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RESEARCH PAPER · Nature Chemistry · 2023

Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals

Gaoyu Chen, Xiaoyu Liu, Jiakun An, Shibin Wang, Xiao-Kun Zhao, Zhongzheng Gu, Caojin Yuan, Xiangxing Xu, Jianchun Bao, Han‐Shi Hu, Jun Li, Xun Wang

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Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystalsOriginalEngineering yeast to produce plant-derived anti-obesity agent11D Chiral Enantiomer Lead-Free Perovskites Induced Chiralopical Activity and Photoelectric Response20Self‐Powered Photodetector Based on Perovskite/Ge Heterojunction with High Responsivity11Understanding the bio-crystallization: An insight to therapeutic relevance2Luminescent metal-halide perovskites: fundamentals, synthesis, and light-emitting devices20Chiral photon emission from a chiral–achiral perovskite heterostructure3Mechanically Tunable Circularly Polarized Luminescence of Liquid Crystal‐Templated Chiral Perovskite Quantum Dots38Mechanically Tunable Circularly Polarized Luminescence of Liquid Crystal‐Templated Chiral Perovskite Quantum Dots137Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead‐free Hybrid Metal Halides7Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead‐free Hybrid Metal Halides63Cooperative Octahedral Tilt Modes Drive Coexisting Displacive and Order–Disorder Pressure-Induced Phase Transitions in MAPbBr32Chiral ZnO-CuO Nanorod Arrays for Circularly Polarized Photodetection6Solvothermal Growth of Chiral β-In2S3 Nanosheet Arrays for Circularly Polarized Photodetection2Thermodynamic and Kinetic Modulation of Methylammonium Lead Bromide Crystallization Revealed by In Situ Monitoring4Transformer enables ion transport behavior evolution and conductivity regulation for solid electrolyte12Research progress in design and synthesis of chiral metal halide perovskites and their circular polarization luminescence3Pyro‐Phototronic Effect Induced Circularly Polarized Light Detection with a Broadband Response22Chiral 3D Perovskite Formation Induced by Chiral Templates29Multi‐Template‐Guided Synthesis of High‐Dimensional Molecular Assemblies for Humidity Gradient‐Based Power Generators16Multi‐Template‐Guided Synthesis of High‐Dimensional Molecular Assemblies for Humidity Gradient‐Based Power Generators7Synthesis and growth of solution-processed chiral perovskites12Giant chiral amplification of chiral 2D perovskites via dynamic crystal reconstruction52A 9R-Type Hexagonal Perovskite Polytype Structure, Me3HyPbBr3, Exhibits Reversible Phase Transition and Fluorescent Semiconductor Properties4Dimensional control of chiral perovskites for high-performance circularly polarized light detection via ligand engineering14High‐Performance Single‐Microplate Perovskite Photodetectors Based on Polyvinyl Alcohol Filled Planar Electrodes for Weak‐Light Imaging and Pixel Integration7Sub-1 nm Materials Chemistry: Challenges and Prospects44Remote chirality transfer in low-dimensional hybrid metal halide semiconductors67Erbium chloride‐mediated nucleation/crystallization control for high‐performance tin‐based perovskite solar cells7Strong Magneto‐Chiroptical Effects through Introducing Chiral Transition‐Metal Complex Cations to Lead Halide19Strong Magneto‐Chiroptical Effects through Introducing Chiral Transition‐Metal Complex Cations to Lead Halide4Spin‐Orbital Ordering Effects of Light Emission in Organic–Inorganic Hybrid Metal Halide Perovskites16Why Mixed Halides in 2D Chiral Perovskites Weaken Chirality-Induced Spin Selectivity24Renal Clearable Chiral Manganese Oxide Supraparticles for In Vivo Detection of Metalloproteinase‐9 in Early Cancer Diagnosis20A three-dimensional lead iodide-bromide perovskitoid with distinct photoelectric anisotropy4Highly textured single-crystal-like perovskite films for large-area, high-performance photodiodes5Remote control of chirality in hybrid perovskite materials5Single-crystalline MAPbCl 3 thin-films for photo- and X-ray voltaics3Spin effects in metal halide perovskite semiconductors25Spatially Isomeric Fulleropyrrolidines Enable Controlled Stacking of Perovskite Colloids for High‐Performance Tin‐Based Perovskite Solar Cells51Spatially Isomeric Fulleropyrrolidines Enable Controlled Stacking of Perovskite Colloids for High‐Performance Tin‐Based Perovskite Solar Cells4Self-assembly of chiroptical ionic co-crystals from silver nanoclusters and organic macrocycles32Roadmap on metal-halide perovskite semiconductors and