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RESEARCH PAPER · Inorganic Chemistry · 2011

Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties

Guang‐Ning Liu, Xiao‐Ming Jiang, Mei‐Feng Wu, Guan‐E Wang, Guo‐Cong Guo, Jin‐Shun Huang

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Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical PropertiesOriginalDifferent Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline)m]2+ (m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components501-D Selenidoindates {[In2Se5]}∞ Directed by Chiral Metal Complex Cations of 1,10-Phenanthroline22Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator47Assembly of novel organic-decorated quaternary TM–Hg–Sb–Q compounds (TM = Mn, Fe, Co; Q = S, Se) by the combination of three types of metal coordination geometries723-D Germanate Constructed with Ge7 Cluster Layers and Nickel–Ethanolamine Linkage14A Mixed Valent Thioantimonate(III,V): [SbS3]3– and [SbS4]3– as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7]12Wheel-shaped indium telluride nanoclusters co-crystallized with metal-phenanthroline complexes8Solvent effect on condensation of pyramidal [AsSe3]3–: solvothermal syntheses of new selenidoarsenates containing transition metal(II) complexes with 1,10-phenanthroline8Non‐Corner‐Capped Discrete T4 Cluster Stabilized by a Metal‐Bipyridine Complex3Structural diversity of Ag/3-nitrophthalate coordination polymers controlled by solvent and induction agent27The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex20Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework285Heterometallic Clusters [CuSn3S9]5− and [Cu6Sn6S20]10−: Solvothermal Synthesis and Characterization of 4f–3d Thiostannates26Clusters [Co(As3S3)2]2–, [Ni(As3S3)2]2–, and [{Co(en)}6(μ3-S)4(AsS3)4]2– with Co–As or Ni–As Bonds: Solvothermal Syntheses and Characterizations of Thioarsenates Containing Transition-Metal Complexes30(enH 2 ) 4.5 [In(As V S 4 ) 3 ][As 2 III (μ-S 2 )S 3 ]Cl and (enH 2 )MnAs III As V S 6 : two thioarsenates( iii , v ) with mixed-valent optical properties16[Ni(dap) 3 ] 4 [As 10 Cu 2 S 18 ]: a new thioarsenate containing the rare [As 3 CuS 6 ] cluster with mixed-valence As 2+ /As 3+ ions27Novel thioarsenates {[Mn(2,2′-bipy) 2 (SCN)][Mn(2,2′-bipy)](As V S 4 )} 2 and {[Mn(2,2′-bipy) 2 (SCN)] 2 [As III 2 (S 2 ) 2 S 2 ]}: introducing an anionic second ligand to modify Mn II complex cations of 2,2′-bipyridine20Synthesis, characterization, crystal structures and thermal and photoluminescence studies of dimethylpyrazine-carboxylate mixed ligand silver( i ) coordination polymers with various multinuclear silver units37Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand15Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes69Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties9Syntheses, crystal and band structures, and optical properties of a selenidoantimonate and an iron polyselenide7[Mn(dien) 2 ]MnSnS 4 , [Mn(1,2-dap)] 2 Sn 2 S 6 and [Mn(en) 2 ]MnGeS 4 : from 1D anionic and neutral chains to 3D neutral frameworks33[Mn 2 Ga 4 Sn 4 S 20 ] 8− T3 supertetrahedral nanocluster directed by a series of transition metal complexes42Different Contributions of Aliphatic and Conjugated Organic Cations to Both the Crystal and Electronic Structures: Three Hybrid Iodoargentates Showing Two Isomers of the (AgI2)– Chain41A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates25A series of new manganese thioarsenates( v ) based on different unsaturated [Mn(amine) x ] 2+ complexes14Structures and multiple properties of two polar metal–organic frameworks based on achiral N,O-coordinated ligands: toward multifunctional materials29Structural modulation and properties of silver(I) coordination polymers from 2,6-naphthalenedicarboxylic acid and flexible N-donor linkers10Three New Cadmium Complexes Based on 3-Nitrophthalic Acid: Syntheses, Crystal Structures and Fluorescent Properties3A 3-D net based on weak metallophilic (Cu⋯Cu) interactions4A simultaneous disulfide bond cleavage, N,S-bialkylation/N-protonation and self-assembly reaction: syntheses, structures and properties of two hybrid iodoargentates with thiazolyl-based heterocycles20Four new silver phosphonates constructed from semi-rigid phosphonate ligands: synthesis, structure and properties7Three iodocuprate hybrids symmetrically modulated by positional isomers and the chiral conformation of N-benzyl-methylpyridinium36Unsaturated Mn complex decorated hybrid thioarsenates: Syntheses, crystal structures and physical properties11Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands7Combination of Metal Coordination Tetrahedra and Asymmetric Coordination Geometries of Sb(III) in the Organically Directed Chalcogenidometalates: Structural Diversity and Ion-exchange Properties25Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements94Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg4As2S6⋅2 H2O and One‐Dimensional BaAgAsS320Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)68Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method13Unprecedented 3D and 2D Frameworks of Manganese Thioarsenates Based on Heterometallic Cubic Cluster [Mn6(µ6‐S)(AsS3)4] and Covalent Linker N2H46Assembly of a high stable POM-based Cu(I) coordination polymer with visible-light-driven photocatalytic properties18Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine59Solvothermal syntheses and characterization of three new silver(I)/copper(I)-thioarsenates based on As2+/As3+ ions9Syntheses, crystal structures, and photocatalytic properties of two ammonium-directed Ag–Sb–S complexes30Water Stability Studies of Hybrid Iodoargentates Containing N-Alkylated or N-Protonated Structure Directing Agents: Exploring Noncentrosymmetric Hybrid Structures33Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework8Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates [Ni(1,2-dap)3][As2CdSe4], [Zn(1,2-dap)3][As2CdSe4] and [Ni(en)3][As2CdSe4]5Synthesizing Crystalline Chalcogenidoarsenates in Thiol–Amine Solvent Mixtures26Temperature controlling valance changes of crystalline thioarsenates and thioantimonates21Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Two Organic Hybrid Manganese Selenoarsenates: The Discovery of One-Dimensional Low-Valent Selenoarsenate(II)10Mild solvothermal syntheses and characterizations of five Nb-containing quaternary sulfides6Rare examples of hybrid chalcogenoarsenate( iii ) incorporating trivalent vanadium complexes3Solvothermal syntheses, structures, and characterizations of four thioarsenates A7Cu4As3S13 (A = Rb, Cs), Rb2Cu5As3S8, and CsCu2AsS35Strong Photocurrent Response of Selenoarsenates With Different Transition Metal Complexes as Structure-Directing Agents3

