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RESEARCH PAPER · Inorganic Chemistry · 2004

Toward Templated Metal−Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide−Adipate Frameworks

Daniel T. de Lill, Noel S. Gunning, Christopher L. Cahill

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Toward Templated Metal−Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide−Adipate FrameworksOriginal3D-nets as specific synthetic targets - Crystal Engineering1A New Strategy for Synthesizing Zeolites and Zeolite-Like Materials1Supramolecular stabilization of host molecules within [MPy4(NCO)2]·2Py (M = Cu, Cd) clathrates5Templated metal–organic frameworks: synthesis, structures, thermal properties and solid-state transformation of two novel calcium–adipate frameworks44Why bother with nets ?0MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area444Supramolecular Materials: Metal–Quinonoid Complexes1Unusual Robust Luminescent Porous Frameworks Self-Assembled from Lanthanide Ions and 2,2‘-Bipyridine-4,4‘-dicarboxylate100An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data75π-Bonded quinonoid transition-metal complexes41Discrete and infinite metal–organometallic coordination networks consisting of europium(III) nodes and quinone π-complexes as spacers8Carboxylato-bridged 3D polymeric networks of Gd(III): Synthesis, crystal structure, magnetic property and thermal behavior49Synthesis and crystal structure of a new dysprosium(III) complex with 2-fluorobenzoato and 1,10-phenanthroline4Influence of Water Content on the Self-Assembly of Metal−Organic Frameworks Based on Pyridine-3,5-dicarboxylate111Organometallic Coordination Networks Based on $\uppi$ -Bonded Transition Metal Quinonoid Complexes13Selten‐Erd‐Metall‐Koordinationspolymere: Synthese und Kristallstrukturen von fünf neuen Adipinaten, [M2(Adi)3(H2O)4](AdiH2)(H2O)4 (M = La, Nd), [Er(Adi)(H2O)5]Cl(H2O) und [M(Adi)(H2O)5](NO3)(H2O) (M = Gd, Er)7Grand Canonical Monte Carlo Simulations of the 129Xe NMR Line Shapes of Xenon Adsorbed in (±)-[Co(en)3]Cl314Microporous Metal−Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks373Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized Luminescence163Three-dimensional ionic frameworks built up from La (III) and Ce (III) succinates201D Tubular Chains and 3D Polycatenane Frameworks Constructed with Cu 2 X 2 Dimers (X = Br - , I - , CN - ) and Flexible Dipyridyl Spacers99Assembly and structures of five new Cu(II) complexes based on the V-shaped building block [Cu(dbsf)]28Homo- and heterometallic coordination polymers from the f elements413Construction of 2-D lanthanide coordination frameworks: syntheses, structures and luminescent property87Diversity of crystal structure with different lanthanide ions involving in situ oxidation–hydrolysis reaction132Hybrid Porous Solids34Lanthanide-based emitting materials in light-emitting diodes507Metal-organic frameworks: the young child of the porous solids family62A New Series of Three-Dimensional Metal−Organic Framework, [M2(H2O)][C5N1H3(COO)2]3·2H2O, M = La, Pr, and Nd: Synthesis, Structure, and Properties115Two 3D Porous Lanthanide−Fumarate−Oxalate Frameworks Exhibiting Framework Dynamics and Luminescent Change upon Reversible De- and Rehydration174Two- and Three-Dimensional Lanthanide Complexes: Synthesis, Crystal Structures, and Properties285Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines61Hydrothermal syntheses, structures and properties of five rare earth coordination polymers with (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid19Construction of Robust Open Metal−Organic Frameworks with Chiral Channels and Permanent Porosity156Syntheses, Crystal Structures, and Magnetic Properties of Metal−Organic Hybrid Materials of Cu(II): Effect of a Long Chain Dicarboxylate Backbone, and Counteranion in Their Structural Diversity71Exploring Lanthanide Luminescence in Metal-Organic Frameworks: Synthesis, Structure, and Guest-Sensitized Luminescence of a Mixed Europium/Terbium-Adipate Framework and a Terbium-Adipate Framework292Influence of Connectivity and Porosity on Ligand-Based Luminescence in Zinc Metal−Organic Frameworks669Coordination Polymers of the Lanthanide Elements: A Structural Survey20Synthesis, characterization and fluorescence of lanthanide Schiff-base complexes46Hybrid porous solids: