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RESEARCH PAPER · Nature Communications · 2020

Emergence of chirality and structural complexity in single crystals at the molecular and morphological levels

Maria Chiara di Gregorio, Linda J. W. Shimon, Vlad Brumfeld, Lothar Houben, Michal Lahav, Milko E. van der Boom

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Emergence of chirality and structural complexity in single crystals at the molecular and morphological levelsOriginalCrystals of Benzamide, the First Polymorphous Molecular Compound, Are Helicoidal35Crystals of Benzamide, the First Polymorphous Molecular Compound, Are Helicoidal12Chiral and SHG-Active Metal–Organic Frameworks Formed in Solution and on Surfaces: Uniformity, Morphology Control, Oriented Growth, and Postassembly Functionalization56Surfactant‐Mediated Morphological Evolution of MnCo Prussian Blue Structures99Induction of Chirality in a Metal–Organic Framework Built from Achiral Precursors66Induction of Chirality in a Metal–Organic Framework Built from Achiral Precursors21Influence of polymer binder on the performance of diF-TES-ADT based organic field effect transistor20Surface chiroselective assembly of enantiopure crystalline porous films containing bichiral building blocks20Physiology and Physical Chemistry of Bile Acids184Molecular cannibalism: Sacrificial materials as precursors for hollow and multidomain single crystals26The Egg-Shaped Crystals That Should Not Be: A Brain-like Texture Combined with Single Crystallinity0The Egg-Shaped Crystals That Should Not Be: A Brain-like Texture Combined with Single Crystallinity0Crystalline Porous Materials for Nonlinear Optics91X-ray Natural Circular Dichroism Imaging of Multiferroic Crystals16Unusual Surface Texture, Dimensions and Morphology Variations of Chiral and Single Crystals**5Unusual Surface Texture, Dimensions and Morphology Variations of Chiral and Single Crystals**15Crystals versus Electrochromic Films: Pathway-Dependent Coordination Networks0Stereochemistry and Twisted Crystals17Directing both the Morphology and Packing of Chiral Metal-Organic Frameworks by Cation Exchange Mediated by Nanochannels0Metal‐Organic Frameworks as a New Platform for Enantioselective Separations17Pathway-Dependent Coordination Networks: Crystals versus Films9Design of MOFs with Absolute Structures: A Case Study13Chirality determination in crystals35Origins of Structural Elasticity in Metal–Phenolic Networks Probed by Super-Resolution Microscopy and Multiscale Simulations38Ultrafast chiral peptides purification via surface plasmon enhanced spin selectivity4Directing the Morphology, Packing, and Properties of Chiral Metal–Organic Frameworks by Cation Exchange**21Directing the Morphology, Packing, and Properties of Chiral Metal–Organic Frameworks by Cation Exchange**7Chiral Motifs in Highly Interpenetrated Metal–Organic Frameworks Formed from Achiral Tetrahedral Ligands**10Classifying handedness in chiral nanomaterials using label error robust deep learning12Architectural Chirality in a Metal–Organic Framework Superstructure3Regulation of Chirality in Metal–Organic Frameworks (MOFs) Based on Achiral Precursors through Substituent Modification9Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels**18Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels**1Triple-Helical Self-Assembly of Atomically Precise Nanoclusters69Crystallographic–Morphological Connections in Star Shaped Metal–Organic Frameworks16Polarization-induced nanohelixes of organic cocrystals from asymmetric components with dopant-induced chirality inversion12On the Helical Crystals of Cholesterol Monohydrate2Structure-directed growth and morphology of multifunctional metal-organic frameworks100Chiral metal-organic frameworks materials for racemate resolution58Factors Controlling Complex Morphologies of Isomorphous Metal‐Organic Frameworks**4Selective Chiral Recognition between Amino Acids and Growing Gypsum Crystals8Chirality Supramolecular Systems: Helical Assemblies, Structure Designs, and Functions60Macroscopic Helical Assembly of One-Dimensional Coordination Polymers: Helicity Inversion Triggered by Solvent Isomerism48Archimedean heterologous helixes in Ti 10 Cd 6 -oxo nanoclusters: double-helical self-assembly and therapeutic application in Parkinson's disease5Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H 2 O 2 photosynthesis5Disorder and diffuse scattering in single-chirality ( TaSe4)2I crystals4Molecular Chirality of Biosynthesized PHB Translates into Uniformly Curved Single Crystals in Langmuir Films1Chirality Determination of Nanocrystals by Electron Crystallography8Macroscopic homochiral helicoids self-assembled via screw dislocations34Selective Chiral Interactions between Hydrophilic/Hydrophobic Amino Acids and Growing Gypsum Crystals0Experimental Determination of the Chiral and Achiral Shape Diagrams of Tellurium Nanocrystals4Size Asymmetry in Multidomain Single Crystals and the Development of Curved Surfaces1Machine learning applications in nanomaterials: Recent advances and future perspectives94Morphological Evolution of Metal‐Organic Frameworks into Hedrite, Sheaf and Spherulite Superstructures with Localized Different Coloration3Emergent chiral and topological nanoarchitectonics in self-assembled supramolecular systems44One-pot synthesis of atomically precise chiral PtAg 4 nanoclusters2Bimetallic Catalysts Based on Chiral Amplification, Inversion, and Assembly for an Asymmetric Cascade Process0Pattern matching workflows for EBSD data analysis: Quartz chirality mapping3Direct chiroptical correlation of dissymmetric crystal morphologies0Chiral biomaterials for promoting wound healing: Fabrication strategies, therapeutic applications, and future prospects2Chiral nanomaterials for oncology and beyond: advancing disease treatment2Insights into Racemization of Metal Nanoclusters and Strategic Spontaneous Resolution6Correlative Imaging Captures a Fusion Mechanism as the Origin of Single Crystals with Multidomain Appearance0Constructing tea polyphenol-trimesoyl chloride-induced 3D phenolic ester cross-linked networks into MXene membranes for superior cation separation1

