Interactions, Structures, and Applications in Heterogeneous Catalytic Reactions

    ACS Catalysis · 2025-12-19

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  28. Aggregation-induced structural clamping drives NIR photoluminescence switching in Au 2 Cu 6 nanoclusters by suppressing El-Sayed-allowed intersystem crossing

    Chemical Communications · 2026-01-01

    Hayato Yamauchi, Daichi Arima, Masaaki Mitsui

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  29. Cluster-based materials: design and applications

    Chemical Society Reviews · 2026-01-01

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  30. Hierarchical graphene quantum dot–copper nanocluster superstructures: synergistic assembly for optical limiting applications

    Journal of Materials Chemistry C · 2026-01-01

    Fadeela Chundekatt Ummer, Mallikarjun H. Anandalli, Parvathy Nancy, Nandakumar Kalarikkal

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  31. Stepwise assembly of rhombic Cu 2 building blocks enables the construction of dimension-tunable luminescent copper nanoclusters

    Nanoscale · 2026-01-01

    Hao Tian, Ying Xu, Ningjing Si, Hao Li, Xi Kang, Manzhou Zhu

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  32. Inverse palladocenes

    Nature Communications · 2026-01-30

    Qing You, Xue-Lian Jiang, Yan Zhao, Wanmiao Gu, Jun Li, Zhikun Wu

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  33. Molecular-Level Decoding of Electron Transfer Dynamics in Metal Nanoclusters

    Accounts of Chemical Research · 2026-02-11

    Kai‐Yuan Huang, Qiaofeng Yao, Hao‐Hua Deng, Wei Chen, Jinghe Xie

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  34. Plasmonic resonance coupling in a heterogeneous ML-MoS₂/Au nanoarray for ultrasensitive SERS-based glucose detection

    Sensors and Actuators A Physical · 2026-03-12

    Yingjiao Zhai, Junjie Yu, Xuanyu Chen, Fujun Liu

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  35. Ion Mobility–Mass Spectrometry: A Powerful Platform for Structural Characterization of Metal Nanoclusters

    Analytical Chemistry · 2026-03-19

    Longbo Zhang, Longbo Zhang, Lili Zhang, Lili Zhang, Xiaoyan Sun

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  36. Structurally Resolved Water-Soluble Copper Nanoclusters with NIR TADF Exhibiting Multifunctional Catalytic Activity

    The Journal of Physical Chemistry Letters · 2026-06-16

    Sameeksha Agrawal, Thrisha Swaminathan, Sanyam, Koushik Mandal, Deepak Chopra, Anirban Mondal, Saptarshi Mukherjee

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  37. Solvent- and Cation-Controlled Aggregation-Induced Emission of Thiolate-Protected Cu Nanoclusters

    The Journal of Physical Chemistry C · 2026-06-29

    Sikta Chakraborty, Sarita Kolay, Sanchita Paramanik, Amitava Patra

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  38. Lighting up Metal Nanoclusters as Promising Molecular Emitters

    Advanced Materials · 2026-08-04

    Ruixuan Zhang, Zhucheng Yang, Tiankai Chen, Jianping Xie

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  39. Synthesis of Luminescent Metal Nanoclusters with Atomically Precise Structures and High Quantum Yields

    Royal Society of Chemistry eBooks · 2026-08-05

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  40. Metal Nanoclusters: Structure Design, Enzymatic Activity, and Biomedical Applications

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  41. Ion-Mediated Configuration Regulation and Chiralization in Cu(I) Cluster-Based Metallic Cages

    Journal of the American Chemical Society · 2026-09-09

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  42. Thermally Activated Delayed Fluorescence (TADF) in Coinage Metal Nanoclusters: Bridging Molecular and Nanoscopic Photophysics

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  43. Hydrogen-Bonding Assembly of Monolayer Metallic Silver Nanocluster Superlattices Improving Guest Fluorescence

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    Hui-na Liao, Qi Dai, Nian-Ling Li, Jing-Hao Zhuang, Pei-Juan Dai, Xi Chen, Quan‐Ming Wang, Xian‐Kai Wan

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  44. High-energy-density copper nanoclusters enabled by synergistic carborane and pyrazolate ligands

    Chemical Engineering Journal · 2026-10-01

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  45. Conducting Flexible Single Crystalline Silver Nanocluster Chain

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  46. Heavier Counterparts for Phosphine-Protected Gold Clusters. Electronic, Bonding, and Optical Properties of Au13Cl2(L5) and Au13(L6) Superatoms

    The Journal of Physical Chemistry Letters · 2026-10-06

    Alvaro Rafael Muñoz-Castro

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