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RESEARCH PAPER · Journal of the American Chemical Society · 2006

Se2(B2O7): A New Type of Second-Order NLO Material

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Se2(B2O7): A New Type of Second-Order NLO MaterialOriginalSe2(B2O7): A New Type of Second‐Order NLO Material.0New compounds and structures in the solid state2A White‐Light‐Emitting Borate‐Based Inorganic–Organic Hybrid Open Framework185A White‐Light‐Emitting Borate‐Based Inorganic–Organic Hybrid Open Framework25Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters36Biosynthesis and biological activity of enniatins49New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand17Cu20Sb35O44Br37 – one structure, two temperature dependencies6La4(Si5.2Ge2.8O18)(TeO3)4 and La2(Si6O13)(TeO3)2: Intergrowth of the lanthanum(III) tellurite layer with the XO4 (X=Si/Ge) tetrahedral layer20Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems109A new promising scintillator Ba3InB9O1828Phase relations of the Li2O–Ta2O5–B2O3 and Li2O–WO3–B2O3 systems and promising nonlinear optical compounds in K2O–Ta2O5–B2O3 system4Modulation of Third‐Order Nonlinear Optical Properties by Backbone Modification of Polymeric Pillared‐Layer Heterometallic Clusters97ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations54New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides13Synthesis, crystal structure and NLO property of a nonmetal pentaborate [C6H13N2][B5O6(OH)4]46A stable second-order NLO and luminescent Cd(II) complex based on 6-hydroxynicotinic acid28Structures and Properties of Functional Metal Selenites and Tellurites164Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties159Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties26A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate103Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster48A Multifunctional 3D Ferroelectric and NLO-Active Porous Metal−Organic Framework269KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework99Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System15BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Studies on two coordination polymers [M(μ4-pz25dc)] (M = Cd or Zn, pz25dc = pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties9A Novel Boron Oxide Organic Open‐Framework Compound: B6O9(en)2@(H2en)Cl233Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Hyperpolarizabilities of Chelidamic Acid Complexes Mm(C7H3O5N)n (MCu, Ag): Theoretical Analysis0Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites10Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Zn[Htma][ddm]: An Interesting Three-Dimensional Chiral Nonlinear Optical-Active Zinc-Trimesate Framework34Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9New compounds and structures in the solid state1NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143A Strong Second-Harmonic Generation Material Cd4BiO(BO3)3 Originating from 3-Chromophore Asymmetric Structures295Syntheses and Characterizations of Cs 2 Cr 3 (BP 4 O 14 )(P 4 O 13 ) and CsFe(BP 3 O 11 ) Compounds with Novel Borophosphate Anionic Partial Structures31Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO340A Series of Open‐Framework Aluminoborates Templated by Transition‐Metal Complexes107Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O3Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43(CH3NH3)2[Ge(B4O9)]: An organically-templated chiral borogermanate with second-order nonlinear and ferroelectric properties29Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation361Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O13A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System37Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Synthesis, Crystal Structure, and Characterization of a Novel Metallo‐Organically‐Templated Pentaborate with Mixed Ligands8Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials132Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br314Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H3210[Ni(en)3][InSbS4]: A One‐Dimensional Polymeric Indium Thioantimonate with a Polar Structure25Synthesis and structure of [C6N4H20]0.5[B5O6(OH)4]: A new organically templated pentaborate with white-light-emission17Structures and properties of functional metal iodates72Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931Syntheses and crystal structures of two new aluminoborates with helical channels4Crystal structure and photoluminescence of Tb3+-activated Ba3InB3O914A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503A new mixed-ligand copper pentaborate with square-like, rectangle-like and ellipse-like channels formed via hydrogen bonds13Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57Synthesis, structural characterization and optical properties of a new cesium aluminum borate, Cs2Al2B2O725New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180A series of boroselenite-based open frameworks mediated by the cationic sizes of the alkali metals25Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Cation Effect in Doped BBO and Halogen Anion Effect in Pb2B5O9X (X− = I−, Br−, Cl−)1Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements4Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structural Designs and Property Characterizations for Second-Harmonic Generation Materials1Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Crystal structures and second-order