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RESEARCH PAPER · Dalton Transactions · 2007

Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid

Yan‐Qiong Sun, Guo‐Yu Yang

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Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acidOriginalDie Doppel-Integrale ihre gegenseitigen Beziehungen und die Reduction derselben auf einfache bestimmte Integral-Ausdrücke.1Statistik der Krankenversicherung der Arbeiter im Deutschen Reiche für die Jahre 1885, 1886 und 18870Statistik der Krankenversicherung der Arbeiter im Deutschen Reiche für die Jahre 1885, 1886 und 18870Mitteilungen: Die indogermanische Sektion auf dem Münchener Philologentag0La Terza. Dott. Prof. Ermenegildo Modi e tempi formatisi sul tema del perfetto nelle lingue indo-europee e specialmente nell' antico indiano ed iranico, nel greco e nel latino0Wiederholtes Preisausschreiben0Karsten T.E. Beiträge zur Geschichte der ē-Verba im Altgermanischen0Die Kindersterblichkeit in Stadt und Land10Etymologische Probleme und Prinzipien. (zu A. Thomas Romania XXXI, I ff. und Mélanges d’étymologie française 1902).4XI. Die Arbeiterwohlfahrtseinrichtungen der Firma Gebr. Stumm in Neunkirchen0Erdmann, B., Historische Untersuchungen über Kants Prolegomena0Karl Rosenkranz über Schiller0Die periodische Presse des Auslandes0Geschichte Böhmens0Gustav v. Mevissen. Ein rheinisches Lebensbild 1815–18990Konstanzer Häuserbuch. Festschrift zur Jahrhundertfeier der Vereinigung der Stadt Konstanz mit dem Hause Baden0Hartmann, E. Y., System d. Philosophie im Grundriss0Elaboratior grammatica hungarica , von Joh. Nie. Révai0CNUCHA CNOC OS CIONN LIFE.2Schneider, Hermann, Metaphysik als exakte Wissenschaft0IV. Die Valutafrage0A Series of Lanthanide−Transition Metal Frameworks Based on 1-, 2-, and 3D Metal−Organic Motifs Linked by Different 1D Copper(I) Halide Motifs94Solvothermal synthesis a novel hemidirected 2-D (3,3)-net metal-organic framework [Pb(HIDC)] based on the linkages of left- and right-hand helical chains40A new class of 3-D porous framework: [Ln(H2O)n]3+ ions act as pillars between π-stacked and H-bonded sheets of (m-BDTH)− organic anions in [Ln(H2O)n](m-BDTH)3·9(H2O) (Ln = Pr, n = 9; Ln = Gd, n = 8)35Assembly of two 3-D metal–organic frameworks from Cd(II) and 4,5-imidazoledicarboxylic acid or 2-ethyl-4,5-imidazoledicarboxylic acid109Luminescent metal–organic frameworks4960Two- and three-dimensional lanthanide–organic frameworks constructed using 1-hydro-6-oxopyridine-3-carboxylate and oxalate ligands37Three-dimensional 3d–4f heterometallic coordination polymer containing Sm2Mn4 clusters: Synthesis, crystal structure and properties36Two Types of Lanthanide Coordination Polymers of (2,3-f)-Pyrazino(1,10)phenanthroline-2,3-dicarboxylic Acid: Syntheses, Structures, and Properties41Lanthanide-Based Luminescent Hybrid Materials3349Synthesis, structures, and photoluminescent properties of 3D lanthanide coordination polymers with rare (4,5)-connected topology13Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism35Three novel lanthanide complexes with imidazole-4,5-dicarboxylate ligand: Hydrothermal syntheses, structural characterization, and properties27Three Coordination Polymers Based on 1H-Tetrazole (HTz) Generated via in Situ Decarboxylation: Synthesis, Structures, and Selective Gas Adsorption Properties85Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence672D and 3D lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and sulfate bridged secondary building units75A novel three-dimensional 3d–4f heterometallic coordination polymer with unique (3,4)-connected topology and helical units: Synthesis, crystal structure and photoluminescence property58Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates13Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids26Synthesis and Characterization of Novel Lanthanide(III) Complexes-Functionalized Mesoporous Silica Nanoparticles as Fluorescent Nanomaterials57Construction of two 2D 3d-4f coordination complexes based on the linkages of left-and right-handed helical chains38Synthetic Chemistry of Cluster Compounds3Three new coordination complexes based on 2-methyl-4, 5-imidazoledicarboxylic acid varying from zero- to two-dimensionality33A Series of Lanthanide Secondary Building Units Based Metal−Organic Frameworks Constructed by Organic Pyridine-2,6-Dicarboxylate and Inorganic Sulfate97A Novel (3,6,6)-Connected 3D Supramolecular Framework Constructed from 2D (4,4) Coordination Network [Pb(H2pimdc)2(H2O)2]n1A Novel 2D Coordination Polymer Constructed from Left- and Right-handed Helical Chains and 4,4′-bipyridine Bridges12A facile building-block synthesis of multifunctional lanthanide MOFs45An unusual (3,6)-connected microporous metal–organic framework based on tetrahedral Zn4 clusters with selective adsorption of CO213Solvothermal synthesis, crystal structure, and properties of lanthanide-organic frameworks based on thiophene-2,5-dicarboxylic acid61A bimetallic CoII–DyIII complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}n20Diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato)]manganese(II)1Organic‐inorganic Hybrid Lanthanide‐Silver Heterometallic Coordination Frameworks Constructed from Oxalate and Sulfate Anion: Syntheses, Structures, and Photoluminescent Properties10Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal–Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate110Monometallic nickel and bimetallic nickel–europium complexes based on oxydiacetic acid and N-heterocyclic ligands17Diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato)]nickel(II) dihydrate2Poly[tetradecaaquatetrakis(μ3-1H-imidazole-4,5-dicarboxylato)tetra-μ3-sulfato-cobalt(II)hexagadolinium(III)]2Luminescent Metal–Organic Frameworks15Poly[tetradecaaquatetrakis(μ3-imidazole-4,5-dicarboxylato)hexa-μ3-sulfato-cobalt(II)hexasamarium(III)]1Two Lanthanide‐Organic Frameworks Derived from 1H‐Benzimidazole‐5‐Carboxylic Acid and Oxalate Mixed Ligands: Synthesis, Structure and Luminescence Property3Porous coordination polymers based on three planar rigid ligands35Synthesis, Crystal Structures, and Thermal Properties of Two Ni(II) Supramolecules Constructed from Imidazole Dicarboxylates6Lanthanide-pyridyl-2,5-dicarboxylate N-oxide frameworks with rutile topology30Bottom-up synthesis of three heterometallic coordination polymers with layered structures constructed from presynthesized [Sb2(tart)2]2− metalloligands7New two-dimensional metal–organic