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RESEARCH PAPER · Journal of Solid State Chemistry · 2012

Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains

Romain Gautier, Martin D. Donakowski, Kenneth Reinhard Poeppelmeier

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Orientational order of [VOF5]2− and [NbOF5]2− polar units in chainsOriginalThe Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8From Racemic Units to Polar Materials23ChemInform Abstract: Orientational Order of [VOF5]2‐ and [NbOF5]2‐ Polar Units in Chains.0The dimeric [V2O2F8]4− anion: Structural characterization of a magnetic basic-building-unit18Nonlinear Active Materials: An Illustration of Controllable Phase Matchability113Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16Crystal Growth of New Hexahydroxometallates Using a Hydroflux60Spin Frustration from cis-Edge or -Corner Sharing Metal-Centered Octahedra29From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species26Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )3Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds8A metal-organic framework–based splitter for separating propylene from propane1196A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption559Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material142Enhanced Stability toward Humidity in a Family of Hybrid Ultramicroporous Materials Incorporating Cr2O72– Pillars16Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F41Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions207Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)2Cyclohexylammonium sulfanilate: A simple representative of the chiral materials containing only achiral building units8Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride2Heteroanionic Materials by Design: Progress Toward Targeted Properties236Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands9Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization11Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1Thermodynamic Properties of Vanadium Oxypentafluoride (IV) (NH4)3VOF52The state of the field: from inception to commercialization of metal–organic frameworks121An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution10Structural phase transition and switchable dielectric behaviour of a one-dimensional chain niobium oxyfluoride2Novel layered heterobimetallic fluorides with large optical band gaps3Mixed anion materials0Effect of deuteration on the barocaloric properties of complex vanadates (NH4)3VO F6− (x: 1, 2)1Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization10Copper(II) complexes of hindered diazines: methylquinoxalines0Dynamic recognition aperture enables sieving of C3H5Cl/C3H7Cl mixtures in a robust-flexible metal-organic frameworks1Pore Compartmentalization of CO 2 and H 2 O in a Redox‐Active Adsorbent0Pore Compartmentalization of CO 2 and H 2 O in a Redox‐Active Adsorbent0

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  1. The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)

    Zeitschrift für anorganische und allgemeine Chemie · 2012-06-27

    Martin D. Donakowski, Anastasiya I. Vinokur, Kenneth Reinhard Poeppelmeier

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  2. From Racemic Units to Polar Materials

    Crystal Growth & Design · 2012-11-06

    Romain Gautier, Alexander J. Norquist, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  3. ChemInform Abstract: Orientational Order of [VOF5]2‐ and [NbOF5]2‐ Polar Units in Chains.

    ChemInform · 2012-12-18

    Romain Gautier, Martin D. Donakowski, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  4. The dimeric [V2O2F8]4− anion: Structural characterization of a magnetic basic-building-unit

    Journal of Solid State Chemistry · 2013-01-26

    Hongcheng Lu, Romain Gautier, Zuo-Xi Li, Wanqi Jie, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  5. Nonlinear Active Materials: An Illustration of Controllable Phase Matchability

    Journal of the American Chemical Society · 2013-07-18

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, T. Thao Tran, Bryce W. Edwards, Juan C. Nino, P. Shiv Halasyamani, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  6. Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model

    Crystal Growth & Design · 2013-07-31

    Romain Gautier, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  7. Crystal Growth of New Hexahydroxometallates Using a Hydroflux

    Inorganic Chemistry · 2013-10-09

    W. Michael Chance, Daniel E. Bugaris, Athena S. Sefat, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  8. Spin Frustration from cis-Edge or -Corner Sharing Metal-Centered Octahedra

    Journal of the American Chemical Society · 2013-12-02

    Romain Gautier, Kengo Oka, Takumi Kihara, Nitesh Kumar, Athinarayanan Sundaresan, Masashi Tokunaga, Masaki Azuma, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  9. From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species

    Inorganic Chemistry · 2013-12-12

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  10. Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )

    CrystEngComm · 2014-01-01

    Romain Gautier, Sandy Auguste, Simon Clevers, Valérie Dupray, Gérard Coquerel, Éric Le Fur

    Read original paper ↗ ·

  11. Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–

    Crystal Growth & Design · 2014-01-06

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, Lindsay Fuoco, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  12. Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

    Inorganic Chemistry · 2014-08-19

    Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  13. On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units

    Inorganic Chemistry · 2015-01-22

    Romain Gautier, Régis Gautier, Kelvin B. Chang, Kenneth Reinhard Poeppelmeier

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  14. On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds

    Journal of Structural Chemistry · 2016-03-01

    N. M. Laptash, Anatoly A. Udovenko

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  15. A metal-organic framework–based splitter for separating propylene from propane

    Science · 2016-07-07

    Amandine Cadiau, Karim Adil, Prashant M. Bhatt, Youssef Belmabkhout, Mohamed Eddaoudi

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  16. A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption

    Journal of the American Chemical Society · 2016-07-08

    Prashant M. Bhatt, Youssef Belmabkhout, Amandine Cadiau, Karim Adil, Osama Shekhah, Aleksander Shkurenko, Leonard J. Barbour, Mohamed Eddaoudi

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  17. Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material

    ACS Applied Materials & Interfaces · 2017-01-27

    Hayley S. Scott, Mohana Shivanna, Alankriti Bajpai, David Gerard Madden, Kai‐Jie Chen, Tony Pham, Katherine A. Forrest, Adam Hogan, Brian Space, John J. Perry, Michael John Zaworotko