past, present, future5822Hydrothermal synthesis, crystal structure and luminescence properties of lanthanide fumarate coordination polymers containing 2,2′-bipyridine12Synthesis and Characterization of a Praseodymium–Adipate Framework Templated with 1,2-bis(4-Pyridyl)ethane: Host–Guest Interactions and Structural Survey39New Examples of Metal Coordination Architectures of 4,4′‐Sulfonyldibenzoic Acid: Syntheses, Crystal Structure and Luminescence63Structures, thermal stabilities, and magnetic properties of four new lanthanide coordinative frameworks incorporating mixed organic ligands7Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families461,3,5-Tris(functionalised-phenylethynyl)benzene–metal complexes: synthetic survey of mesoporous coordination polymers and investigation of their carbonisation19Three novel 3D metal–organic frameworks with a 1D ladder, tube or chain as assembly units25Triply interpenetrated (3,4)- and (3,5)-connected binodal metal–organic networks prepared from 1,3,5-benzenetrisbenzoate and 4,4′-bipyridyl56Metal−Peptide Frameworks (MPFs): “Bioinspired” Metal Organic Frameworks192(4, 4)- and (6, 3)-2-D luminescent lanthanide(III) metal-organic frameworks constructed from tetrafluorosuccinate and 1,10-phenanthroline16Synthesis, crystal structure and luminescence of a two-dimensional interpenetrating supermolecular complex {[Cd(phen)2(sube)] · 2H2O} n2Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties52Hydrothermal synthesis and structural characterization of three lanthanide coordination polymers with adipic acid and 1,10-phenanthroline2Lanthanide Coordination Polymers Constructed from Dinuclear Building Blocks: Novel Structure Evolution from One-Dimensional Chains to Three-Dimensional Architectures60Hydrothermal synthesis of two novel three-dimensional cobalt(II) metal–organic frameworks based on polycarboxylate and benzotriazole19Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of Two Lanthanide Coordination Polymers with Diglycolic Acid2Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands40N,N′-bis(salicylidene)propane-1,2-diamine lanthanide(III) coordination polymers: Synthesis, crystal structure and luminescence properties39The synthesis and X-ray crystal structures of rare earth(III) perfluoroadipate complexes — Novel coordination polymers2Zn( ii ) and Cu( ii ) coordination polymers assembled from V-shaped tetracarboxylate ligands and N-donor ancillary ligands: syntheses, structures and properties48Construction of hybrid d10 metal–organic frameworks by flexible aromatic dicarboxylate and N-donor ligands : syntheses, structures and physical properties62Luminescent metal–organic frameworks4960Porous Metal Organic Frameworks17Systematic investigation on the coordination chemistry of a sulfonated monoazo dye: Ligand-dominated d- and f-block derivatives16The Long Story and the Brilliant Future of Crystallized Porous Solids5Two- and three-dimensional lanthanide–organic frameworks constructed using 1-hydro-6-oxopyridine-3-carboxylate and oxalate ligands37Luminescent and Magnetic Properties of Lanthanide-Thiophene-2,5-dicarboxylate Hybrid Materials145A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid99Assembly of novel phenanthroline-based cobalt(II) coordination polymers by selecting dicarboxylate ligands with different spacer length: From 1-D chain to 3-D interpenetrated framework24Anion-Induced Formation of Lanthanide-Organic Chains From 3D Framework Solids. Anion Exchange in a Crystal-to-Crystal Manner34Lanthanide‐Based Coordination Polymers Assembled by a Flexible Multidentate Linker: Design, Structure, Photophysical Properties, and Dynamic Solid‐State Behavior61Porous Chromium Terephthalate MIL‐101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis978Two d10 coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties2Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine41Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb3(BDC)4.5(DMF)2(H2O)3 · (DMF)24Lanthanide-Based Luminescent Hybrid Materials3349Synthesis, crystal structure and photoelectric property of two novel coordinated complexes constructed by 4,4′-bipyridine and sebacic acid12Synthesis, structures, and photoluminescent properties of 3D lanthanide coordination polymers with rare (4,5)-connected topology13Syntheses, topological structures and