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RESEARCH PAPER · Matter · 2021

Chiral halide perovskite crystals for optoelectronic applications

Yangyang Dang, Xiaolong Liu, Bingqiang Cao, Xutang Tao

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Chiral halide perovskite crystals for optoelectronic applicationsOriginalRecent Progress on Two-Dimensional Materials472Spin selectivity in chiral metal–halide semiconductors40Using post-synthetic ligand modification to imprint chirality onto the electronic states of cesium lead bromide (CsPbBr 3 ) perovskite nanoparticles44Recent Progress of Chiral Perovskites: Materials, Synthesis, and Properties311Germanium‐Based Halide Perovskites: Materials, Properties, and Applications174Chirality‐Dependent Second‐Order Nonlinear Optical Effect in 1D Organic–Inorganic Hybrid Perovskite Bulk Single Crystal245Chirality‐Dependent Second‐Order Nonlinear Optical Effect in 1D Organic–Inorganic Hybrid Perovskite Bulk Single Crystal18Stimuli-responsive switchable halide perovskites: Taking advantage of instability98Layered Metal‐Halide Perovskite Single‐Crystalline Microwire Arrays for Anisotropic Nonlinear Optics62Organic Chiral Spin‐Optics: The Interaction between Spin and Photon in Organic Chiral Materials40Optically active luminescent nanocrystals complexed with chiral silica nanoribbons0Crystal structure and semiconductor properties of copper(II) complex incorporating chiral (R)-(+)-α-Ethylbenzylammonium cations:[(R)-C9H14N]3[CuBr4].Br.18Full‐Stokes Polarimeter Based on Chiral Perovskites with Chirality and Large Optical Anisotropy671D Chiral Lead Halide Perovskites with Superior Second‐Order Optical Nonlinearity100Alkyl–Aryl Cation Mixing in Chiral 2D Perovskites137Chiral 1D perovskite microwire arrays for circularly polarized light detection34Chiral hybrid organic-inorganic metal halides: A route toward direct detection and emission of polarized light58A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8Air-grown hybrid copper( i ) halide single crystals: structural transformations and ultraviolet-pumped photoluminescence applications36Impact of crystal growth diversity on magneto-photoluminescence and circular dichroism in chiral lead halide perovskites15Spin-polarized excitons and charge carriers in chiral metal halide semiconductors23The light of carbon dots: From mechanism to applications974Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window112Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window13Advances in single crystals and thin films of chiral hybrid metal halides38The synthesis, structures, high thermal stability and photoluminescence of two new crown ether clathrates7Rationalizing the design and implementation of chiral hybrid perovskites129Organic–Inorganic Hybrid Tin Halide Single Crystals with Sulfhydryl and Hydroxyl Groups: Formation, Optical Properties, and Stability6Tunable and Large Magneto‐Photoluminescence for Single‐Crystalline Chiral Perovskites19Polar Photovoltaic Effect in Chiral Alternating Cations Intercalation‐Type Perovskites Driving Self‐Powered Ultraviolet Circularly Polarized Light Detection55Reversible phase transition for switchable second harmonic generation in 2D perovskite microwires34Strong In‐Plane Anisotropy and Giant Second Harmonic Generation Response of Organic Single‐Crystalline Microwire Arrays14Control of light, spin and charge with chiral metal halide semiconductors202Leveraging Hierarchical Chirality in Perovskite(‐Inspired) Halides for Transformative Device Applications40Chiral Perovskite Nanoplatelets Exhibiting Circularly Polarized Luminescence through Ligand Optimization41Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging99Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging29Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals85Recent progress of bulk photovoltaic effect in acentric single crystals and optoelectronic devices62Induction of Chiral Hybrid Metal Halides from Achiral Building Blocks103Chiral Rashba Ferroelectrics for Circularly Polarized Light Detection173Structural, elastic, electronic and optical properties of double perovskites Ba2NaXO6 (X = Cl, Br, I): First-principles study27A chiral lead-free tin(IV)-based halide organic-inorganic semiconductor with dielectric switching and phase transition44Spin Selectivity in Chiral Hybrid Cobalt Halide Films with Ultrasmooth Surface27Full‐Color Circularly Polarized Luminescence of CsPbX 3 Nanocrystals Triggered by Chiral Carbon Dots103Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO48Enabling Efficient Blue‐Emissive Circularly Polarized Luminescence by In Situ Crafting of Chiral Quasi‐2D Perovskite Nanosheets within Polymer Nanofibers59Origin of high piezoelectricity of a bismuth-based organic–inorganic hybrid crystal14Spacer Cation Alloying Enables Markedly Improved Chiroptical Properties of Two‐Dimensional Chiral Hybrid Perovskite Nanosheets37A photoluminescent chiral lead-free hybrid ferroelastic semiconductor with switchable second-harmonic generation23Chiral-induced spin selectivity in biomolecules, hybrid organic–inorganic perovskites and inorganic materials: a comprehensive review on