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RESEARCH PAPER · Chemical Society Reviews · 2006

Organically-templated metal sulfates, selenites and selenates

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Organically-templated metal sulfates, selenites and selenatesOriginalOrganically‐Templated Metal Sulfates, Selenites and Selenates1Structural characterization of a layered double salt Mn3(OH)2(SO4)2(H2O)2· K2SO412Amine‐Templated One‐Dimensional Metal Sulfates Including a Mixed‐Valent Fe Compound with a Half‐Kagome Structure30Hydrothermal Synthesis of Molybdenum Oxide Based Materials: Strategy and Structural Chemistry62A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition33Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain186Hydrothermal synthesis and luminescent properties of a new family of organically templated lanthanide fluorides8Coordination Polymers and Hybrid Networks of Different Dimensionalities Formed by Metal Sulfites33The crystal structure of a new bismuth tellurium oxychloride Bi0.87Te2O4.9Cl0.87 from neutron powder diffraction data6New inorganic discrete 8-membered wheel clusters: Organically directed titanium sulfate supermolecules25Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions. 3. Structure and Characterization of [Cu(enMe)2]2{[Cu(enMe)2(H2O)]2[Cu6(enMe)2(B-a-SiW9O34)2]}·4H2O111Synthesis, structure and characterization of 4,4′-bipyridine directed isolated cluster and 1D chain of iron sulfates6Syntheses, crystal structures and photoluminescence properties of three novel organically bonded indium selenates or selenites27Amine-Controlled Assembly of Metal−Sulfite Architecture from 1D Chains to 3D Framework33Crystal structures and luminescent properties of two novel coordination polymers containing Ln3+ and SO 4 2 -14Ethylenediammonium tetraaquabis(sulfato)cobaltate(II)2Luminescent Organically Templated Lanthanide Oxalate–Selenate Hybrids6Amine-Templated Open-Framework Zinc Arsenates of Varying Dimensionalities: Synthesis, Structure, Polymorphism, and Transformation Reactions34A novel 3D supramolecular inorganic–metal–organic architecture with honeycomb-like motifs directed by the water tetramer and sulfate anion18Hybrid compounds with chain and layered structures formed by β-alanine7A manganese sulfite with extended metal–oxygen–metal bonds exhibiting hydrogen uptake7Synthesis and structural characterization of four new organically-directed bismuth sulfates5The first examples of lanthanide selenite-carboxylate compounds: syntheses, crystal structures and properties32Three-dimensional hybrid networks based on aspartic acid5Hybrid structures formed by homo- and heteroleptic aliphatic dicarboxylates of lead with 2-D inorganic connectivity18Hydrothermal synthesis and characterization of a zigzag chain and transformation between isomeric iron–sulfate chains1Chiral and Achiral Malate Frameworks with Different Dimensionalities8Offene Gerüststrukturen von Übergangsmetallen24Open‐Framework Structures of Transition‐Metal Compounds380Synthesis, Structure, and Polymorphism Studies in Amine-Templated Open-Framework Zinc Phosphites47Synthesis, crystal structure and photoelectric property of Mn(II/IV) coordination complexes21Synthesis and crystal structures of two inorganic–organic hybrid vanadium selenites with layered structures: (DABCOH2)[(VO2)(SeO3)]2·1.25H2O and (pipeH2)[(VO)2(C2O4)(SeO3)2]4An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids42Supercritical hydrothermal synthesis of Cu2O(SeO3): Structural characterization, thermal, spectroscopic and magnetic studies19A group of new selenite-chlorides of strontium and d-metals (Co,Ni): Synthesis, thermal behavior and crystal chemistry14Mild Hydrothermal Synthesis of Cu(SeO3).2H2O: Structural Characterization, Thermal, Spectroscopic and Magnetic Studies16Synthesis and Structural Characterization of Open-Framework Copper (II) Sulfates22Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate21A layered iodocuprate based on a 3D cationic supramolecular network of dimeric Co(ii) complexes by offset face-to-face interactions15Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate9Synthesis and Characterization of Three Diverse Coordination Frameworks under Co‐ligand Intervention0Solvothermal Synthesis, Crystal Structure and Properties of the First Organic‐templated Holmium Sulfate [C2N2H10]3[Ho2(SO4)6·2H2O]24Two- and three-dimensional lead-1H-imidazole-4,5-dicarboxylates29Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate19Hydrothermal Synthesis and Characterization of a Novel Lead(II) Framework Containing Infinite Pb–O–Pb Linkage Extended by Novel Pb–μ1,1‐(N)CS–Pb Bridges4Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O16Non-carboxylate based metal-organic frameworks (MOFs) and related aspects25Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatolanthanum(III)]]2Co3(SO4)3(OH)2[enH2]: A New S = 3/2 Kagome-Type Layered