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  1. Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline)m]2+ (m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components

    Inorganic Chemistry · 2011-09-08

    Guang‐Ning Liu, Guo‐Cong Guo, Ming‐Jian Zhang, Jin-Shuang Guo, Hui‐Yi Zeng, Jin‐Shun Huang

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  2. 1-D Selenidoindates {[In2Se5]}∞ Directed by Chiral Metal Complex Cations of 1,10-Phenanthroline

    Inorganic Chemistry · 2011-10-14

    Wen Xu, Zhi‐Xin Lei, Wen Luo, Wen-Qin Mu, Xiang Zhang, Qin‐Yu Zhu, Jie Dai

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  3. Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator

    Inorganic Chemistry · 2011-12-08

    Guang‐Ning Liu, Guo‐Cong Guo, Feng Chen, Shuai‐Hua Wang, Jing Zhi Sun, Jin‐Shun Huang

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  4. Assembly of novel organic-decorated quaternary TM–Hg–Sb–Q compounds (TM = Mn, Fe, Co; Q = S, Se) by the combination of three types of metal coordination geometries

    Dalton Transactions · 2012-01-01

    Kai‐Yao Wang, Liujiang Zhou, Mei‐Ling Feng, Xiao‐Ying Huang

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  5. 3-D Germanate Constructed with Ge7 Cluster Layers and Nickel–Ethanolamine Linkage

    Inorganic Chemistry · 2012-01-09

    Wen Luo, Wen-Qin Mu, Wen Xu, Xiang Zhang, Ya-Yang Pu, Qin‐Yu Zhu, Jie Dai

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  6. A Mixed Valent Thioantimonate(III,V): [SbS3]3– and [SbS4]3– as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7]

    Zeitschrift für Kristallographie - Crystalline Materials · 2012-02-17

    Nicola Herzberg, Christian Näther, Wolfgang Bensch

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  7. Wheel-shaped indium telluride nanoclusters co-crystallized with metal-phenanthroline complexes