recent progress54Construction of chiral-2D/3D perovskite heterojunction films for efficient circularly polarized light detection22Linear optical afterglow and nonlinear optical harmonic generation from chiral tin( iv ) halides: the role of lattice distortions37Strong anisotropic second-order nonlinear optical responses in 0D lead-free chiral perovskite single-crystalline microwire arrays21Structural diversity in proline-based lead bromide chiral perovskites11Two-dimensional lead-free silver-bismuth double perovskite nanobelts with intrinsic chirality via co-antisolvent modulation strategy4Strong circularly polarized luminescence from quantum dots/2D chiral perovskites composites29Resonant Second Harmonic Generation in Proline Hybrid Lead Halide Perovskites56Solvent Modulation of Chiral Perovskite Films Enables High Circularly Polarized Luminescence Performance from Chiral Perovskite/Quantum Dot Composites44Cascade Chirality Transfer Through Diastereomeric Interaction Enables Efficient Circularly Polarized Electroluminescence30Chirality–Racemization Strategy Toward Copper (I) Iodide Hybrid Single‐Crystalline Scintillators for X‐Ray Detection and Imaging Applications44Experimental and Theoretical Studies of Magnetic Circular Dichroism for Chiral Lead Halide Perovskites41Symmetry-Broken 2D Lead–Tin Mixed Chiral Perovskite for High Asymmetry Factor Circularly Polarized Light Detection93Inversion of Molecular Chirality Associated with Ferroelectric Switching in a High-Temperature Two-Dimensional Perovskite Ferroelectric88Research progress in optical activities and nonlinear optics of chiral perovskites1Optical properties of two-dimensional perovskites9Discovering New Type of Lead‐Free Cluster‐Based Hybrid Double Perovskite Derivatives with Chiral Optical Activities and Low X‐Ray Detection Limit43Bismuth‐Based Chiral Perovskite with Different Dimensions for Second‐Order Nonlinear Optical Properties27Chiral Perovskite Nanocrystal Growth inside Helical Hollow Silica Nanoribbons41Spin Polarization of Chiral Amorphous Fe‐Ni Electrocatalysts Enabling Efficient Electrochemical Oxygen Evolution671D Diisopropylammonium Lead Iodide Perovskite Shows Exceptional Optical Stability and Third‐Order Nonlinearity16Planar Chirality for Acid/Base Responsive Macrocyclic Pillararenes Induced by Amino Acid Derivatives: Molecular Dynamics Simulations and Machine Learning9Inorganic Lead Halide Perovskite Micro-/Nanostructures: From Self-Assembly to Applications4Metal Halide Perovskite Photo-Field-Effect Transistors with Chiral Selectivity24Chiral Hybrid Perovskites (R-/S-CLPEA)4Bi2I10 with Enhanced Chirality and Spin–Orbit Coupling Splitting for Strong Nonlinear Optical Circular Dichroism and Spin Selectivity Effects36The First Enantiomeric Stereogenic Sulfur‐Chiral Organic Ferroelectric Crystals41The First Enantiomeric Stereogenic Sulfur‐Chiral Organic Ferroelectric Crystals0Spin Control and Multifunctional Photocurrent Switch in Chiral Hybrid Organic–Inorganic Perovskites5Multiple Stimuli‐Responsive Luminescent Chiral Hybrid Antimony Chlorides for Anti‐Counterfeiting and Encryption Applications14Multiple Stimuli‐Responsive Luminescent Chiral Hybrid Antimony Chlorides for Anti‐Counterfeiting and Encryption Applications114Multifunctional Perovskite Photodetectors: From Molecular-Scale Crystal Structure Design to Micro/Nano-scale Morphology Manipulation115Achiral Fluorinated Aromatic Ligands Based Chiral Hybrid Antimony Halides with High‐Efficiency Second‐Harmonic Generation18Design of an Ad Hoc Bifunctional Chiral Ligand for the Preparation of Low-Dimensional Perovskites3(R/S-ClMBA)3GeI5: A Novel Low-Dimensional Ge-Containing Chiral Perovskite1Interlayer Polymerization of 2D Chiral Perovskite Single‐Crystal Films toward High‐Performance Flexible Circularly Polarized Light Detection46Spatially Correlated Chirality in Chiral Two-Dimensional Perovskites Revealed by Second-Harmonic-Generation Circular Dichroism Microscopy56Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties114Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties12Chiral Ligand‐Induced Inversion and Tuning of Excitonic Optical Activity in Intrinsically Chiral CsPbBr3 Perovskite Nanoplatelets32Multiple degrees of freedom photoprogramming of soft helical microstructures featuring copper-gated photoswitch28Bulk Photovoltaic Effect in Chiral Layered Hybrid Perovskite Enables Highly Sensitive Near-Infrared Circular Polarization Photodetection33A Wet‐Fusing Assembly Strategy for Forming Low Dark Current 2D/3D Perovskite X‐Ray Detector on a Thin Film Transistor Backplane10Chiral induction and Sb3+ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence22Dielectric Relaxation Mechanism in the Phase-Transition Region of a Chiral Hybrid Perovskite and Its Piezoelectric-Energy-Harvesting Properties23Shapeshifting Nanoplatelets : Inducing Chirality in Ultrathin Systems0A robust 3D self-powered photoelectrochemical type photodetector based on ReS2 nanoflowers4Spin Quantum Dot Light‐Emitting Diodes Enabled by 2D Chiral Perovskite with Spin‐Dependent Carrier Transport83Chiral Carbon Dots and Chiral Carbon Dots with Circularly Polarized Luminescence: Synthesis, Mechanistic Investigation and Applications13An introduction of perovskite materials in chiral metasurfaces11D Chiral Enantiomer Lead-Free Perovskites Induced Chiralopical Activity and Photoelectric Response20Universal Wet‐Chemistry‐Methods Synthesized Novel Halide‐Intercalated Perovskites with Reduced Exciton Confinement for Low‐Dose X‐ray Scintillation Imaging1Metal-free chiral molecular ferroelectric photovoltaics13Chiral‐Achiral Cations Intercalation Induced Lead‐Free Chiral‐Polar Hybrid Perovskites Enable Self‐Powered X‐Ray and Ultraviolet–Visible–Near‐Infrared Photo Detection33Circularly Polarized Light-Dependent Pyro-Phototronic Effect from 2D Chiral–Polar Double Perovskites74Free Halogen Substitution of Chiral Hybrid Metal Halides for Activating the Linear and Nonlinear Chiroptical Properties140Homochirality in Ferroelectrochemistry32Calculating the Circular Dichroism of Chiral Halide Perovskites: A Tight-Binding Approach21In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation11In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation68Chiral zero-dimensional hybrid organic–inorganic metal halides based on nipecotic acid and tetrabromocuprate7Circularly polarized luminescence in quantum dot-based materials42Homochiral hybrid hexagonal antiperovskite crystals [ R - and S -3-chloroquinuclidinium] 3 (CdCl 3 )(CdCl 4 )3Multicolor Chiral Perovskite Nanowire Films with Strong and Taiorable Circularly Polarized Luminescence0The role of halogens in structural diversity and chirality enhancement of 1D chiral hybrid metal halides8Variable energy transfer in one-dimensional chiral Mn/Cd-based halides and strong stereo-selective fluorescence for chiral recognition5Ligand‐Induced Chirality in ClMBA2SnI4 2D Perovskite**38Synthesis and Characterization of Cu-containing Chiral Metal Halides and Role of Halogenation of the Organic Ligand1Ligand‐Induced Chirality in ClMBA2SnI4 2D Perovskite**6Highly Circularly Polarized Light‐Sensitive Chiral One‐Dimensional Perovskites Enabled by Antisolvent Engineering26Chiral Multidentate Ligand Facilitating Perovskite Nanocrystals with Circularly Polarized Luminescence and Chiral Assembly27Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation16Synthesis and Characterization of Cu-Containing Chiral Metal Halides and Role of Halogenation of the Organic Ligand14Chiral photon emission from a chiral–achiral perovskite heterostructure3Efficient Circularly Polarized Luminescence and Bright White Emission from Hybrid Indium‐Based Perovskites via Achiral Building Blocks62Circularly Polarized Luminescence Induced by Hydrogen‐Bonding Networks in a One‐Dimensional Hybrid Manganese(II) Chloride9Circularly Polarized Luminescence Induced by Hydrogen‐Bonding Networks in a One‐Dimensional Hybrid Manganese(II) Chloride87Research Progress on Rashba Effect in Two-Dimensional Organic–Inorganic Hybrid Lead Halide Perovskites9Generation and Enhancement of Chirality-Induced Spin-Polarized Emission in 3D@1D Lead Halide Perovskites4Dimensional and Doping Engineering of Chiral Perovskites with Enhanced Spin Selectivity for Green Emissive Spin Light-Emitting Diodes44Nonlinear Optical Activity of a Chiral Organic–Inorganic ([(NH 3 CH 2 CH 2 ) 3 NH]) 2 [MnBr 5 ]Br 5 Photoluminescent and Piezoelectric Crystal10Giant circular dichroism in all-dielectric planar chiral Meta-GMR4Narrow-Bandgap Tellurium-Based Chiral Hybrid Perovskite Single Crystals with Rashba–Dresselhaus Effect and Piezoelectricity3The Mn2+‐Doped Chiral 2D Perovskite with Strong Orange Fluorescent and Enhanced Circularly Polarized Luminescence5Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials22Collective chiroptical activity through the interplay of excitonic and charge-transfer effects in localized plasmonic fields12Progress on Coherent Perovskites Emitters: From Light‐Emitting Diodes under High Current Density Operation to Laser Diodes2Recent progress on chiral perovskites as chiroptical active layers for next-generation LEDs25Mixed Organic Cation in Chiral Two-Dimensional Organic–Inorganic Hybrid Metal Halides─An Ab Initio Study of Nonlinear Optical (NLO) Properties9Obtaining, Structure, and Optical and Electrical Properties of Chiral Perovskites: A Review4Chiral Templating in a Hybrid Chromium Chloride Hydrate2Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal2l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation14Unraveling the Role of Structural Topology on Chirality Transfer and Chiroptical Properties in Chiral Germanium Iodides31CPL-active hybrid copper(I) halides enabled by cation inclusion with chiral crown-ether11Energy transfer-based X-ray imaging scintillators74Chiral Ionic Liquids Enable High‐Performance Room Temperature Single Junction Spin‐Light Emitting Diodes21Histidine-based hybrid perovskites as promising materials for wide wavelength photodetection3Organic Circularly Polarized Room‐Temperature Phosphorescence: Strategies, Applications and Challenges8Halogen-Dependent Circular Dichroism and Magneto-Photoluminescence Effects in Chiral 2D Lead Halide Perovskites9Organic Circularly Polarized Room‐Temperature Phosphorescence: Strategies, Applications and Challenges56