Sulfate with a Unique Connectivity12Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism35A new organically templated vanadium tellurite: (H2dien)[(VO2)(TeO3)]2·2H2O (dien is diethylenetriamine)5New organically templated vanadium tellurites: (H2pn)[V2TeO8] (pn is propane-1,3-diamine)3(C 2 H 8 N) 9 [Eu 5 (SO 4 ) 12 ]·2H 2 O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels32Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium36Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation23[B4O9H2] Cyclic Borate Units as the Building Unit in a Family of Zinc Borate Structures58Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides33Strontium nickel and barium nickel selenites: Synthesis and X-ray diffraction parameters1Structural chemistry of organically-templated metal fluorides61Synthesis, structure, transformation studies and catalytic properties of open-framework cadmium thiosulfate compounds32Water-induced reversible structural phase transformation with chromotropism in metal supramolecular frameworks containing aminopyrazine and sulfate anions27Amine-Templated Aluminoborates Exhibiting Graphite and Diamond Nets35Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains14Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O3Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates13Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]0One-dimensional lanthanide selenite-carboxylate compounds: Synthesis, crystal structure and properties3Solvothermal Synthesis, Crystal Structures, and Magnetic Properties of Two Organically Templated Iron Sulfates with Chain Structures3Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties38A Slow Leak Synthetic Route to Organically Templated Gallium Sulfates8Multifunctional Homochiral Lanthanide Camphorates with Mixed Achiral Terephthalate Ligands86Two novel organic amine templated lanthanide sulfates: Layer H3DETA · [Nd(H2O)(SO4)3] and chain-like H3DETA · [Ho(H2O)2(SO4)3]1Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La3(SO4)6(H2O)3] constructed from La–O–S tubes and cubic cages12Second structural directing agent induces the formation of 1D organic templated terbium sulfate17Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)35Lanthanide Sulfate Frameworks: Synthesis, Structure, and Optical Properties31Solvothermal synthesis, crystal structure and luminescence property of a new 1D organic amine templated europium sulfate with helical chains17Amine‐Templated Cobalt(II) Coordination Polymer Exhibiting Novel Magnetic Properties: Effect of Dehydration26Organic‐inorganic Hybrid Lanthanide‐Silver Heterometallic Coordination Frameworks Constructed from Oxalate and Sulfate Anion: Syntheses, Structures, and Photoluminescent Properties10Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates4Structural systematic design of organic templated samarium sulfates and their luminescence property14Solvothermal synthesis, crystal structure and properties of three new 1D and 3D organically templated lanthanide sulfates7A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds19Mixed lanthanide succinate–sulfate 3D MOFs: catalysts in nitroaromatic reduction reactions and emitting materials66A series of boroselenite-based open frameworks mediated by the cationic sizes of the alkali metals25A series of new rare earth sulfates based on lanthanide contraction and dual organic-amine templating effects12A six-bladed impeller-like Cu18 nanocluster with S6 symmetry constructed from simple inorganic linkers21Synthesis, structure and magnetic properties of two organically-templated coordination polymers, {[EDAH2][M1M2F2(SO4)2(H2O)2]} (M1= M2= NiII and M1= CoII, M2= NiII)4Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines4Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains26Neutral Mononuclear, Dinuclear, Tetranuclear d7/d10 Metal Complexes Containing bis-Pyrazole/Pyridine Ligands Supported by 2,6-bis(3-Pyrazolyl)Pyridine: Synthesis, Structure, Spectra, and Catalytic Activity54A novel organic–inorganic hybrid 3D framework based on neodymium oxalate–selenites [Nd2(SeO3)2(C2O4)(H2O)2]·2H2O6The synthesis, structure and magnetism studies of two manganese sulfates with a 3D zeolite GIS framework and 1D chain structure8An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Nanostructured Inorganic–Organic Hybrid Semiconductor Materials3Reaction in situ found in the synthesis of a series of lanthanide sulfate complexes and investigation on their structure, spectra and catalytic activity15Two new piperazine templated lanthanide sulfates with 2D corrugated layered crystal structures5Crystal structure of μ-oxo-di-μ-sulfato-κ2O:O'-bis[(2,2'-bipyridine-κ2N, N')-bis(dimethylsulfoxide-κO)-diiron(III)]monohydrate, C24H30Fe2N4O12S40(C4N2H12)3[Ln3(OH)(SO4)7] (Ln = Sm, Eu, and Tb): A Series of Honeycomb-like Open-Framework Lanthanide Sulfates with Extra-Large Channels Containing 24-Membered Rings31Steric-Induced