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RESEARCH PAPER · Journal of the American Chemical Society · 2022

Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point Groups

Hao Li, Fei Song, Desheng Zhu, Yongbo Song, Chuanjun Zhou, Feng Ke, Liang Lü, Xi Kang, Manzhou Zhu

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Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point GroupsOriginalStepwise structure evolution from 2D cluster-based frameworks to silver( i ) clusters8Self‐Regulated Pathway‐Dependent Chirality Control of Silver Nanoclusters27Self‐Regulated Pathway‐Dependent Chirality Control of Silver Nanoclusters4Self‐Assembly of Adaptive Chiral [1]Rotaxane for Thermo‐Rulable Circularly Polarized Luminescence10Self‐Assembly of Adaptive Chiral [1]Rotaxane for Thermo‐Rulable Circularly Polarized Luminescence58Chiroptical Activity of An Achiral Emissive Eu Metal–Organic Framework6Triple-Helical Self-Assembly of Atomically Precise Nanoclusters69Platonic and Archimedean solids in discrete metal-containing clusters138A supramolecular assembly strategy towards organic luminescent materials28Electrostatic Interaction-Induced Aggregation-Induced Emission-Type AgAu Bimetallic Nanoclusters as a Highly Efficient Electrochemiluminescence Emitter for Ultrasensitive Detection of Glial Fibrillary Acidic Protein35Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation33Structurally Flexible Au–Cu Alloy Nanoclusters Enabling Efficient Triplet Sensitization and Photon Upconversion73Atomically precise gold nanoclusters at the molecular-to-metallic transition with intrinsic chirality from surface layers80Size Growth of Au 4 Cu 4 : From Increased Nucleation to Surface Capping16Photoluminescence Anisotropy in Eutectic Crystals of Polynuclear Lanthanide Complexes and Silver Clusters2Photoluminescence Anisotropy in Eutectic Crystals of Polynuclear Lanthanide Complexes and Silver Clusters12Small Molecules Mediated the Chirality Transfer in Self-Assembled Nanocomposites with Strong Circularly Polarized Luminescence56Ligand-protected metal nanoclusters as low-loss, highly polarized emitters for optical waveguides294Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF37Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF6Ligand-correlated crystalline assembly of nanoclusters with atomic precision5Enzyme-activatable charge transfer in gold nanoclusters14Influence of the substituents of the thiol ligand on the optical properties of AuCu 149Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts5Metal Clusters Confined in Chiral Zeolitic Imidazolate Framework for Circularly Polarized-Luminescence Inks29Silver Cluster Assembled Materials: A Model‐Driven Perspective on Recent Progress, with a Spotlight on Ag12 Cluster Assembly7Carborane-Cluster-Wrapped Copper Cluster with Cyclodextrin-like Cavities for Chiral Recognition47DNA Framework-Guided Self-Limiting Aggregation for Highly Luminescent Metal Cluster Nanoaggregates24Hierarchical Self-assembly of Atomically Precise Au Nanoclusters with Molecular Rotor-based Ligands1Vaporchromic Domino Transformation and Polarized Photonic Heterojunctions of Organoplatinum Microrods14Vaporchromic Domino Transformation and Polarized Photonic Heterojunctions of Organoplatinum Microrods2Exceptionally High-glum Circularly Polarized Lasers Empowered by Strong 2D-Chiroptical Response in a Host–Guest Supramolecular Microcrystal29Enhancing solar-driven overall water splitting via both sacrifice and noble metal free photocatalysis: copper cluster/boron-doped carbon nitride catalysts8Superlattice Assembly for Empowering Metal Nanoclusters46Regulating Second‐Harmonic Generation in 2D Chiral Perovskites Through Achiral Organic Spacer Cation Alloying Strategy15A comprehensive review of atomically precise metal nanoclusters with emergent photophysical properties towards diverse applications169Self-assembly of chiroptical ionic co-crystals from silver nanoclusters and organic macrocycles32Unveiling the Racemization in Ferroelectrics with Coupled Ferroelectricity and Optical Activity2Mercaptan Ligand Effect in Determining the Geometric Structures of Silver Nanoclusters2Preparation Methods of Metal Nanoclusters6Theoretical Insights into the Impact of the Central Atom on the Photoluminescence Mechanisms of Ligand-Protected Cu Nanoclusters13Surface Structural Symmetry Breaking of Highly Symmetrical Ag29 Nanoclusters0Nanocluster-based aggregates: Assembled forms, driving forces, and structure-related properties25Assembling Octahedral Pt 2 Ag 4 Clusters for High‐Efficiency Circularly Polarized Luminescence22Controlling Circularly Polarized Luminescence Enabled by Chirality and Energy Transfer from Optimized Chiral Molecules to Quantum Dots15Photoluminescence Modulation of Cation-Induced Gold(I)-Thiolate Aggregates6Achieving Efficient Self‐Driven Full‐Stokes Photodetection in Optically Active Ferroelectric4Achieving Efficient Self‐Driven Full‐Stokes Photodetection in Optically Active Ferroelectric1Atomically defined two-dimensional assembled nanoclusters for Li-ion batteries15Chiral assembly of atomically precise metal nanoclusters11Conformation‐Driven Circularly Polarized Luminescence Sign Inversion in Chiral Bispyrene Based Cocrystals with Optical Waveguide1Conformation‐Driven Circularly Polarized Luminescence Sign Inversion in Chiral Bispyrene Based Cocrystals with Optical Waveguide8Modulating the carbon tails of ligands on AuCu 14 nanoclusters enables the transition from single to dual emission3Electronic structures of a new atomically precise Cu 14 H nanocluster revealed by combined spectro-electrochemistry and first-principles calculations0Halogen bonding in functional chiral systems18Inch-sized achiral perovskite ferroelectric single crystals for multiaxial passive circularly polarized light response0Molecular packing modulated photocatalytic degradation using cocrystal catalysts1Spatial and temporal control over photoresponsive nanoclusters8Schiff Base-Wrapped Co, Zn-Based Clusters with Hierarchical Chiral Structures for Therapeutic Application in Parkinson’s Disease39Structure-property correlation in atomically precise Group-12 nanoclusters and their alloys with Group-11 coinage metals0Lighting up Metal Nanoclusters as Promising Molecular Emitters1