physical properties of two 2D lanthanide–organic frameworks constructed from 5-nitroisophthalic acid13Facile Purification of Porous Metal Terephthalates with Ultrasonic Treatment in the Presence of Amides52Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands53Syntheses and structural characterization of three coordination polymers of Cd(II), Zn(II) and Pb(II) with the “V” shape ligand 4,4′-[isopropylidenebis(p-phenyleneoxy)]diacetic acid7Effect of N-donor auxiliary ligands on the engineering of crystalline architectures of a series of lead(ii) complexes with 5-amino-2,4,6-triiodoisophthalic acid49Five 3D metal–organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidazole-based ligands76Synthesis of a Metal–Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study369Synthesis of isostructural porous metal-benzenedicarboxylates: Effect of metal ions on the kinetics of synthesis59The influence of the guest ion on the synthesis and sorption properties of an open framework lanthanide tetrakisphosphonate16Phase-Transition and Phase-Selective Synthesis of Porous Chromium-Benzenedicarboxylates107Synthesis and Characterization of Three Ytterbium Coordination Polymers Featuring Various Cationic Species and a Luminescence Study of a Terbium Analogue With Open Channels49Coordination and inclusion compounds formed by addition of quinoline (Q) or isoquinoline (Iq) to a metal(II) dibenzoylmethanate (Co, Ni, Zn, Cd)3Lanthanide(III) Coordination Polymers with Longer-Spanning Flexible Ligand: Synthesis, Crystal Structure and Luminescence Property8Rigid and Flexible Lanthanide Complexes with an Infinite Ln–O–Ln Framework: Synthesis, Structure and Properties9Direct Observation of Molecular‐Level Template Action Leading to Self‐Assembly of a Porous Framework113Rare Earth Complexes with Carboxylic Acids, Polyaminopolycarboxylic Acids, and Amino Acids19Synthesis, Crystal Structure and Luminescent Property of a Ternary Complex [Cd(sfdb)(3-pytpy)]2·2H2O (H2sfdb = 4,4′-Sulfonyldibenzoic Acid, 3-pytpy = 4′-(3-Pyridyl)-2,2′:6′,2″-Terpyridine)7A en-templated 3D coordination polymer based on H2pzdc with macrometallocycles14Microporous La(III) Metal−Organic Framework Using a Semirigid Tricarboxylic Ligand: Synthesis, Single-Crystal to Single-Crystal Sorption Properties, and Gas Adsorption Studies72Hydrothermal syntheses, structures, and properties of four metal–organic coordination polymers assembled from V-shaped tetracarboxylate ligands and N-donor ancillary ligands7A new 2D network constructed by polymeric anions and lanthanides. Synthesis, structure and magnetic property of two new compounds20Accelerated Syntheses of Porous Isostructural Lanthanide–Benzenetricarboxylates (Ln–BTC) Under Ultrasound at Room Temperature89Correlation between adsorption and thermal properties of lanthanide(III) dinicotinates5New photoluminescent coordination polymers constructed from dicarboxylate and 1,2-bis(imidazol-1-ylmethyl)benzene3Simple synthesis recipes of porous materials62Homoleptic imidazolate frameworks 3∞[Sr 1−x Eu x (Im) 2 ]—hybrid materials with efficient and tuneable luminescence58Microwave synthesis and crystal structures of two cobalt-4,4′-bipyridine-sulfate frameworks constructed from 1-D coordination polymers linked by hydrogen bonding11Network dimensionality and ligand flexibility in lanthanide terephthalate hydrates37Synthesis, structure and property of lanthanide–organic frameworks with pyridyl- and carboxylate-containing ligand6Photoluminescent and Magnetic Properties of a Series of Lanthanide Coordination Polymers with 1H-Tetrazolate-5-formic Acid95Synthesis, Structure, Luminescent and Thermal Properties of Ytterbium(III) and Dysprosium(III) Complexes with 5‐Sulfoisophthalic Acid Sodium Salt17Functionalization and Assembling of Inorganic Nanocontainers for Optical and Biomedical Applications3Three new 3D coordination polymers constructed by biphenyl-2,2′,4,4′-tetracarboxylic acid: Effect of metal ions and the second ligands22Synthesis, Magnetic Properties, and Structural Investigation of Mixed-Ligand Cu(II) Helical Coordination Polymers with an Amino Acid Backbone and N-Donor Propping: 1-D Helical, 2-D Hexagonal Net (hcb), and 3-D ins Topologies81Effect of ring coordination of pyridine-3,5-dicarboxylate and metatungstate to Ln ions on metatungstate structure: Synthesis, structure