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  1. Crystals of Benzamide, the First Polymorphous Molecular Compound, Are Helicoidal

    Angewandte Chemie International Edition · 2020-05-29

    Alexander G. Shtukenberg, Ran Drori, Elena V. Sturm, Netta Vidavsky, Asaf Haddad, Jason Zheng, Lara A. Estroff, Haim Weissman, Sharon G. Wolf, Eyal Shimoni, Chao Li, Noalle Fellah, Efi Efrati, Bart E. Kahr

    Read original paper ↗ ·

  2. Crystals of Benzamide, the First Polymorphous Molecular Compound, Are Helicoidal

    Angewandte Chemie · 2020-05-30

    Alexander G. Shtukenberg, Ran Drori, Elena V. Sturm, Netta Vidavsky, Asaf Haddad, Jason Zheng, Lara A. Estroff, Haim Weissman, Sharon G. Wolf, Eyal Shimoni, Chao Li, Noalle Fellah, Efi Efrati, Bart E. Kahr

    Read original paper ↗ ·

  3. Chiral and SHG-Active Metal–Organic Frameworks Formed in Solution and on Surfaces: Uniformity, Morphology Control, Oriented Growth, and Postassembly Functionalization

    Journal of the American Chemical Society · 2020-07-10

    Qiang Wen, Shira Tenenholtz, Linda J. W. Shimon, Omri Bar Elli, Lior M. Beck, Lothar Houben, Sidney Cohen, Yishay Feldman, Dan Oron, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  4. Surfactant‐Mediated Morphological Evolution of MnCo Prussian Blue Structures

    Small · 2020-10-01

    Xian Wang, Anrui Dong, Ziyi Zhu, Lulu Chai, Junyang Ding, Li Zhong, Tingting Li, Yue Hu, Jinjie Qian, Shaoming Huang

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  5. Induction of Chirality in a Metal–Organic Framework Built from Achiral Precursors

    Angewandte Chemie International Edition · 2020-11-13

    Dong Wu, Kang Zhou, Jindou Tian, Caiping Liu, Jia‐Yue Tian, Feilong Jiang, Daqiang Yuan, Jian Zhang, Qihui Chen, Maochun Hong

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  6. Induction of Chirality in a Metal–Organic Framework Built from Achiral Precursors

    Angewandte Chemie · 2020-11-13

    Dong Wu, Kang Zhou, Jindou Tian, Caiping Liu, Jia‐Yue Tian, Feilong Jiang, Daqiang Yuan, Jian Zhang, Qihui Chen, Maochun Hong

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  7. Influence of polymer binder on the performance of diF-TES-ADT based organic field effect transistor

    CrystEngComm · 2020-12-10

    Tommaso Salzillo, Francesco D’Amico, Nieves Montes, Raphael Pfattner, Marta Mas‐Torrent

