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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2005

Open‐Framework Polar Compounds: Synthesis and Characterization ofRare‐Earth Polyoxometalates (C6NO2H5)2[Ln(H2O)5(CrMo6H6O24)]·0.5H2O (Ln = Ce and La)

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Open‐Framework Polar Compounds: Synthesis and Characterization ofRare‐Earth Polyoxometalates (C6NO2H5)2[Ln(H2O)5(CrMo6H6O24)]·0.5H2O (Ln = Ce and La)OriginalOpen‐Framework Polar Compounds: Synthesis and Characterization of Rare‐Earth Polyoxometalates (C6NO2H5)2 [Ln(H2O)5 (CrMo6H6O24)]×0.5H2O (Ln: Ce and La).0Synthesis and characterization of two new extended structures based on Anderson-type polyoxoanions21Self-Assembly of a Series of Extended Architectures Based on Polyoxometalate Clusters and Silver Coordination Complexes190Synthesis and Characterization of a Novel Organic/Inorganic Hybrid Based on Octamolybdates and Benzimidazole Molecules [Hbenzimi]4 [(benzimi)2Mo8O26] · 2H2O (benzimi = benzimidazole)11Polyoxometalate-Supported Transition Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of [M(OH)6Mo6O18{Cu(Phen)(H2O)2}2][M(OH)6Mo6O18{Cu(Phen)(H2O) Cl}2]·5H2O (M = Al3+, Cr3+)90Synthesis, Structure, and Magnetic Behavior of a Series of Trinuclear Schiff Base Complexes of 5f (U IV , Th IV ) and 3d (Cu II , Zn II ) Ions120Self-Assembly of Extended High-Dimensional Architectures from Anderson-type Polyoxometalate Clusters133Hydrothermal synthesis and characterization of a novel 3D open framework structure of mixed valence ethylenediamine–vanadium phosphate: [C2H10N2][(HVIVO3)(HVVO2) (PO4)]9Synthesis and characterization of two novel high-dimensional extended structures based on Keggin-type polyoxometalates and potassium–glycine complex subunits17Organic−Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes95An Inorganic Aggregate Based on a Sandwich‐Type Polyoxometalate with Lanthanide and Potassium Cations: From 1D Chiral Ladder‐Like Chains to a 3D Open Framework62A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanions [Pr(PW11O39)2]11− and sodium cation linkers7Vibrational spectra of transition element compounds0Influence of different site symmetries of Eu3+ centers on the luminescence properties of Anderson-based compounds27Synthesis and characterization of a novel Anderson-type tungstotellurate decorated by transition metal complexes: [Na(H2O)3]2[{Cu(2,2′-bipy)2}2(TeW6O24)] · 4H2O6Phase transformation of a rare-earth Anderson polyoxometalate at low temperature24Polyoxometalates16Synthesis and Structures of Novel Lanthanide Benzenedicarboxylates4Self‐Assembly of Polyoxometalate‐Supported Ln‐H nydroxo/Oxo Clusters with 1D Extended Structure: [LnIII(H2O)7Cr(OH)6Mo6O18]n·4nH2O (Ln = Ce, Sm, Eu)16Synthesis and Structure of a Novel Polyoxomolybdate Lanthanide Complex: [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18] · 14H2O6An inorganic-organic compound with 1D honeycomb-like channels constructed from non-covalent linkage: synthesis and properties4Hydrothermal assembly and luminescence property of lanthanide-containing Anderson polyoxometalates22Synthesis and characterization of B-type Anderson polyoxoanions supported copper complexes with mixed ligands24The first crystallographic observation of up to the third hydration layer of Cu(II) ion in an unusual ‘water-cation layer’ templated by an Anderson polyoxometallate4Two new architectures based on Anderson-type polyoxoanions and cadmium fragments11Two new extended frameworks constructed from the sandwiching polytungstoarsenate clusters6Three Hybrid Organic−Inorganic Assemblies Based on Different Arsenatomolybdates and CuII−Organic Units23Hydrothermal synthesis of two Anderson POM-supported transition metal organic–inorganic compounds16High-dimensional frameworks dependent on coordination mode of ligand controlled by acidity of reaction solution. Syntheses, structures, magnetic and fluorescence properties of eight new compounds34A 3D organic–inorganic network constructed from an Anderson-type polyoxometalate anion, a copper complex and a tetrameric [Na4(H2O)14]4+ cluster,44Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na4(H2O)14}{Cu(gly)}2][TeMo6O24] and [{Cu(en)2}3{TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines55Rare Earth Polyoxometalate Complexes7A new 2D network constructed by polymeric anions and lanthanides. Synthesis, structure and magnetic property of two new compounds20A hydrotalcitelike Ce(III) coordination polymer pillared by Keggin anions: Synthesis, single crystal structure and photocatalysis31Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes101Two