Layer Flection in Templated Vanadium Tellurites11Solvothermal Synthesis, Crystal Structure, and Strong Luminescence of the First Organic‐Templated Europium Sulfate Chloride5The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior3New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16Graphen‐analoge anorganische Schichtmaterialien41Graphene Analogues of Inorganic Layered Materials472From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613Synthesis, structure and photoluminescence properties of amine-templated open-framework bismuth sulfates9A New 1D Coordination Polymer of Lanthanum-Sulfate-1,10-Phenanthroline: Synthesis, Structure, and Photoluminescence Property4Coordination polymers built with transition metal sulphates and angular 2,5-bis(imidazol-1-yl)thiophene (thim 2 ): synthesis, structure and photoluminescent properties12Hybrid vanadates constructed from extended metal–organic arrays: crystal architectures and properties27Solvent-cooperatively directed iodoargentate hybrids: Structures and optical properties48Synthesis and characterization of robust three-dimensional chiral metal sulfates9Temperature-Dependent Organic Functionalization of {Ni6PW9} Species: from Isolated Clusters to 1D Chain6Two Hexa-Ni-Substituted AsW9O34 Clusters Functionalized by Organic Ligands2A Supramolecular Double Sulfate Salt with a Lamellar Type: Crystal Structure and Thermal Behavior21Synthesis, Structure and Characterisation of One Two-Dimensional Layered Vanadium Tellurite [H2en] n [V2Te2O10] n2The two-dimensional coordination polymer poly[diaqua(μ2-1H-imidazo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3-sulfato-dicadmium(II)]1NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units41Formation Principles for Vanadium Selenites: The Role of pH on Product Composition12Inorganic Graphene Analogs46H-bond supported coordination polymers of transition metal sulfites with different dimensionalities7Hierarchical symmetry transfer and flexible charge matching in five [M(phen) 3 ] 2+ directed iodoargentates with 1 to 3D frameworks57Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B2Se3O109Materials1Layered structure of a supramolecular hybrid sulfate salts: Thermal stability and magnetic behavior13Synthesis and structure of coordination polymers of praseodymium(III) and erbium(III) with hydrogen maleate and benzene-1,3-disulfonate as linkers4The first organically templated open-framework metal-sulfites with layered and three-dimensional diamondoid structures17Three rare Ln–Na heterometallic 3D polymers based on sulfate anion: Syntheses, structures, and luminescence properties13Two novel 2D lanthanide sulfate frameworks: Syntheses, structures, and luminescence properties5Three iodocuprate hybrids symmetrically modulated by positional isomers and the chiral conformation of N-benzyl-methylpyridinium36Interpenetrated and Catenated Zinc Thiosulfates Frameworks with dia and qtz Nets: Synthesis, Structure, and Properties10Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions20Reactions of metal salts with bronsted acidic ionic liquid: Formations of imidazole template metal sulfates or imidazole-metal complexes6Synthesis, structure and characterization of five new organically templated metal sulfates with 2-aminopyridinium14Machine-learning-assisted materials discovery using failed experiments1712Synthesis, structural characterization, IR- and Raman spectroscopy, magnetic properties of new organically templated metal sulfates with 4-aminopyridinium20Dynamic Directing Effect and Symmetric Correlation in Three pH‐Modulated 1,4‐Diazabicyclo[2.2.2]octane/Iodoargentate Hybrids15Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate32Metal Organic Frameworks as Dual Functional Adsorbent/Catalysts for Plasma Air Purification Systems1Synthesis and characterization of layered metal sulfates containing MII3(μ 3 -OH/F) 2 (M = Mg, Co) diamond chains7A series of color-tunable light-emitting open-framework lanthanide sulfates containing extra-large 36-membered ring channels9Novel amine templated three-dimensional zinc-organophosphonates with variable pore-openings21Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite‐Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 ‐OH)(TeO 3 ) 3 (NO 3 ) 216Optical and Structural Properties of Natural MnSeO4 Mineral Thin Film7Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)326Rare Examples of Amine-Templated Organophosphonate Open-Framework Compounds: Combined Role of Metal and Amine for Structure Building21The Synthesis of New-Type Rare Earth Luminescent Material [Eu(SO4)F·H2O]0Crystal structure of bis(piperazin-1-ium-κN 4)bis(thiosulfato-κS)zinc(II) dihydrate2Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures10

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  40. Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate

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