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  8. Surface chiroselective assembly of enantiopure crystalline porous films containing bichiral building blocks

    Chemical Science · 2021-01-01

    Hao Chen, Zhi‐Gang Gu, Jian Zhang

    Read original paper ↗ ·

  9. Physiology and Physical Chemistry of Bile Acids

    International Journal of Molecular Sciences · 2021-02-10

    Maria Chiara di Gregorio, Jacopo Cautela, Luciano Galantini

    Read original paper ↗ ·

  10. Molecular cannibalism: Sacrificial materials as precursors for hollow and multidomain single crystals

    Nature Communications · 2021-02-11

    Maria Chiara di Gregorio, Merna Elsousou, Qiang Wen, Linda J. W. Shimon, Vlad Brumfeld, Lothar Houben, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  11. The Egg-Shaped Crystals That Should Not Be: A Brain-like Texture Combined with Single Crystallinity

    ChemRxiv · 2021-03-02

    vivek singh, Lothar Houben, Linda J. W. Shimon, Sidney Cohen, Ofra Golani, Yishay Feldman, Michal Lahav, Milko E. van der Boom

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  12. The Egg-Shaped Crystals That Should Not Be: A Brain-like Texture Combined with Single Crystallinity

    ChemRxiv · 2021-03-02

    vivek singh, Lothar Houben, Linda J. W. Shimon, Sidney Cohen, Ofra Golani, Yishay Feldman, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  13. Crystalline Porous Materials for Nonlinear Optics

    Small · 2021-03-18

    Rongchao Shi, Xiao Han, Jialiang Xu, Xian‐He Bu

    Read original paper ↗ ·

  14. X-ray Natural Circular Dichroism Imaging of Multiferroic Crystals

    Crystals · 2021-05-11

    Mikhail S. Platunov, Irina A. Gudim, Elena N. Ovchinnikova, Ksenia A. Kozlovskaya, F. Wilhelm, Andreï Rogalev, Amir Hen, Vsevolod Yu. Ivanov, A. A. Mukhin, В. Е. Дмитриенко

    Read original paper ↗ ·

  15. Unusual Surface Texture, Dimensions and Morphology Variations of Chiral and Single Crystals**

    Angewandte Chemie · 2021-06-11

    Vivek Singh, Lothar Houben, Linda J. W. Shimon, Sidney Cohen, Ofra Golani, Yishay Feldman, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  16. Unusual Surface Texture, Dimensions and Morphology Variations of Chiral and Single Crystals**

    Angewandte Chemie International Edition · 2021-06-11

    Vivek Singh, Lothar Houben, Linda J. W. Shimon, Sidney Cohen, Ofra Golani, Yishay Feldman, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  17. Crystals versus Electrochromic Films: Pathway-Dependent Coordination Networks

    Unknown journal · 2021-08-03

    Milko E. van der Boom, Naveen Malik, Vivek Singh, Linda J. W. Shimon, Lothar Houben, Michal Lahav

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  18. Stereochemistry and Twisted Crystals

    Israel Journal of Chemistry · 2021-09-13

    C. Elizabeth Killalea, David Brian Amabilino

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  19. Directing both the Morphology and Packing of Chiral Metal-Organic Frameworks by Cation Exchange Mediated by Nanochannels

    Unknown journal · 2021-09-28

    Hadar Nasi, Maria Chiara di Gregorio, Qiang Wen, Linda J. W. Shimon, Ifat Kaplan‐Ashiri, Tatyana A. Bendikov, Michal Lahav, Milko E. van der Boom

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  20. Metal‐Organic Frameworks as a New Platform for Enantioselective Separations

    Israel Journal of Chemistry · 2021-09-29

    Gaurav Verma, Ruhi Mehta, Sanjay Kumar, Shengqian Ma

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  21. Pathway-Dependent Coordination Networks: Crystals versus Films

    Journal of the American Chemical Society · 2021-10-07

    Naveen Malik, Vivek Singh, Linda J. W. Shimon, Lothar Houben, Michal Lahav, Milko E. van der Boom

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  22. Design of MOFs with Absolute Structures: A Case Study

    Israel Journal of Chemistry · 2021-10-21

    Haoze Wang, Xiaokun Pei, Davide Maria Proserpio, Omar M. Yaghi

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  23. Chirality determination in crystals