and optical property of four new compounds17Synthesis, crystal structure and catalytic property of praseodymium(III) coordination polymer containing tetrazole-5-acetato(tza) anion ligands23Templated synthesis of a layered erbium-organic framework based on 4,6-dimethyl-5-nitroisophthalic acid (H2dna)5Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents124Conjugated Ligands Modulated Sandwich Structures and Luminescence Properties of Lanthanide Metal–Organic Frameworks119Two new nickel(II) complexes constructed by biphenyl-2,2′,6,6′-tetracarboxylic acid: A case study with 2,2′-bipyridine and 1H,1’H-2,2′-biimidazole8Luminescent Functional Metal–Organic Frameworks5697Self-Assembly of Isopolyanion Clusters and Lanthanide-Organic Units into 2D Layers: (NH4)2{[Ln2(C7H4NO4)2(H2O)9][(H2W12O40)]}·nH2O (Ln = Gd, Tb, Ho)5A multifunctional three-dimensional uninodal eight-connected metal–organic framework based on pentanuclear cadmium subunits: New topology, fluorescent and NLO properties29Crystallogeny and photobehavior of supramolecular aggregates based on Nd(III)-binicotinate sheets: Toward the effect of 4,4′-bipyridine0A Series of 3D Rare‐Earth‐Metal–Organic Frameworks with Isolated Guest Keggin Silicotungstate Fragments as Anion Templates19Effect of auxiliary-ligand on assembly of lanthanide(III) complexes with quinoline-2-carboxylic acid: Synthesis, structure, photoluminescent and magnetic properties31Supramolecular Materials: Metal–Quinonoid Complexes0Synthesis, structure and properties of three-dimensional organic–inorganic hybrids based on α-metatungstate16Alkaline earth metal ion doped Zn(ii)-terephthalates127Syntheses, structures, and properties of 3D lanthanide coordination polymers based on pyridine-2,3,5,6-tetracarboxylate21Syntheses, Crystal Structures, and Magnetic Properties of Manganese(II) and Cobalt(II) Complexes with 4‐Hydroxypyridine‐2, 6‐dicarboxylic Acid7Targeted Highly-Thermostable Metal–Organic Frameworks Directed by Imidazole: Syntheses, Structures, Thermal Behaviors and Luminescent Properties9Construction of lanthanide/zinc coordination polymers: In situ ligand reactions and templated synthesis16Syntheses, Structures, Luminescence, and Magnetic Properties of One-dimensional Lanthanide Coordination Polymers with a Rigid 2,2′-Bipyridine-3,3′,6,6′-tetracarboxylic Acid Ligand66Superbase Route to Supertetrahedral Chalcogenide Clusters86Effect of aliphatic dicarboxylate tether on topology in luminescent cadmium coordination polymers containing bis(4-pyridylformyl)piperazine13A novel praseodymium coordination polymer with Pcu topology: Crystal structure, thermal decomposition, luminescence and magnetic properties20Microporous lanthanide metal-organic frameworks106Three cobalt(ii) coordination polymers based on V-shaped aromatic polycarboxylates and rigid bis(imidazole) ligand: syntheses, crystal structures, physical properties and theoretical studies46Study on Novel Structure of Glycolic and Oxalic Acid Holmium: [Ho (C3 H6O9)]·CH3OH0Auxiliary ligand-directed and counter anion-templated effects on coordination networks based on semirigid 2-aminodiacetic terephthalic acid ligand30Luminescent Properties and Applications of Metal-Organic Frameworks21Metal–organic frameworks constructed from flexible ditopic ligands: conformational diversity of an aliphatic ligand33Structural and fluorescent regulation of Cd(ii) coordination polymers with homoterephthalate by N-donor second ligands47Versatile frameworks constructed from divalent metals with 4,4′-methylenedibenzoic acid and imidazole derivative ligands: Syntheses, crystal structures and physical properties10Cobalt metal organic framework as an efficient heterogeneous catalyst for the oxidation of alkanes and alkenes44Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Coordination polymers of lanthanide elements and metatungstate: Syntheses, structure and magnetic property10Topological aspects of lanthanide–adipate–aqua compounds: Close packed and open framework structures6Novel magnetic CoII complexes: Synthesis and characterization8The cerium(III) coordination polymer with mixed polycarboxylic acids. Preparation of the CeO2 nanoparticles by thermal decomposition of the polymer20Solvothermal Synthesis, Structural Diversity, and Properties of Alkali Metal–Organic Frameworks Based on V-shaped Ligand31

