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RESEARCH PAPER · Journal of the American Chemical Society · 2003

Combining Second-Order Jahn−Teller Distorted Cations to Create Highly Efficient SHG Materials: Synthesis, Characterization, and NLO Properties of BaTeM 2 O 9 (M = Mo 6+ or W 6+ )

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Combining Second-Order Jahn−Teller Distorted Cations to Create Highly Efficient SHG Materials: Synthesis, Characterization, and NLO Properties of BaTeM 2 O 9 (M = Mo 6+ or W 6+ )OriginalCombining Second‐Order Jahn—Teller Distorted Cations to Create Highly Efficient SHG Materials: Synthesis, Characterization, and NLO Properties of BaTeM2O9 (M: Mo6+ or W6+).0Synthesis, structure and characterization of two new antimony oxides–LaSb 3 O 9 and LaSb 5 O 12 : Formation of LaSb 5 O 12 from the reaction of LaSb 3 O 9 with Sb 2 O 31822 New compounds and structures in the solid state2The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11182The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O113420 New compounds and structures in the solid state5Syntheses and structures of two novel inorganic–organic hybrid octamolybdates: [H2enMe]2[Mo8O26]·2H2O and [Ni(2,2′-bpy)3]2[δ-Mo8O26]40Zn2(bipy)2V4TeO14: A new type of layered vanadium(V) tellurite with organically covalently bonded zinc(II) complex12Open‐Framework Polar Compounds: Synthesis and Characterization ofRare‐Earth Polyoxometalates (C6NO2H5)2[Ln(H2O)5(CrMo6H6O24)]·0.5H2O (Ln = Ce and La)69A novel organically templated three-dimensional open framework vanadium tellurite: (NH3CH2CH2NH3)2V2Te6O1812Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures37Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl221Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O1253Effective second-order nonlinearity in acentric optical crystals with low symmetry53A new noncentrosymmetric tellurite: BaMo2Te2O11(H2O) with {Mo(1)Mo(2)O10}n spiral chains19[Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures35Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity929Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties232Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl222Se2(B2O7): A New Type of Second-Order NLO Material355Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents31New Members in the Nin+1(QO3)nX2 Family: Unusual 3D Network Based on Ni4ClO3 Cubane-like Clusters in Ni7(TeO3)6Cl235Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]210Syntheses, structures, and optical properties of novel zinc(ii) complexes with multicarboxylate and N-donor ligands194Hydrothermal Synthesis of a New Vanadium Tellurate(VI) with a Novel Chain Structure: (NH4)4{(VO2)2[Te2O8(OH)2]}·2H2O15New Organically Templated Gallium and Indium Selenites or Selenates with One-, Two-, and Three-Dimensional Structures18Syntheses and characterization of zero-dimensional molybdoantimonites, A2(Mo4Sb2O18) (A=Y, La, Nd, Sm, Gd and Dy)9Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)230Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters36New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems35Biosynthesis and biological activity of enniatins49Synthesis and Structure of a Cadmium Selenite-Sulfate Cd4(SeO3)2(SO4)24Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand17(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9125Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems109Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl432A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material66Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties52ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations54New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides13Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand98Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response32Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response194Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O973Structures and Properties of Functional Metal Selenites and Tellurites164A New Organically Templated Noncentrosymmetric Bismuth Chloride: Synthesis, Structure, and Characterization of [N(CH3)2H2][(CH3)2NH(CH2)2NH(CH3)2][BiCl6]7Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)265Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal62Organic–inorganic hybrid based on the molybdenum tellurite5Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6307Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate22New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Structure and Thermal Properties of the Nonlinear Optical Crystal BaTeMo2O965Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6112KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework99Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System15BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331Prediction of acentric crystal structure of complex crystals by neural net analysis0A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Three New Coordination Compounds with Push‐Pull Ligand p‐Aminobenzonitrile (4ABN)11Synthesis and structures of two novel non-centrosymmetric metal–organic polymers containing 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid ligands47Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites10Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O1187Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A II 3 M III (PO 4 ) 3 (A = Pb, M = Bi; A = Ba, M = Bi, La)34$^3_\infty$[Tl2Zn(ADC)2(H2O)2]: the First Coordination Polymer with Acetylenedicarboxylate (ADC2–) as Bridging Ligand containing two Different Metal Ions4Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143A Strong Second-Harmonic Generation Material Cd4BiO(BO3)3 Originating from 3-Chromophore Asymmetric Structures295First-principles study of electronic structures and nonlinear optical properties of AMoO3(IO3) (A = Li, Rb and Cs) crystals13Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43First‐Principles Studies on Novel Polar Oxide ZnSnO3; Pressure‐Induced