devices17Chiral-Polar Photovoltage-Driven Efficient Self-Powered Circularly Polarized Light Detection in Three-Dimensional Hybrid Perovskites21Integrated Circular Polarization Detectors Based on Asymmetric Materials or Structures1Chiral All-Inorganic Perovskite Subnanowires26Lead-free single crystal metal halide perovskite detectors37Chiral metal halide perovskites toward room temperature spin light-emitting diodes: Insights and perspectives9Effect of Trivalent Metal Cations in Layered Double Perovskites on Highly Selective CO2 Photoreduction to CO3Unusual polarization-insensitive negative photoresponse of chiral double perovskite ( R/ S-MBA) 4AgBiI 88A Chiral CdS Magic-Size Cluster with Enantiomerically-Biased Crystallization143D Chiral Metal Halide Semiconductors16Dynamic mechanical modulation of chiroptical structures via linearly assembled plasmonic nanoparticles on birefringent polymer films16Chiral Perovskite Single Crystals: Toward Promising Design and Application7Chiral 3D Perovskite Single Crystals Realized by Lattice Expansion6Chiral Fluorine Engineering in Amine Molecular Design: Toward High‐ T c Multifunctional Rare‐Earth Hybrid Double Perovskites5Activating the Chiroptical Properties of High-Fold Axial Chiral Perovskite by a Chiral Induction Strategy11Meticulous Design of Chiral Molecules in Efficient and Stable Perovskite Solar Cells8Giant Room‐Temperature Chiral Quantum Emission ( g lum >0.4) From Lattice‐Symmetry‐Broken Perovskites4Organic-inorganic covalent selenium reversing ischemic reperfusion injury20Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals17Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals6Polarized Luminescence in Halide Perovskite Nanomaterials23Ligand-Driven Chirality in Perovskites for Advanced Optoelectronics19Oriented Crystallization of Perovskite Film via Fluorine‐Containing Hyperbranched Polymer for Efficient and Stable Perovskite Solar Cells24Symmetry Breaking Induced by Chiral Phosphonic Acids in a 2D Tin-Halide Perovskite12Chiral Metal Halides toward Circularly Polarized Photodetectors12Recent Advances in Spin‐LEDs Based on Chiral Nanomaterials: Bridging Fundamental Physics, Materials, and Devices Performance9Structural Engineering for Chirality-Induced Spin Control in Metal–Halide Perovskites10Flexible perovskite light‐emitting diodes: A comprehensive review of emission control strategies for enhanced performance5Anisotropy in bulk-like lead halide perovskite nanorods triggers circularly polarized photoluminescence2Hierarchical assembly for resolving enantiomeric metal clusters0Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Magneto-optic effects of chiral perovskites: from circularly polarized luminescence to spin–photon coupling0Chiral perovskites for circularly polarized light detection0Mechanochemical engineering of chiroptical properties in indium-based chiral metal halides by grinding0Boosting Intrinsic Chirality of One‐dimensional Perovskite Single Crystals via Extended Cation Conjugation4Insights into Racemization of Metal Nanoclusters and Strategic Spontaneous Resolution6Solid-liquid interface synthesis of selective (111)-oriented Cs2AgBiBr6 perovskite crystals13Chiral Metal Halide Perovskites for Spin‐Polarized Light‐Emitting Diodes9Chiral perovskites: From chirality mechanisms to photovoltaics2Recent Progress in CH 3 NH 3 PbX 3 (X = Cl, Br, I) Organic–Inorganic Hybrid Perovskite Optoelectronic Devices2Twisted Lead Halide Perovskite Microbelts with Enhanced Chiroptical Activity via Chiral Ligand-Assisted Self-Assembly of Nanoplatelets3Unraveling A-Site Heterogeneity-Induced Phase Behavior in Mixed-Cation Lead Halide Perovskites1Top-down synthesis of three-dimensional ABO 3 -type perovskite oxides with rich grain boundaries and lattice defects for molecular oxygen activation in catalytic oxidation reactions0Interfacial design principles in mixed-dimensional perovskite heterostructures: Bridging nanostructure chemistry and device functionality0Coherent 2D–3D van der Waals perovskite epitaxial heterostructures0Coordination-Constraint-Driven Enhanced Chirality Induction in Perovskite Quantum Dot Solids1Large-scale optically active nanomaterials: Synthesis, structural modulation, and functional integration1Prussian blue regulates ion dynamics in perovskite solar cells0Giant Anisotropic Spin Absorption in Chiral Hybrid Semiconductors0Room-temperature spin control in WS 2 enabled by chiral seeded lead-free chiral perovskites0

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