    Polyhedron · 2012-08-07

    Xiang Zhang, Ya-Yang Pu, Li-Shen You, Guo‐Qing Bian, Qin‐Yu Zhu, Jie Dai

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  8. Solvent effect on condensation of pyramidal [AsSe3]3–: solvothermal syntheses of new selenidoarsenates containing transition metal(II) complexes with 1,10-phenanthroline

    Journal of Coordination Chemistry · 2012-08-10

    Ruihong Chen, Weiwei Tang, Wenqing Jiang, Yong Zhang, Dingxian Jia

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  9. Non‐Corner‐Capped Discrete T4 Cluster Stabilized by a Metal‐Bipyridine Complex

    Zeitschrift für anorganische und allgemeine Chemie · 2012-09-07

    Ya-Yang Pu, Xiang Zhang, Li-Shen You, Guo‐Qing Bian, Qin‐Yu Zhu, Jie Dai

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  10. Structural diversity of Ag/3-nitrophthalate coordination polymers controlled by solvent and induction agent

    CrystEngComm · 2012-11-28

    Di Sun, Fu-Jing Liu, Rong‐Bin Huang, Lan‐Sun Zheng

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  11. The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex

    Dalton Transactions · 2013-01-01

    Jian Zhou, Xing Liu, Rong Li, Litao An, Fei-Long Hu, Rong Chen, Yuanchun Wei

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  12. Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework

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  13. Heterometallic Clusters [CuSn3S9]5− and [Cu6Sn6S20]10−: Solvothermal Synthesis and Characterization of 4f–3d Thiostannates

    Chemistry - A European Journal · 2013-04-24

    Ruihong Chen, Fang Wang, Chunying Tang, Yong Zhang, Dingxian Jia

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  14. Clusters [Co(As3S3)2]2–, [Ni(As3S3)2]2–, and [{Co(en)}6(μ3-S)4(AsS3)4]2– with Co–As or Ni–As Bonds: Solvothermal Syntheses and Characterizations of Thioarsenates Containing Transition-Metal Complexes

    Inorganic Chemistry · 2013-09-24

    Chunying Tang, Fang Wang, Wenqing Jiang, Yong Zhang, Dingxian Jia

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  15. (enH 2 ) 4.5 [In(As V S 4 ) 3 ][As 2 III (μ-S 2 )S 3 ]Cl and (enH 2 )MnAs III As V S 6 : two thioarsenates( iii , v ) with mixed-valent optical properties

    Dalton Transactions · 2013-12-02

    Ke‐Zhao Du, Mei‐Ling Feng, Xing‐Hui Qi, Zuju Ma, Long-Hua Li, Jian‐Rong Li, Cheng‐Feng Du, Guo‐Dong Zou, Xiao‐Ying Huang

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  16. [Ni(dap) 3 ] 4 [As 10 Cu 2 S 18 ]: a new thioarsenate containing the rare [As 3 CuS 6 ] cluster with mixed-valence As 2+ /As 3+ ions

    Dalton Transactions · 2013-12-04

    Xing Liu, Jian Zhou, Litao An, Guo‐Qing Bian, Rong-Qing Zhao, Zong‐Wen Mo

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  17. Novel thioarsenates {[Mn(2,2′-bipy) 2 (SCN)][Mn(2,2′-bipy)](As V S 4 )} 2 and {[Mn(2,2′-bipy) 2 (SCN)] 2 [As III 2 (S 2 ) 2 S 2 ]}: introducing an anionic second ligand to modify Mn II complex cations of 2,2′-bipyridine

    Dalton Transactions · 2014-01-01

    Guang‐Ning Liu, Guo‐Cong Guo, Ming‐Sheng Wang, Jin‐Shun Huang

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  18. Synthesis, characterization, crystal structures and thermal and photoluminescence studies of dimethylpyrazine-carboxylate mixed ligand silver( i ) coordination polymers with various multinuclear silver units

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    Zhanhui Wang, Danfeng Wang, Ting Zhang, Rong‐Bin Huang, Lan‐Sun Zheng

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  19. Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand

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    Zhan-Hui Wang, Danfeng Wang, Ting Zhang, Rong‐Bin Huang, Lan‐Sun Zheng

