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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2009

Syntheses, Crystal Structures and Mass Spectrometry of Mononuclear NiII Inclusion Product and Self‐Assembled [2 × 1+1 × 2] NiII3MII (M = Cu, Ni, Co, Fe or Mn) Cocrystals Derived from N,N′‐Ethylenebis(3‐ethoxysalicylaldimine)

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Syntheses, Crystal Structures and Mass Spectrometry of Mononuclear NiII Inclusion Product and Self‐Assembled [2 × 1+1 × 2] NiII3MII (M = Cu, Ni, Co, Fe or Mn) Cocrystals Derived from N,N′‐Ethylenebis(3‐ethoxysalicylaldimine)OriginalTetrametallic [2 × 1 + 1 × 2], octametallic double-decker–triple-decker [5 × 1 + 3 × 1], hexametallic quadruple-decker and dimetallic-based one-dimensional complexes of copper(ii) and s block metal ions derived from N,N′-ethylenebis(3-ethoxysalicylaldimine)47Syntheses, Structures and Magnetic Properties of Trinuclear Cu II M II Cu II (M = Cu, Ni, Co and Fe) and Tetranuclear [2×1+1×2] Cu II Mn II –2Cu II Complexes Derived from a Compartmental Ligand: The Schiff Base 3‐Methoxysalicylaldehyde Diamine Can also Stabilize a Cocrystal40Current literature in mass spectrometry0The azidopentacyanoferrate(III) ion as a tecton in constructing heterometallic complexes: Synthesis, crystal structure and magnetic properties of [Mn(valphen)(H2O)2]2[(H2O)(valphen)Mn(μ-CN)Fe(CN)4(N3)]·8H2O12Syntheses, crystal structures and magnetic properties of trinuclear and [3 × 1 + 1 × 2] pentanuclear complexes derived from a compartmental ligand: Role of solvent on nuclearity and number of components27Syntheses and crystal structures of dinuclear, trinuclear [2 × 1 + 1 × 1] and tetranuclear [2 × 1 + 1 × 2] copper( ii )–d 10 complexes (d 10 ⇒ Zn II , Cd II , Hg II and Ag I ) derived from N,N′-ethylenebis(3-ethoxysalicylaldimine)47Bis(nitrate)diaquauranyl( vi ) synthon to generate [1 × 2 + 1 × 1] and [1 × 1 + 1 × 1] co-crystalized 3d⋯5f self-assemblies41Syntheses, crystal structures and supramolecular topologies of nickel(II)–s/p/d10/NH4+ complexes derived from a compartmental ligand40Syntheses, crystal structures and magnetic properties of [2 × 1 + 1 × 2] heterotetrametallic and [1 × 1 + 1 × 1] heterodimetallic cocrystals of copper(II) and iron(II/III)22Syntheses, crystal structures and supramolecular topologies of copper(II)–main group metal complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine)31Syntheses, structures, electrochemical measurements and magnetic properties of two iron(III) complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine)14Acyclic and cyclic compartmental ligands: Recent results and perspectives186Two Environmentally Friendly Energetic Compounds, [Mn(AZT)4(H2O)2](PA)2·4H2O and [Co(AZT)2(H2O)4](PA)2, Based on 3‐Azido‐1,2,4‐triazole (AZT) and Picrate (PA)25A new tetraiminodiphenol macrocyclic ligand and its two dicopper(II) complexes: Syntheses, crystal structures, electrochemistry and magnetochemistry27Design of weak interaction directed self-assemblies of nickel(II) complexes using diprotonated diamines as supramolecular tectons: Syntheses and crystal structures7Syntheses, characterizations, and crystal structures of 3d–s/d10 metal complexes derived from two compartmental Schiff base ligands36Crystal structures of discrete, one-dimensional and cocrystalline copper(ii)–uranyl(vi) systems: the influence of the reactant ratio in the competition between hydrogen bonds and coordinate bonds36Metal complex analogues of crown ethers as the preorganized motif to stabilize aquated proton in solid state15More surprising differences between two closely similar compartmental ligand families and another dinuclear synthon to stabilize dinuclear–mononuclear cocrystals31Sodium-mediated self-assembly of two nickel(II) Schiff base complexes: crystal structure and characterizations11Diaquadinitratouranyl(VI) enforces the O(phenoxo)2O(methoxy)2 compartment of 3-methoxysalicylaldehyde-diamine ligands to interact with water molecules16New mononuclear CuII and tetranuclear CuII2–LaIII2 Schiff base complexes – Physicochemical properties15First examples of 3d-uranium compounds derived from single-compartment Schiff base ligands: Syntheses, crystal structures and d–d band correlation15Syntheses, structures, catecholase activity, spectroscopy and electrochemistry of a series of manganese(III) complexes: Role of auxiliary anionic ligand on catecholase activity69A tale of crystal engineering of metal complexes derived from a special ligand family having a cosmopolitan