frameworks constructed from 1H-benzimidazole-5,6-dicarboxylic acid with luminescent studies10Two novel 3D microporous heterometallic 3d–4f coordination frameworks with unique (7, 8)-connected topology: Synthesis, crystal structure and magnetic properties14Four cadmium(II) polymeric frameworks constructed by 2-methyl or 2-ethyl imidazole dicarboxylates37Series of Metal Organic Frameworks Assembled from Ln(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates Exhibiting Tunable UV–vis–IR Light Emission66Anion-dependent assembly and solvent-mediated structural transformations of three Cd(ii) coordination polymers based on 1H-imidazole-4-carboxylic acid39Hydrothermal synthesis, crystal structure and properties of Ni(ii)–4f complexes based on 1H-benzimidazole-5,6-dicarboxylic acid35In Situ Formed White-Light-Emitting Lanthanide–Zinc–Organic Frameworks118Syntheses, Structures, Luminescence, and Magnetic Properties of One-dimensional Lanthanide Coordination Polymers with a Rigid 2,2′-Bipyridine-3,3′,6,6′-tetracarboxylic Acid Ligand66Construction of three lanthanide organic frameworks with (3,5)-connected topology based on 2-methyl-4,5-imidazoledicarboxylate and oxalate14Synthesis, structure and properties of a metal–organic complex built up from ferrous sulfate chains and 2,2'-bipyridyl-5,5'-dicarboxylic acid ligands12Lanthanide Coordination Polymers Constructed from Imidazole-4,5-Dicarboxylate and Sulfate: Syntheses, Structural Diversity, and Photoluminescent Properties81Syntheses, structures and luminescence properties of two series of 3D lanthanide coordination polymers based on benzimidazole-5,6-dicarboxylic acid and oxalate13Crystal structure of diaqua-bis-(2-ethyl-1H-imidazole-4,5-dicarboxylato- O,N)-cobalt(II) trihydrate, [Co(C6H4N2O4)2(H2O)2]·2(H2O)O, C14H22CoN4O131Rational design of cobalt molecular square complexes with exact coplanar corners by bis-chelating 4,5-imidazoledicarboxylate bridges9Synthesis, characterization and thermal decomposition kinetics as well as evaluation of luminescent properties of several 3D lanthanide coordination polymers as selective luminescent probes of metal ions153d–4f Heterometallic coordination polymers constructed by tetranuclear lanthanide-based cluster as secondary building unit37A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: Structural diversity, luminescence and magnetic properties157Auxiliary ligand-directed synthesis of a series of Cd(ii)/Co(ii) coordination polymers with methylenebis(3,5-dimethylpyrazole): syntheses, crystal structures, and properties20The construction of Cu(i)/Cu(ii) coordination polymers based on pyrazine–carboxylate: Structural diversity tuned by in situ hydrolysis reaction27Three-dimensional pillared layered supramolecular networks comprising polymeric layers and tetrameric {H2O}4 pillars11A Three-Dimensional Heterometallic CuII–GdIII Coordination Polymer: Hydrothermal Synthesis, Crystal Structure, Thermal and Magnetic Properties2Syntheses, crystal structures of two coordination polymers constructed from imidazole-based dicarboxylate ligands containing alkyl group14Syntheses and Crystal Structures of Three Cu(II) Complexes Based on 2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4, 5-dicarboxylic Acid)12Hydrothermal syntheses, crystal structures and luminescence properties of Cd(II) coordination polymers based on 2-(pyridine-2-yl)-1H-imidazole-4,5-dicarboxylic acid23Two new 2p–3d–4f heterometallic coordination polymers based on 3,5-pyrazoledicarboxylic acid: synthesis, crystal structures and magnetic properties9Unique (3,8)-connected lanthanide arenedisulfonate metal-organic frameworks containing benzimidazole-5,6-dicarboxylic acid co-ligand: Syntheses, structures and luminescence11A polymeric europium complex with the ligand thiophene-2-carboxylic acid: Synthesis, structural and spectroscopic characterization33A New Metal–Organic Molecular Square Based on Imidazole-4,5-dicarboxylicate0A series of lanthanide complexes based on pyridine-3,5-dicarboxylate and succinate ligands: syntheses, structures and properties28Luminescent lanthanide-2-phenylpyrimidine-carboxylate frameworks: structure and luminescence tuning14A series of 3D isomorphous lanthanide coordination polymers based on flexible dicarboxylate ligand: Synthesis, structure, characterization, and properties21Two new coordination polymers based on N-heterocyclic carboxylic acids8Self-assembled microporous lanthanide coordination polymers built by 2-hydroxynicotinic acid and oxalate ligands1Syntheses, structures and properties of three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands10Optimization in luminescent emission by extended quasi-planar and zigzag chainlike CuII-coordinated geometries2Luminescent lanthanide coordination polymers for photonic applications233Two novel 3d–4f heterometallic coordination polymers with infinite [Ln 4 (OH) 4 ] n 8n+ chains involving in situ decarboxylation8A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid9Lanthanide‐Coordination Polymers with Pyridinedicarboxylic Acids: Syntheses, Structures, and Luminescent Properties15Crystal structure of diaqua-bis(2-methyl-1H-imidazole-4,5-dicarboxylato-κ2-O,N)cadmium(II) tetrahydrate, C12H22CdN4O1421Cluster Compounds4Structural characterization of two tetrachloridozincate salts of 4-carboxy-1H-imidazol-3-ium: a salt hydrate and a co-crystal salt hydrate0Synthesis and characterization of lanthanide-based coordination polymers for highly selective and sensitive luminescent sensor for Pb2+ over mixed metal ions20Imidazole‐dicarboxylic Acid Nickel Complex as a Novel Grafting Agent for Pearl Oyster, Pinctada martensii2White Light Emitting EuIII and TbIII Doped Lanthanide Coordination Polymers Based on in Situ Formed Nitrilotriacetic Anion5The coordination chemistry of N-heterocyclic carboxylic acid: A comparison of the coordination polymers constructed by 4,5-imidazoledicarboxylic acid and 1H-1,2,3-triazole-4,5-dicarboxylic acid124Crystal structure of pyrimidine-2,5-dicarboxylic acid 1.5 hydrate, C12H14N4O110Crystal structure of tetraaqua-bis(1H-indazole-6-carboxylate-κN)cadmium (II), C16H18CdN4O81Lanthanide azolecarboxylate compounds: Structure, luminescent properties and applications84Structure regulation, fluorescence and explosive identification of cadmium(II) complexes based on 4,5-imidazoledicarboxylic acid ligand17Variations of Lanthanide Molecular Materials0A Novel MOF Based on a Viologen Ligand: Photochromism, Ammonia Sensing, and Cr 2 O 7 2− Detection8