large ionic crystals: Both their anions and cations constructed by Anderson-type POM-supported transition metal complex9Self-assembly of d-penicillaminato M6M′8 (M = Niii, Pdii, Ptii; M′ = Cui, Agi) clusters and their organization into extended LaiiiM6M′8 supramolecular structures19Two extended architectures formed by Anderson-type polyoxometalates and Zr4+/Ce3+–1,2-diaminoethanetetraacetate complexes12Hydrothermal synthesis and characterization of a new Anderson-type polyoxometalate7First Three-Dimensional Inorganic–Organic Hybrid Material Constructed From an “Inverted Keggin” Polyoxometalate and a Copper(I)-Organic Complex160A series of three-dimensional architectures constructed from lanthanide-substituted polyoxometalosilicates and lanthanide cations or lanthanide–organic complexes as linkers27Three-dimensional lanthanide polyoxometalate organic complexes: correlation of structure with properties55Synthesis, Structure, and Properties of Two Supramolecular Compounds Based on Silicotungstic Acid and Transition Metal(II) Coordinated Isonicotinic Acid4A novel organic–inorganic hybrid with Anderson type polyanions as building blocks: (C6H10N3O2)2Na(H2O)2[Al(OH)6Mo6O18]·6H2O14Lanthanopolyoxometalates: From the structure of polyanions to the design of functional materials49Transition metal-induced self-assembly of small molybdenum clusters15A 3D all-inorganic architecture based on the [H2W12O42]10− building block with different alkaline-earth metal linkers: crystal structures, surface photovoltage and photoluminescent properties18Assembly of trimeric polyoxovanadate aggregates based on [MnV13O38]7− building blocks and lanthanide cations13In Situ Recrystallization of Polyoxometalates: From 0D Architectures to 2D Inorganic–Organic Hybrids4Heteropolyacid‐Based Materials as Heterogeneous Photocatalysts136Assembly and photocatalysis of two novel 3D Anderson-type polyoxometalate-based metal–organic frameworks constructed from isomeric bis(pyridylformyl)piperazine ligands78Photoluminescent chromium molybdate cluster coordinated with rare earth cations: synthesis, structure, optical and magnetic properties16Multidimensional all-inorganic frameworks based on new molybdovanadate cluster of [VMo 7 O 28 ] 9− with Cu( ii ) linker showing semiconducting behavior18Synthesis, Crystal Structure, Fluorescence and Photocatalytic Properties of a Copper Compound with 2‐Phenyl‐1H‐1,3,7,8‐tetraazacyclopenta[l]phenanthrene and Silicotungstic Acid2Novel Anderson-type [TeMo 6 O 24 ] 6− -based metal–organic complexes tuned by different species and their coordination modes: assembly, various architectures and properties33Heteropolyacid-Based Heterogeneous Photocatalysts for Environmental Application9pH-tuned diverse structures and properties: two Anderson-type polyoxometalate-based metal–organic complexes for selective photocatalysis and adsorption of organic dyes23Crystal Structures and Photoluminescence of Two Inorganic–Organic Hybrids of Anderson Anions2Syntheses, structural characterization and photophysical properties of two series of rare-earth-isonicotinic-acid containing Waugh-type manganomolybdates17A series of novel Anderson-type polyoxometalate-based Mn II complexes constructed from pyridyl-derivatives: assembly, structures, electrochemical and photocatalytic properties47An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide–organic complex: synthesis, crystal structure and properties13Assembly, structures, electrocatalytic and photocatalytic properties of a series of Anderson-type polyoxometalate-based metal–organic complexes based on flexible pyridyl-amide ligands15Solvent-controlled synthesis of various Anderson-type polyoxometalate-based metal–organic complexes with excellent capacity for the chromatographic separation of dyes37Two rare Cr–Ln (Ln = Dy, Tb) heterometallic cluster substituted polyoxometalates featuring hexameric aggregates: hydrothermal syntheses, crystal structures and magnetic studies14Cu dendrites induced by the Anderson-type polyoxometalate NiMo6O24 as a promising electrocatalyst for enhanced hydrogen evolution86Various Anderson-type polyoxometalate-based metal–organic complexes induced by diverse solvents: assembly, structures and selective adsorption for organic dyes44Synthesis, crystal structure and optical properties of Anderson-type heteropolyanion with cobalt cations7Methylated B-type Anderson heteropolymolybdate: synthesis, structure, and magnetic properties2Carbon dots/PtW6O24 composite as efficient and stable electrocatalyst for hydrogen oxidation reaction in PEMFCs36