    Chirality · 2021-11-11

    Ángela Valentín‐Pérez, Patrick Rosa, Elizabeth Anne Hillard, Michel Giorgi

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  24. Origins of Structural Elasticity in Metal–Phenolic Networks Probed by Super-Resolution Microscopy and Multiscale Simulations

    ACS Nano · 2021-11-29

    Sukhvir Kaur Bhangu, Patrick Charchar, Benjamin B. Noble, Chan‐Jin Kim, Shuaijun Pan, Irene Yarovsky, Francesca Cavalieri, Frank S Caruso

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  25. Ultrafast chiral peptides purification via surface plasmon enhanced spin selectivity

    Biosensors and Bioelectronics · 2022-05-06

    Yi‐Sheng Lai, Yulin Chen, Chia‐Chun Lin, Yen‐Hsun Su

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  26. Directing the Morphology, Packing, and Properties of Chiral Metal–Organic Frameworks by Cation Exchange**

    Angewandte Chemie International Edition · 2022-05-20

    Hadar Nasi, Maria Chiara di Gregorio, Qiang Wen, Linda J. W. Shimon, Ifat Kaplan‐Ashiri, Tatyana A. Bendikov, Gregory M. Leitus, Miri Kazes, Dan Oron, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  27. Directing the Morphology, Packing, and Properties of Chiral Metal–Organic Frameworks by Cation Exchange**

    Angewandte Chemie · 2022-05-20

    Hadar Nasi, Maria Chiara di Gregorio, Qiang Wen, Linda J. W. Shimon, Ifat Kaplan‐Ashiri, Tatyana A. Bendikov, Gregory M. Leitus, Miri Kazes, Dan Oron, Michal Lahav, Milko E. van der Boom

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  28. Chiral Motifs in Highly Interpenetrated Metal–Organic Frameworks Formed from Achiral Tetrahedral Ligands**

    Chemistry - A European Journal · 2022-06-23

    Qiang Wen, Maria Chiara di Gregorio, Linda J. W. Shimon, Iddo Pinkas, Naveen Malik, Anna Eden Kossoy, Eugeny V. Alexandrov, Davide Maria Proserpio, Michal Lahav, Milko E. van der Boom

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  29. Classifying handedness in chiral nanomaterials using label error robust deep learning

    npj Computational Materials · 2022-07-12

    Catherine Groschner, Alexander J. Pattison, Assaf Ben Moshe, A. Paul Alivisatos, Wolfgang Theis, Mary Cooper Scott

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  30. Architectural Chirality in a Metal–Organic Framework Superstructure

    Crystal Growth & Design · 2022-08-29

    Guillaume Collet, Frédéric Foucher, Antonio Hrvat, Francès Westall, Céline Besnard, Stéphane Pètoud

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  31. Regulation of Chirality in Metal–Organic Frameworks (MOFs) Based on Achiral Precursors through Substituent Modification

    Inorganic Chemistry · 2022-11-08

    Xiangjing Gao, Tingting Wu, Fa-Yuan Ge, Mingyuan Lei, He‐Gen Zheng

    Read original paper ↗ ·

  32. Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels**

    Angewandte Chemie International Edition · 2022-11-17

    Qiang Wen, Naveen Malik, Yoseph Addadi, Maren Weißenfels, Vivek Singh, Linda J. W. Shimon, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  33. Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels**

    Angewandte Chemie · 2022-11-17

    Qiang Wen, Naveen Malik, Yoseph Addadi, Maren Weißenfels, Vivek Singh, Linda J. W. Shimon, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  34. Triple-Helical Self-Assembly of Atomically Precise Nanoclusters

    Journal of the American Chemical Society · 2022-12-09

    Hao Li, Pu Wang, Zhu Chen, Wei Zhang, Meng Ran Zhou, San Zhang, Chunfeng Zhang, Yapei Yun, Xi Kang, Yong Pei, Manzhou Zhu

    Read original paper ↗ ·

  35. Crystallographic–Morphological Connections in Star Shaped Metal–Organic Frameworks

    Journal of the American Chemical Society · 2022-12-12

    Maria Chiara di Gregorio, Vivek Singh, Linda J. W. Shimon, Michal Lahav, Milko E. van der Boom

    Read original paper ↗ ·

  36. Polarization-induced nanohelixes of organic cocrystals from asymmetric components with dopant-induced chirality inversion