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  2. Statistik der Krankenversicherung der Arbeiter im Deutschen Reiche für die Jahre 1885, 1886 und 1887

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  4. Mitteilungen: Die indogermanische Sektion auf dem Münchener Philologentag

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  9. Etymologische Probleme und Prinzipien. (zu A. Thomas Romania XXXI, I ff. und Mélanges d’étymologie française 1902).

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  10. XI. Die Arbeiterwohlfahrtseinrichtungen der Firma Gebr. Stumm in Neunkirchen

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  19. CNUCHA CNOC OS CIONN LIFE.

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  21. IV. Die Valutafrage

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  24. A new class of 3-D porous framework: [Ln(H2O)n]3+ ions act as pillars between π-stacked and H-bonded sheets of (m-BDTH)− organic anions in [Ln(H2O)n](m-BDTH)3·9(H2O) (Ln = Pr, n = 9; Ln = Gd, n = 8)

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  39. Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

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  40. Synthesis and Characterization of Novel Lanthanide(III) Complexes-Functionalized Mesoporous Silica Nanoparticles as Fluorescent Nanomaterials

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  41. Construction of two 2D 3d-4f coordination complexes based on the linkages of left-and right-handed helical chains

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  42. Synthetic Chemistry of Cluster Compounds

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  48. An unusual (3,6)-connected microporous metal–organic framework based on tetrahedral Zn4 clusters with selective adsorption of CO2

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  49. Solvothermal synthesis, crystal structure, and properties of lanthanide-organic frameworks based on thiophene-2,5-dicarboxylic acid

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  50. A bimetallic CoII–DyIII complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}n

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