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  18. Enhanced Stability toward Humidity in a Family of Hybrid Ultramicroporous Materials Incorporating Cr2O72– Pillars

    Crystal Growth & Design · 2017-03-14

    Hayley S. Scott, Mohana Shivanna, Alankriti Bajpai, Kai‐Jie Chen, David Gerard Madden, John J. Perry, Michael John Zaworotko

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  19. Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F4

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2017-11-15

    Anatoly A. Udovenko, Evgeny I. Pogoreltsev, Yuri Marchenko, N. M. Laptash

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  20. Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions

    Journal of the American Chemical Society · 2018-06-12

    Hongwei Yu, Matthew Lander Nisbet, Kenneth Reinhard Poeppelmeier

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  21. Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)

    Acta Crystallographica Section C Structural Chemistry · 2018-07-18

    Anastasiya V. Sharko, Oliver Erhart, Harald Krautscheid, K.V. Domasevitch

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  22. Cyclohexylammonium sulfanilate: A simple representative of the chiral materials containing only achiral building units

    Materials Letters · 2019-01-11

    Antoine Blaise Kama, Romain Génois, Florian Massuyeau, Mamadou Sidibé, Cheikh Diop, Romain Gautier

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  23. Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride

    Physics of the Solid State · 2019-02-01

    Evgeniy V. Bogdanov, Evgeniy I. Pogoreltsev, М. В. Горев, Мaxim S. Моlokeev, Igor N. Flerov

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  24. Heteroanionic Materials by Design: Progress Toward Targeted Properties

    Advanced Materials · 2019-03-12

    Jaye K. Harada, Nenian Charles, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  25. Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands

    Crystal Growth & Design · 2019-05-10

    Belal Ahmed, Hongil Jo, Kang Min Ok

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  26. Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization

    European Journal of Inorganic Chemistry · 2019-06-27

    Belal Ahmed, Hongil Jo, Sung Won Yoon, Kwang‐Yong Choi, Wei‐Tin Chen, F. C. Chou, Kang Min Ok

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  27. Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides

    CrystEngComm · 2020-01-01

    Belal Ahmed, Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  28. Thermodynamic Properties of Vanadium Oxypentafluoride (IV) (NH4)3VOF5

    Physics of the Solid State · 2020-07-01

    Evgeniy V. Bogdanov, Evgeniy I. Pogoreltsev, A. V. Kartashev, М. В. Горев, Мaxim S. Моlokeev, S. V. Mel’nikova, Igor N. Flerov, N. M. Laptash

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  29. The state of the field: from inception to commercialization of metal–organic frameworks

    Faraday Discussions · 2020-10-12

    Zhijie Chen, Megan C. Wasson, Riki J. Drout, Lee Robison, Karam B. Idrees, Julia G. Knapp, Florencia A. Son, Xuan Zhang, Wolfgang Hierse, Clemens Kühn, Stefan Peter Marx, Benjamín Hernández, Omar K. Farha

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  30. An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution

    Angewandte Chemie International Edition · 2021-09-28

    Ying Hou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  31. An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution

    Angewandte Chemie · 2021-09-28

    Ying Hou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  32. Structural phase transition and switchable dielectric behaviour of a one-dimensional chain niobium oxyfluoride

    CrystEngComm · 2022-01-01

    Yan Feng, Ze-Jie Wang, Long‐He Li, Rong‐Meng Liao, Zhao‐Bo Hu, Jian‐Rong Li, Chao Yi Shi, Hen-Yun Ye

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  33. Novel layered heterobimetallic fluorides with large optical band gaps

    Journal of Solid State Chemistry · 2022-02-02

    Belal Ahmed, Kang Min Ok

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  34. Mixed anion materials

    Elsevier eBooks · 2022-08-24

    Tong Zhu, Daichi Kato, Shenghan Gao, Hiroshi Kageyama

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  35. Effect of deuteration on the barocaloric properties of complex vanadates (NH4)3VO F6− (x: 1, 2)

    Solid State Sciences · 2022-09-21

    Evgeniy V. Bogdanov, М. В. Горев, Igor N. Flerov

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  36. Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization

    Crystal Growth & Design · 2024-04-01

    Wenyao Zhang, Zichen Li, Xudong Leng, Qun Jing, Qiao Wen

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  37. Copper(II) complexes of hindered diazines: methylquinoxalines

    Journal of Coordination Chemistry · 2024-09-10

    Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira

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  38. Dynamic recognition aperture enables sieving of C3H5Cl/C3H7Cl mixtures in a robust-flexible metal-organic frameworks

    Separation and Purification Technology · 2025-03-13

    Xiaotian Wang, Lei Li, Lei Li, Junbo Xu, Xiangfeng Liang, Chao Yang, Yingbo Li, Yingbo Li

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  39. Pore Compartmentalization of CO 2 and H 2 O in a Redox‐Active Adsorbent

    Angewandte Chemie International Edition · 2026-09-30

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  40. Pore Compartmentalization of CO 2 and H 2 O in a Redox‐Active Adsorbent

    Angewandte Chemie · 2026-09-30

    Ankit Kumar Yadav, Emmanuel Nyela Musa, Ah‐Young Song, Alireza Pourghaderi, Micah Lee Wilson, Chun‐Wai Chang, Kai Shen Choong, Casey R. Simons, Zhenxing Feng, Jeffrey A. Reimer, Ammar H. Alahmed, Mourad Younes, Aqil Jamal, Andrzej Gładysiak, Kyriakos C. Stylianou

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