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  20. Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes

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  21. Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties

    Chemistry - A European Journal · 2014-05-07

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  22. Syntheses, crystal and band structures, and optical properties of a selenidoantimonate and an iron polyselenide

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  23. [Mn(dien) 2 ]MnSnS 4 , [Mn(1,2-dap)] 2 Sn 2 S 6 and [Mn(en) 2 ]MnGeS 4 : from 1D anionic and neutral chains to 3D neutral frameworks

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  24. [Mn 2 Ga 4 Sn 4 S 20 ] 8− T3 supertetrahedral nanocluster directed by a series of transition metal complexes

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  25. Different Contributions of Aliphatic and Conjugated Organic Cations to Both the Crystal and Electronic Structures: Three Hybrid Iodoargentates Showing Two Isomers of the (AgI2)– Chain

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  26. A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates

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  27. A series of new manganese thioarsenates( v ) based on different unsaturated [Mn(amine) x ] 2+ complexes

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  28. Structures and multiple properties of two polar metal–organic frameworks based on achiral N,O-coordinated ligands: toward multifunctional materials

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  29. Structural modulation and properties of silver(I) coordination polymers from 2,6-naphthalenedicarboxylic acid and flexible N-donor linkers

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  30. Three New Cadmium Complexes Based on 3-Nitrophthalic Acid: Syntheses, Crystal Structures and Fluorescent Properties

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  31. A 3-D net based on weak metallophilic (Cu⋯Cu) interactions

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  32. A simultaneous disulfide bond cleavage, N,S-bialkylation/N-protonation and self-assembly reaction: syntheses, structures and properties of two hybrid iodoargentates with thiazolyl-based heterocycles

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  33. Four new silver phosphonates constructed from semi-rigid phosphonate ligands: synthesis, structure and properties

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  34. Three iodocuprate hybrids symmetrically modulated by positional isomers and the chiral conformation of N-benzyl-methylpyridinium

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  35. Unsaturated Mn complex decorated hybrid thioarsenates: Syntheses, crystal structures and physical properties

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  36. Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands

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  37. Combination of Metal Coordination Tetrahedra and Asymmetric Coordination Geometries of Sb(III) in the Organically Directed Chalcogenidometalates: Structural Diversity and Ion-exchange Properties

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  38. Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements

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  39. Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg4As2S6⋅2 H2O and One‐Dimensional BaAgAsS3

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  40. Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)

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  41. Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method

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  42. Unprecedented 3D and 2D Frameworks of Manganese Thioarsenates Based on Heterometallic Cubic Cluster [Mn6(µ6‐S)(AsS3)4] and Covalent Linker N2H4

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  43. Assembly of a high stable POM-based Cu(I) coordination polymer with visible-light-driven photocatalytic properties

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  44. Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine

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  45. Solvothermal syntheses and characterization of three new silver(I)/copper(I)-thioarsenates based on As2+/As3+ ions

    Journal of Solid State Chemistry · 2016-11-14

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  46. Syntheses, crystal structures, and photocatalytic properties of two ammonium-directed Ag–Sb–S complexes

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  47. Water Stability Studies of Hybrid Iodoargentates Containing N-Alkylated or N-Protonated Structure Directing Agents: Exploring Noncentrosymmetric Hybrid Structures

    Inorganic Chemistry · 2017-02-07

    Guang‐Ning Liu, Xiao‐Ming Jiang, Qingshun Fan, Muhammad Bilal Hussain, Ke Li, Hui Sun, Xin-Yu Li, Wan-Qing Liu, Cuncheng Li

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  48. Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework

    RSC Advances · 2018-01-01

    Jingyu Han, Shufen Li, Chunying Tang, Wei Zheng, Wenqing Jiang, Dingxian Jia

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  49. Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates

    Crystal Growth & Design · 2018-04-09

    Dandan Yang, Ying Jie Song, Bo Zhang, Nan‐Nan Shen, Guilan Xu, Wei‐Wei Xiong, Xiao‐Ying Huang

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  50. Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates [Ni(1,2-dap)3][As2CdSe4], [Zn(1,2-dap)3][As2CdSe4] and [Ni(en)3][As2CdSe4]

    Chemical Research in Chinese Universities · 2019-07-09

    Cui-Xia Du, Juan Chen, Menghe Baiyin

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