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  6. Chirality‐Dependent Second‐Order Nonlinear Optical Effect in 1D Organic–Inorganic Hybrid Perovskite Bulk Single Crystal

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  7. Chirality‐Dependent Second‐Order Nonlinear Optical Effect in 1D Organic–Inorganic Hybrid Perovskite Bulk Single Crystal

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  8. Stimuli-responsive switchable halide perovskites: Taking advantage of instability

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  12. Crystal structure and semiconductor properties of copper(II) complex incorporating chiral (R)-(+)-α-Ethylbenzylammonium cations:[(R)-C9H14N]3[CuBr4].Br.

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  14. 1D Chiral Lead Halide Perovskites with Superior Second‐Order Optical Nonlinearity

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  15. Alkyl–Aryl Cation Mixing in Chiral 2D Perovskites

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  16. Chiral 1D perovskite microwire arrays for circularly polarized light detection

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  17. Chiral hybrid organic-inorganic metal halides: A route toward direct detection and emission of polarized light

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  19. Air-grown hybrid copper( i ) halide single crystals: structural transformations and ultraviolet-pumped photoluminescence applications

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  24. Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window

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  33. Control of light, spin and charge with chiral metal halide semiconductors

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  34. Leveraging Hierarchical Chirality in Perovskite(‐Inspired) Halides for Transformative Device Applications

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  35. Chiral Perovskite Nanoplatelets Exhibiting Circularly Polarized Luminescence through Ligand Optimization

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  36. Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging

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  37. Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X‐ray Imaging

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  38. Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals

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  39. Recent progress of bulk photovoltaic effect in acentric single crystals and optoelectronic devices

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  40. Induction of Chiral Hybrid Metal Halides from Achiral Building Blocks

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  41. Chiral Rashba Ferroelectrics for Circularly Polarized Light Detection

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    Chang‐Chun Fan, Xiang‐Bin Han, Bei‐Dou Liang, Chao Yi Shi, Le‐Ping Miao, Chao‐Yang Chai, Chengdong Liu, Qiong Ye, Wen Zhang

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  42. Structural, elastic, electronic and optical properties of double perovskites Ba2NaXO6 (X = Cl, Br, I): First-principles study

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    Hao-Jia Wu, Qiu Yang, Cui-E Hu, Yan Ming Cheng, Guang‐Fu Ji

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  43. A chiral lead-free tin(IV)-based halide organic-inorganic semiconductor with dielectric switching and phase transition

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  44. Spin Selectivity in Chiral Hybrid Cobalt Halide Films with Ultrasmooth Surface

    Small Methods · 2022-11-20

    Qian Wang, Ying Lü, Ruilin He, Ruyi Chen, Leilei Qiao, Feng Pan, Zhou Yang, Cheng Song

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  45. Full‐Color Circularly Polarized Luminescence of CsPbX 3 Nanocrystals Triggered by Chiral Carbon Dots

    Advanced Materials · 2022-11-21

    Yi Ru, Baowei Zhang, Xue Yong, Laizhi Sui, Jingkun Yu, Haoqiang Song, Siyu Lu

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