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RESEARCH PAPER · Angewandte Chemie · 2004

The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11

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The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11OriginalSoluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response32Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response194Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate22$^3_\infty$[Tl2Zn(ADC)2(H2O)2]: the First Coordination Polymer with Acetylenedicarboxylate (ADC2–) as Bridging Ligand containing two Different Metal Ions4Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion111Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br19A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method8CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21Chemistry, Structure, and Function of Lone Pairs in Extended Solids117Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30Spectroscopie de processus optiques non linéaires de suspensions de nano-objets non centrosymétriques.0Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16A review on the advancements in the characterization of the high-pressure properties of iodates44[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60

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  1. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie · 2008-08-28

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  2. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie International Edition · 2008-08-29

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  3. Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate

    Solid State Sciences · 2009-03-21

    Ruth Ahlers, Uwe Ruschewitz

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  4. $^3_\infty$[Tl2Zn(ADC)2(H2O)2]: the First Coordination Polymer with Acetylenedicarboxylate (ADC2–) as Bridging Ligand containing two Different Metal Ions

    Zeitschrift für anorganische und allgemeine Chemie · 2009-12-22

    Ruth Ahlers, Uwe Ruschewitz

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  5. Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion

    Inorganic Chemistry · 2011-11-10

    Zhenbo Cao, Yinchao Yue, Jiyong Yao, Zheshuai Lin, Ran He, Zhanggui Hu

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  6. Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br

    Inorganica Chimica Acta · 2013-05-06

    Zhaohui Chen, Shilie Pan, Xiaoyu Dong, Zhihua Yang, Min Zhang, Xin Su

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  7. A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups

    Journal of Materials Chemistry C · 2014-01-01

    Yin Huang, Xiang‐Gao Meng, Pifu Gong, Lei Yang, Zheshuai Lin, Xingguo Chen, Jingui Qin

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  8. K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units

    Chemistry - A European Journal · 2016-01-07

    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  9. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie International Edition · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  10. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  11. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie International Edition · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  12. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  13. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie International Edition · 2017-06-20

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  14. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie · 2017-06-20

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  15. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  16. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  17. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

    Inorganic Chemistry Frontiers · 2019-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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  18. TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)

    Chinese Journal of Physics · 2019-02-22

    Soraya Belhadj, Brahim Lagoun, Mohamed B. Taouti, Salah Khenchoul, Ali Benghia, Djamel Benbertal

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  19. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  20. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  21. Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties

    ChemistrySelect · 2019-08-06

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Yanjun Li

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  22. SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method

    Solid State Sciences · 2019-08-22

    Huimin Song, Naizheng Wang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

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  23. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie International Edition · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  24. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  25. From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution

    Chemistry - An Asian Journal · 2020-09-25

    Fei‐Fei Mao, Jiadi Liu, Jinyu Hu, Hua Wu

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  26. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  27. [ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain

    Angewandte Chemie International Edition · 2021-05-31

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  28. [o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain

    Angewandte Chemie · 2021-06-01

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  29. Chemistry, Structure, and Function of Lone Pairs in Extended Solids

    Accounts of Chemical Research · 2022-03-23

    Geneva Laurita, Ram Seshadri

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  30. Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br3

    Solid State Sciences · 2022-04-28

    Bao Jiang, Kewang Zhang, Yuchen Yan, Yanhui Zhang, Zhi Su

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  31. Spectroscopie de processus optiques non linéaires de suspensions de nano-objets non centrosymétriques.

    Unknown journal · 2022-06-28

    Kévin Bredillet

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  32. Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase

    Inorganic Chemistry · 2023-01-30

    Mingli Liang, Matthew R. Lacroix, Ce Tao, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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  33. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

    Akun Liang, Robin Turnbull, Daniel Errandonea

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  34. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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