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  2. A New Strategy for Synthesizing Zeolites and Zeolite-Like Materials

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  3. Supramolecular stabilization of host molecules within [MPy4(NCO)2]·2Py (M = Cu, Cd) clathrates

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  4. Templated metal–organic frameworks: synthesis, structures, thermal properties and solid-state transformation of two novel calcium–adipate frameworks

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  5. Why bother with nets ?

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  6. MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area

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  7. Supramolecular Materials: Metal–Quinonoid Complexes

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  26. Hybrid Porous Solids

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  27. Lanthanide-based emitting materials in light-emitting diodes

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  36. Exploring Lanthanide Luminescence in Metal-Organic Frameworks: Synthesis, Structure, and Guest-Sensitized Luminescence of a Mixed Europium/Terbium-Adipate Framework and a Terbium-Adipate Framework

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  37. Influence of Connectivity and Porosity on Ligand-Based Luminescence in Zinc Metal−Organic Frameworks

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  38. Coordination Polymers of the Lanthanide Elements: A Structural Survey

    Progress in inorganic chemistry · 2007-06-26

    Daniel T. de Lill, Christopher L. Cahill

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  39. Synthesis, characterization and fluorescence of lanthanide Schiff-base complexes

    Journal of Coordination Chemistry · 2007-08-22

    Peng‐Fei Yan, Wen‐Bin Sun, Guangming Li, Chunhong Nie, Ting Gao, Zheng-Yu Yue

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  40. Hybrid porous solids: past, present, future

    Chemical Society Reviews · 2007-09-19

    Gérard Férey

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  41. Hydrothermal synthesis, crystal structure and luminescence properties of lanthanide fumarate coordination polymers containing 2,2′-bipyridine

    Journal of Coordination Chemistry · 2007-10-10

    Xia Li, Tingting Zhang, Zhuoyong Zhang, Yan-Ling Ju

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  42. Synthesis and Characterization of a Praseodymium–Adipate Framework Templated with 1,2-bis(4-Pyridyl)ethane: Host–Guest Interactions and Structural Survey

    Crystal Growth & Design · 2007-11-03

    Daniel T. de Lill, Christopher L. Cahill

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  43. New Examples of Metal Coordination Architectures of 4,4′‐Sulfonyldibenzoic Acid: Syntheses, Crystal Structure and Luminescence

    European Journal of Inorganic Chemistry · 2007-11-08

    Xiaoli Chen, Lei Gou, Huai‐Ming Hu, Feng Fu, Zhong‐Xi Han, Hui‐Ming Shu, Meng‐Lin Yang, Ganglin Xue, Chuan‐Qin Du

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  44. Structures, thermal stabilities, and magnetic properties of four new lanthanide coordinative frameworks incorporating mixed organic ligands

    Microporous and Mesoporous Materials · 2007-12-05

    Bo-Ren Jian, Hsiao-Chen Liu, You-Wen Lin, Sin-Chiang Huang, Kuei‐Fang Hsu

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  45. Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families

    CrystEngComm · 2007-12-14

    P. Thuéry

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  46. 1,3,5-Tris(functionalised-phenylethynyl)benzene–metal complexes: synthetic survey of mesoporous coordination polymers and investigation of their carbonisation

    Journal of Materials Chemistry · 2008-01-01

    Norifumi Kobayashi, Masashi Kijima

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  47. Three novel 3D metal–organic frameworks with a 1D ladder, tube or chain as assembly units

    CrystEngComm · 2008-01-01

    Haiyan He, Fangna Dai, Aiping Xie, Xin Tong, Daofeng Sun

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  48. Triply interpenetrated (3,4)- and (3,5)-connected binodal metal–organic networks prepared from 1,3,5-benzenetrisbenzoate and 4,4′-bipyridyl

    CrystEngComm · 2008-01-01

    Romain Heck, John Bacsa, John E. Warren, Matthew J. Rosseinsky, Darren Bradshaw

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  49. Metal−Peptide Frameworks (MPFs): “Bioinspired” Metal Organic Frameworks

    Journal of the American Chemical Society · 2008-02-01

    Alexandre Mantion, Lars Massüger, Pierre Rabu, Cornelia G. Palivan, Lynne B. McCusker, Andreas Taubert

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  50. (4, 4)- and (6, 3)-2-D luminescent lanthanide(III) metal-organic frameworks constructed from tetrafluorosuccinate and 1,10-phenanthroline

    Inorganic Chemistry Communications · 2008-04-18

    Xia Li, Yanbin Zhang, Mei Shi, Pei‐Zhou Li

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