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  1. Stepwise structure evolution from 2D cluster-based frameworks to silver( i ) clusters

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  2. Self‐Regulated Pathway‐Dependent Chirality Control of Silver Nanoclusters

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  3. Self‐Regulated Pathway‐Dependent Chirality Control of Silver Nanoclusters

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  4. Self‐Assembly of Adaptive Chiral [1]Rotaxane for Thermo‐Rulable Circularly Polarized Luminescence

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  5. Self‐Assembly of Adaptive Chiral [1]Rotaxane for Thermo‐Rulable Circularly Polarized Luminescence

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  6. Chiroptical Activity of An Achiral Emissive Eu Metal–Organic Framework

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  7. Triple-Helical Self-Assembly of Atomically Precise Nanoclusters

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  8. Platonic and Archimedean solids in discrete metal-containing clusters

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  9. A supramolecular assembly strategy towards organic luminescent materials

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  10. Electrostatic Interaction-Induced Aggregation-Induced Emission-Type AgAu Bimetallic Nanoclusters as a Highly Efficient Electrochemiluminescence Emitter for Ultrasensitive Detection of Glial Fibrillary Acidic Protein

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  11. Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation

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  12. Structurally Flexible Au–Cu Alloy Nanoclusters Enabling Efficient Triplet Sensitization and Photon Upconversion

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  13. Atomically precise gold nanoclusters at the molecular-to-metallic transition with intrinsic chirality from surface layers

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  14. Size Growth of Au 4 Cu 4 : From Increased Nucleation to Surface Capping

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  15. Photoluminescence Anisotropy in Eutectic Crystals of Polynuclear Lanthanide Complexes and Silver Clusters

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  16. Photoluminescence Anisotropy in Eutectic Crystals of Polynuclear Lanthanide Complexes and Silver Clusters

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  17. Small Molecules Mediated the Chirality Transfer in Self-Assembled Nanocomposites with Strong Circularly Polarized Luminescence

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  18. Ligand-protected metal nanoclusters as low-loss, highly polarized emitters for optical waveguides

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  19. Achiral Au(I) Cyclic Trinuclear Complexes with High‐Efficiency Circularly Polarized Near‐Infrared TADF

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  21. Ligand-correlated crystalline assembly of nanoclusters with atomic precision

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  22. Enzyme-activatable charge transfer in gold nanoclusters

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  27. Carborane-Cluster-Wrapped Copper Cluster with Cyclodextrin-like Cavities for Chiral Recognition

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