NLO properties of borogermanates59Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)257UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Explorations of new selenites of the group IIIA and IVA metals13Synthesis and characterization of a new organic–inorganic hybrid zinc borate: [Zn(dab)0.5(dab′)0.5(B4O6(OH)2)]·H2O33Two Acentric Mononuclear Molecular Complexes with Unusual Magnetic and Ferroelectric Properties31Synthesis, crystal structure and properties of a new congruently melting compound, K3ZnB5O1016Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10Highlights on inorganic solid state chemistry and energy materials2An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Growth, optical and electrical properties of a nonlinear optical crystal NaBa4Al2B8O18Cl315Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)29Organic microbelt array based on hydrogen-bond architecture showing polarized fluorescence and two-photon emission47Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Synthesis, Crystal Structure, and Variable‐Temperature‐Luminescent Property of the Organically Templated Pentaborate [C10N2H9][B5O6(OH)4]·H3BO3·H2O8Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O105Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38Synthesis and Structure of KPbBP 2 O 8 – A Congruent Melting Borophosphate with Nonlinear Optical Properties35Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)16Pb2B3O5.5(OH)2 and [Pb3(B3O7)](NO3): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems55Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92The effects of external electric field: creating non-zero first hyperpolarizability for centrosymmetric benzene and strongly enhancing first hyperpolarizability for non-centrosymmetric edge-modified graphene ribbon H2N-(3,3)ZGNR-NO215Chiral and Noncentrosymmetric Metal–Organic Frameworks Featuring a 2D → 3D Parallel/Parallel Inclined Subpolycatenation27Hydrothermal Synthesis of Zn2(MoO4)(SeO3) and Photocatalytic Applications0A new phase in the MnII–SeIV–MoVI–O system, Mn(MoO3)(SeO3)(H2O): Hydrothermal synthesis, crystal structure and properties2High temperature redox reactions with uranium: Synthesis and characterization of Cs(UO2)Cl(SeO3), Rb2(UO2)3O2(SeO3)2, and RbNa5U2(SO4)77Synthesis, Structure, and Luminescent Property of the Templated Borate [C9H14N]·[B5O6(OH)4]15A new mixed metal borate of BaPb[B5O9(OH)]·H2O with acentric structure18Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Ab initio calculation of structural, electronic and optical properties of Hg(IO3)27Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains20SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures50CsPbCO3F: A Strong Second-Harmonic Generation Material Derived from Enhancement via p−π Interaction272Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61[Cu(C12N2H8)2(C2H3O2)][B5O6(OH)4]·C4H9NO: First Borate with Three‐dimensional Supramolecular Framework Formed by Hydrogen Bonds and π···π Stacking Interactions9Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O1013Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate18Investigation of the second-order nonlinear optical properties of Cs2TeMo3O12 single crystal31A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36First-principles materials applications and design of nonlinear optical crystals259Two isostructural layered oxohalide compounds containing Mn2+, Te4+ and Si4+; crystal structure and magnetic susceptibility5Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 217The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)215Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67A Multifunctional 3D Chiral Porous Ferroelectric Metal–Organic Framework for Sensing Small Organic Molecules and Dye Uptake31Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8

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  1. Se2(B2O7): A New Type of Second‐Order NLO Material.

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  2. New compounds and structures in the solid state

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  5. Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters

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  10. Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems

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  19. Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties

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  22. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

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  32. Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships

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  33. Hyperpolarizabilities of Chelidamic Acid Complexes Mm(C7H3O5N)n (MCu, Ag): Theoretical Analysis

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  34. Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites

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  35. Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

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  36. Zn[Htma][ddm]: An Interesting Three-Dimensional Chiral Nonlinear Optical-Active Zinc-Trimesate Framework

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  37. Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers

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  38. New compounds and structures in the solid state

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