    Chemical Science · 2023-01-01

    Jinqiu Chen, Canglei Yang, Shuang Ma, Zhiqi Liu, Wenxin Xiang, Jing Zhang

    Read original paper ↗ ·

  37. On the Helical Crystals of Cholesterol Monohydrate

    Helvetica Chimica Acta · 2023-03-01

    Lia Addadi, Neta Varsano, Assaf Ben Moshe

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  38. Structure-directed growth and morphology of multifunctional metal-organic frameworks

    Coordination Chemistry Reviews · 2023-03-14

    Qi Huang, Yun Hui Yang, Jinjie Qian

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  39. Chiral metal-organic frameworks materials for racemate resolution

    Coordination Chemistry Reviews · 2023-03-21

    Qingsong Cheng, Qian Ma, Hebing Pei, Liang Hao, Xuejiao Zhang, Xuening Jin, Nijuan Liu, Ruibin Guo, Zunli Mo

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  40. Factors Controlling Complex Morphologies of Isomorphous Metal‐Organic Frameworks**

    Chemistry - A European Journal · 2023-06-19

    Vivek Singh, Yishay Feldman, Gregory Leitus, Vlad Brumfeld, Linda J. W. Shimon, Michal Lahav, Milko E. van der Boom

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  41. Selective Chiral Recognition between Amino Acids and Growing Gypsum Crystals

    Langmuir · 2023-09-01

    Jing Gao, Haibin Li, Zhiheng Sun, Jianwei Song, Yue Liu, Chao Jin, Zhisen Zhang, Jun‐An Ma, Wenge Jiang

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  42. Chirality Supramolecular Systems: Helical Assemblies, Structure Designs, and Functions

    Small · 2023-10-27

    Shengzhe Jia, Tiantian Tao, Yujiang Xie, Liuyang Yu, Kang Xiang, Yuan Zhang, Weiwei Tang, Junbo Gong

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  43. Macroscopic Helical Assembly of One-Dimensional Coordination Polymers: Helicity Inversion Triggered by Solvent Isomerism

    Journal of the American Chemical Society · 2023-10-27

    Jia‐Ge Jia, Chen-Chen Zhao, Yifan Wei, Zhi-Min Zhai, Song‐Song Bao, Allan J. Jacobson, Jing Ma, Li‐Min Zheng

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  44. Archimedean heterologous helixes in Ti 10 Cd 6 -oxo nanoclusters: double-helical self-assembly and therapeutic application in Parkinson's disease

    Inorganic Chemistry Frontiers · 2024-01-01

    Ling-Cui Meng, Junyi Chen, Zhi-Ming Feng, Zhan‐Guo Jiang, Zhigang Jin, Cai‐Hong Zhan

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  45. Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H 2 O 2 photosynthesis

    Inorganic Chemistry Frontiers · 2024-01-01

    Liang He, Er‐Xia Chen, Ju-Qiang Xiang, Yujun Guo, Jian Zhang, Qipu Lin

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  46. Disorder and diffuse scattering in single-chirality ( TaSe4)2I crystals

    Physical Review Materials · 2024-03-20

    Jacob A. Christensen, Simon Bettler, Kejian Qu, Jeffrey Huang, Soyeun Kim, Yinchuan Lu, Chengxi Zhao, Jin Chen, Matthew Krogstad, Toby J. Woods, Fahad Mahmood, Pinshane Y. Huang, Peter M. Abbamonte, Daniel P. Shoemaker

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  47. Molecular Chirality of Biosynthesized PHB Translates into Uniformly Curved Single Crystals in Langmuir Films

    Small · 2024-04-05

    Natalia A. Tarazona, Manuela Keller, Rainhard Machatschek

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  48. Chirality Determination of Nanocrystals by Electron Crystallography

    The Journal of Physical Chemistry Letters · 2024-06-27

    Lijin Wang, Yao Wang, Chaoyang Chu, Junyi Hu, Shitao Wu, Yanhang Ma

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  49. Macroscopic homochiral helicoids self-assembled via screw dislocations

    Nature Communications · 2024-07-23

    Sheng-Fu Wu, Xin Song, Cong Du, Minghua Liu

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  50. Selective Chiral Interactions between Hydrophilic/Hydrophobic Amino Acids and Growing Gypsum Crystals

    Langmuir · 2024-08-05

    Zhiheng Sun, Haibin Li, Jing Qing Gao, Yi Xing, Yue Liu, Chao Jin, Jianhong Peng, Zhisen Zhang, Jun‐An Ma, Wenge Jiang

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