compartment36Synthesis and crystal structure of a triple-decker CuII3TlI2 complex: first example of a thallium(I) system in the imino-phenolate Schiff base ligand family6Exploration of heterometallic systems containing silver(I) in acyclic Schiff base ligands: Finite and infinite self-assemblies as a result of silver(I)–carbon bond and silver(I)⋯silver(I) interaction20Surprising difference between two closely similar O(phenoxo)2O(ether)2 compartments as hosts for an aquated proton and a novel type of host–guest system10Mononuclear and heterometallic dinuclear, trinuclear and dimer-of-dinuclear complexes derived from single- and double-compartment Schiff base ligands having a less utilized diamine23Heterometallic copper(II)–lead(II), nickel(II)–lead(II) and copper(II)–indium(III) compounds derived from an acyclic double-compartment Schiff base ligand17Exploration of weak interaction directed self-assemblies on reacting mononuclear copper(II)/nickel(II)⋯water host⋯guest systems of a double-compartment ligand with mono/di/tricarboxylic acids2Syntheses and Structures of Homodinuclear (Na–Na) and Heterodinuclear (Cu–Na, Cu–K) Metal Complexes2Heterometallic Copper(II)–Tin(II/IV) Salts, Cocrystals, and Salt Cocrystals: Selectivity and Structural Diversity Depending on Ligand Substitution and the Metal Oxidation State26Water inclusion mediated structural diversity and the role of H-bonds in molecular assemblies of manganese(III) bicompartmental Schiff-base complexes13Syntheses, crystal structures, lone pair functionality and electrospray ionization mass spectral properties of trinuclear, dimer of trinuclear and trinuclear-based one-dimensional systems of copper(II) and lead(II)11Biological evaluation of dinuclear copper complex/dichloroacetic acid cocrystal against human breast cancer: design, synthesis, characterization, DFT studies and cytotoxicity assays48Interplay of bifurcated hydrogen bonds in making of inclusion/pseudo-inclusion complexes of Ni(II), Cu(II) and Zn(II) of a salophen type ligand: Crystal structures and spectral aspects10Syntheses, crystal structures and ESI-MS of mononuclear–dinuclear, trinuclear and dinuclear based one-dimensional copper(II)–s block metal ion complexes derived from a 3-ethoxysalicylaldehyde–diamine ligand9Water‐Encapsulated Ni(II) Salphen‐Type Host Complexes: Experimental and Theoretical Analysis of Potentially Bioactive Quasi‐Isostructural Polymorphs7Threading Salen-type Cu- and Ni-Complexes into One-Dimensional Coordination Polymers: Solution versus Solid State and the Size Effect of the Alkali Metal Ion46Linear trinuclear copper(II)-alkali/alkaline earth metal compounds derived from a compartmental ligand6Tridentate Schiff base coordinated trigonal bipyramidal / square pyramidal copper(II) complexes: Synthesis, crystal structure, DFT / TD-DFT calculation, catecholase activity and DNA binding23Photosalient Behavior of Photoreactive Zn(II) Complexes55Compartmentalization of Alkaline-Earth Metals in Salen-Type Cu- and Ni-Complexes in Solution and in the Solid State10Development of multi-metallic complexes using metal-salen complexes as building blocks41Fascinating Structures of a Mixed Valence [MnIII]·[MnIIMnIII] Cocrystal and a MnIIINaIComplex: Slow Magnetic Relaxation and Theoretical Investigations4Inorganic Molecular Complexes: Potential for Growth of a New Subject Area in Self-Assembly5Bimetallic Salen-Based Compounds and Their Potential Applications15Doubly mononuclear cocrystal and oxalato-bridged binuclear copper compounds containing flexible 2-((3,5,6-trichloropyridin-2-yl)oxy)acetate tectons: Synthesis, crystal analysis and magnetic properties120Synthetic strategies and structures of zinc(II) complexes with di-azine ligands based on salicylaldehyde or its derivatives5Synthesis, structure and properties of homo- and hetero-trinuclear complexes of salicylaldehyde-based di-Schiff bases26Development of di and polynuclear lead(II) salen (or reduced salen) complexes having PbO2M (M = Cu/Ni) cores: Synthetic strategies and structures7A review on bio-functional models of catechol oxidase probed by less explored first row transition metals23Family of Quasi-Isotropic Mn II and Mn 2 II Complexes Exhibiting Slow Relaxation of the Magnetization12Polymorphism and structural variability of Ni(II)-water complexes derived from a compartmental Schiff base ligand0Structural patterns of Schiff base compartmental ligands in homometallic and heterometallic frameworks: Role of skeletal length, flexibility and auxiliary ligands10