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  2. Synthesis and characterization of two new extended structures based on Anderson-type polyoxoanions

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  3. Self-Assembly of a Series of Extended Architectures Based on Polyoxometalate Clusters and Silver Coordination Complexes

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  4. Synthesis and Characterization of a Novel Organic/Inorganic Hybrid Based on Octamolybdates and Benzimidazole Molecules [Hbenzimi]4 [(benzimi)2Mo8O26] · 2H2O (benzimi = benzimidazole)

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  5. Polyoxometalate-Supported Transition Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of [M(OH)6Mo6O18{Cu(Phen)(H2O)2}2][M(OH)6Mo6O18{Cu(Phen)(H2O) Cl}2]·5H2O (M = Al3+, Cr3+)

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  6. Synthesis, Structure, and Magnetic Behavior of a Series of Trinuclear Schiff Base Complexes of 5f (U IV , Th IV ) and 3d (Cu II , Zn II ) Ions

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  7. Self-Assembly of Extended High-Dimensional Architectures from Anderson-type Polyoxometalate Clusters

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  8. Hydrothermal synthesis and characterization of a novel 3D open framework structure of mixed valence ethylenediamine–vanadium phosphate: [C2H10N2][(HVIVO3)(HVVO2) (PO4)]

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  9. Synthesis and characterization of two novel high-dimensional extended structures based on Keggin-type polyoxometalates and potassium–glycine complex subunits

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  10. Organic−Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes

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  11. An Inorganic Aggregate Based on a Sandwich‐Type Polyoxometalate with Lanthanide and Potassium Cations: From 1D Chiral Ladder‐Like Chains to a 3D Open Framework

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  12. A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanions [Pr(PW11O39)2]11− and sodium cation linkers

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  13. Vibrational spectra of transition element compounds

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  14. Influence of different site symmetries of Eu3+ centers on the luminescence properties of Anderson-based compounds

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  15. Synthesis and characterization of a novel Anderson-type tungstotellurate decorated by transition metal complexes: [Na(H2O)3]2[{Cu(2,2′-bipy)2}2(TeW6O24)] · 4H2O

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  16. Phase transformation of a rare-earth Anderson polyoxometalate at low temperature

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  17. Polyoxometalates

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  18. Synthesis and Structures of Novel Lanthanide Benzenedicarboxylates

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  19. Self‐Assembly of Polyoxometalate‐Supported Ln‐H nydroxo/Oxo Clusters with 1D Extended Structure: [LnIII(H2O)7Cr(OH)6Mo6O18]n·4nH2O (Ln = Ce, Sm, Eu)

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  20. Synthesis and Structure of a Novel Polyoxomolybdate Lanthanide Complex: [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18] · 14H2O

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  21. An inorganic-organic compound with 1D honeycomb-like channels constructed from non-covalent linkage: synthesis and properties

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  23. Synthesis and characterization of B-type Anderson polyoxoanions supported copper complexes with mixed ligands

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  34. A hydrotalcitelike Ce(III) coordination polymer pillared by Keggin anions: Synthesis, single crystal structure and photocatalysis

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  35. Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes

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  36. Two large ionic crystals: Both their anions and cations constructed by Anderson-type POM-supported transition metal complex

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  43. Synthesis, Structure, and Properties of Two Supramolecular Compounds Based on Silicotungstic Acid and Transition Metal(II) Coordinated Isonicotinic Acid

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  44. A novel organic–inorganic hybrid with Anderson type polyanions as building blocks: (C6H10N3O2)2Na(H2O)2[Al(OH)6Mo6O18]·6H2O

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  45. Lanthanopolyoxometalates: From the structure of polyanions to the design of functional materials

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  46. Transition metal-induced self-assembly of small molybdenum clusters

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  47. A 3D all-inorganic architecture based on the [H2W12O42]10− building block with different alkaline-earth metal linkers: crystal structures, surface photovoltage and photoluminescent properties

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  49. In Situ Recrystallization of Polyoxometalates: From 0D Architectures to 2D Inorganic–Organic Hybrids

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  50. Heteropolyacid‐Based Materials as Heterogeneous Photocatalysts

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