Phase Transition and Electric Properties56Syntheses and characterization of inorganic–organic hybrids with 4-(isonicotinamido)phthalate and some divalent metal centers28A Series of New Phases Containing Three Different Asymmetric Building Units55Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Orientational ordering, tilting and lone-pair activity in the perovskite methylammonium tin bromide, CH3NH3SnBr369One-dimensional lanthanide selenite-carboxylate compounds: Synthesis, crystal structure and properties3New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)295Syntheses, crystal structures, and properties of three new metal selenites Na2Co2(SeO3)3, Na2Co1.67Ni0.33(SeO3)3, and Na2Ni2(SeO3)315A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O956Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation22Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation361Recent Advances in Crystal Growth in China: Laser, Nonlinear Optical, and Ferroelectric Crystals58Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2102A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System37Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41Novel BaTeMo 2 O 9 fine particles synthesized via a supercritical water route3A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91Research progress on mid-IR nonlinear optical crystals with high laser damage threshold in China10New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A2Mo4Sb2O18 (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds18First-principles study of the ferroelectric and optical properties of BaTeMo2O911Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34A New Organic–Inorganic Hybrid Oxyfluorotitanate [Hgua]2·(Ti5O5F12) as a Transparent UV Filter13Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br314Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Coordination Polymers with Tetrafluoroterephthalate as Bridging Ligand49Top seeded solution growth and optical properties of a bromic borate crystal: K3B6O10Br31Synthesis of Cu 3 SnS 4 nanocrystals and nanosheets by using Cu 31 S 16 as seeds43Temperature dependence of elastic properties and piezoelectric applications of BaTeMo2o9 single crystal [Correspondence]12Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra31A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180A series of boroselenite-based open frameworks mediated by the cationic sizes of the alkali metals25Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Cation Effect in Doped BBO and Halogen Anion Effect in Pb2B5O9X (X− = I−, Br−, Cl−)1Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements4MgTeMoO6: A neutral layered material showing strong second-harmonic generation110PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments37PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second order nonlinear properties of monoclinic single crystal BaTeMo2O936Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structural Designs and Property Characterizations for Second-Harmonic Generation Materials1Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28Strong Kleinman-Forbidden Second Harmonic Generation in Chiral Sulfide: La 4 InSbS 9167Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)257Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Explorations of new selenites of the group IIIA and IVA metals13Ba2(BO3)1–x(CO3)xCl1+x: A Mixed Borate and Carbonate Chloride Crystallized from High-Temperature Solution37Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4Synthesis, growth, crystal structure and optical properties of BaBiBO49High efficient external resonator Raman laser based on the monoclinic single crystal BaTeMo2O926Investigation of the dielectric, elastic, and piezoelectric properties of Cs2TeMo3O12 crystals22Vibrational properties of the nonlinear optical crystal β-BaTeMo2O917Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites2Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Infrared dielectric properties of the nonlinear optical crystal BaTeMo2O90

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  2. Synthesis, structure and characterization of two new antimony oxides–LaSb 3 O 9 and LaSb 5 O 12 : Formation of LaSb 5 O 12 from the reaction of LaSb 3 O 9 with Sb 2 O 3

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  35. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

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  36. Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9

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  41. ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations

    Inorganic Chemistry · 2008-06-24

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  42. New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides

    Crystal Growth & Design · 2008-07-18

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  43. Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand

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  44. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

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  45. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie International Edition · 2008-08-29

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  46. Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O9

    Inorganic Chemistry · 2008-09-29

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  47. Structures and Properties of Functional Metal Selenites and Tellurites

    Inorganic Chemistry · 2008-09-29

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    Bulletin of the Korean Chemical Society · 2008-11-20

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  49. Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)

    Journal of the American Chemical Society · 2008-12-17

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  50. Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal

    Applied Physics Letters · 2008-12-22

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