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  3. Current literature in mass spectrometry

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  4. The azidopentacyanoferrate(III) ion as a tecton in constructing heterometallic complexes: Synthesis, crystal structure and magnetic properties of [Mn(valphen)(H2O)2]2[(H2O)(valphen)Mn(μ-CN)Fe(CN)4(N3)]·8H2O

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  5. Syntheses, crystal structures and magnetic properties of trinuclear and [3 × 1 + 1 × 2] pentanuclear complexes derived from a compartmental ligand: Role of solvent on nuclearity and number of components

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  6. Syntheses and crystal structures of dinuclear, trinuclear [2 × 1 + 1 × 1] and tetranuclear [2 × 1 + 1 × 2] copper( ii )–d 10 complexes (d 10 ⇒ Zn II , Cd II , Hg II and Ag I ) derived from N,N′-ethylenebis(3-ethoxysalicylaldimine)

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  7. Bis(nitrate)diaquauranyl( vi ) synthon to generate [1 × 2 + 1 × 1] and [1 × 1 + 1 × 1] co-crystalized 3d⋯5f self-assemblies

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  8. Syntheses, crystal structures and supramolecular topologies of nickel(II)–s/p/d10/NH4+ complexes derived from a compartmental ligand

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  9. Syntheses, crystal structures and magnetic properties of [2 × 1 + 1 × 2] heterotetrametallic and [1 × 1 + 1 × 1] heterodimetallic cocrystals of copper(II) and iron(II/III)

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  10. Syntheses, crystal structures and supramolecular topologies of copper(II)–main group metal complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine)

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  11. Syntheses, structures, electrochemical measurements and magnetic properties of two iron(III) complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine)

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  12. Acyclic and cyclic compartmental ligands: Recent results and perspectives

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  13. Two Environmentally Friendly Energetic Compounds, [Mn(AZT)4(H2O)2](PA)2·4H2O and [Co(AZT)2(H2O)4](PA)2, Based on 3‐Azido‐1,2,4‐triazole (AZT) and Picrate (PA)

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  14. A new tetraiminodiphenol macrocyclic ligand and its two dicopper(II) complexes: Syntheses, crystal structures, electrochemistry and magnetochemistry

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  15. Design of weak interaction directed self-assemblies of nickel(II) complexes using diprotonated diamines as supramolecular tectons: Syntheses and crystal structures

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  16. Syntheses, characterizations, and crystal structures of 3d–s/d10 metal complexes derived from two compartmental Schiff base ligands

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  17. Crystal structures of discrete, one-dimensional and cocrystalline copper(ii)–uranyl(vi) systems: the influence of the reactant ratio in the competition between hydrogen bonds and coordinate bonds

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  18. Metal complex analogues of crown ethers as the preorganized motif to stabilize aquated proton in solid state

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  19. More surprising differences between two closely similar compartmental ligand families and another dinuclear synthon to stabilize dinuclear–mononuclear cocrystals

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  20. Sodium-mediated self-assembly of two nickel(II) Schiff base complexes: crystal structure and characterizations

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  21. Diaquadinitratouranyl(VI) enforces the O(phenoxo)2O(methoxy)2 compartment of 3-methoxysalicylaldehyde-diamine ligands to interact with water molecules

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  22. New mononuclear CuII and tetranuclear CuII2–LaIII2 Schiff base complexes – Physicochemical properties

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  23. First examples of 3d-uranium compounds derived from single-compartment Schiff base ligands: Syntheses, crystal structures and d–d band correlation

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  30. Heterometallic copper(II)–lead(II), nickel(II)–lead(II) and copper(II)–indium(III) compounds derived from an acyclic double-compartment Schiff base ligand

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  31. Exploration of weak interaction directed self-assemblies on reacting mononuclear copper(II)/nickel(II)⋯water host⋯guest systems of a double-compartment ligand with mono/di/tricarboxylic acids

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  32. Syntheses and Structures of Homodinuclear (Na–Na) and Heterodinuclear (Cu–Na, Cu–K) Metal Complexes

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  39. Water‐Encapsulated Ni(II) Salphen‐Type Host Complexes: Experimental and Theoretical Analysis of Potentially Bioactive Quasi‐Isostructural Polymorphs

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  49. Doubly mononuclear cocrystal and oxalato-bridged binuclear copper compounds containing flexible 2-((3,5,6-trichloropyridin-2-yl)oxy)acetate tectons: Synthesis, crystal analysis and magnetic properties

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