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RESEARCH PAPER · Dalton Transactions · 2007

Syntheses, structures, and optical properties of novel zinc(ii) complexes with multicarboxylate and N-donor ligands

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Syntheses, structures, and optical properties of novel zinc(ii) complexes with multicarboxylate and N-donor ligandsOriginald10 Metal complexes assembled from isomeric benzenedicarboxylates and 3-(2-pyridyl)pyrazole showing 1D chain structures: syntheses, structures and luminescent properties145Preparation, structure, magnetic and photoluminescence properties of copper(II) and cadmium(II) frameworks with 4,4′-bipyridine-2,2′,6,6′-tetracarboxylate14Structures and Luminescent Properties of a Series of Zinc(II) and Cadmium(II) 4,4′-Oxydiphthalate Coordination Polymers with Various Ligands Based on Bis(pyridyl imidazole) under Hydrothermal Conditions110Crystal Water of Cadmium Acetate-Dependent Formation of One-Dimensional Channel Structure Based on 4,4′-bis(1-Imidazolyl)biphenyl43Three Novel Heterobimetallic Cd/Zn−Na Coordination Polymers: Syntheses, Crystal Structure, and Luminescence90Topological Diversification in Metal‐Organic Frameworks: Secondary Ligand and Metal Effects59Luminescent metal–organic frameworks4960New types of di-, tetra-, hexa- and octanuclear Ag(i) complexes containing 1,3-adamantanedicarboxylic acid74Synthesis, structure and property of cobalt(II) complexes with 3,5-di(1H-imidazol-1-yl)benzoic acid56Three novel 3D (3,8)-connected metal–organic frameworks constructed from flexible-rigid mixed ligands57Synthesis, Crystal Structure, and Photoluminescence of Coordination Polymers with Mixed Ligands and Diverse Topologies134Metal-organic frameworks constructed from monomeric, dimeric and trimeric phenanthroline citrate zinc building units18Structures, Photoluminescence, and Photocatalytic Properties of Six New Metal−Organic Frameworks Based on Aromatic Polycarboxylate Acids and Rigid Imidazole-Based Synthons211Two novel d10 frameworks based on a new V-shaped ligand 2,4′-dipyridylamine and a flexible dicarboxylate ligand8Hydrothermal syntheses, crystal structures and luminescent properties of zinc(II) coordination polymers constructed by bifunctional tetrazolate-5-carboxylate ligands63Co(II) Metal−Organic Frameworks (MOFs) Assembled from Asymmetric Semirigid Multicarboxylate Ligands: Synthesis, Crystal Structures, and Magnetic Properties125Cadmium(II) complexes with 3,5-di(1H-imidazol-1-yl)benzoate: topological and structural diversity tuned by counteranions741D, 2D, and 3D Metal−Organic Frameworks Based on Bis(imidazole) Ligands and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties135Synthesis and structures of three d10 metal coordination polymers constructed from flexible polycarboxylate and 1,10-phenanthroline ligands9Synthesis and Characterization of 3d-3d Homo- and Heterometallic Coordination Polymers with Mixed Ligands63Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands114Diverse Ni( ii ) MOFs constructed from asymmetric semi-rigid V-shaped multicarboxylate ligands: structures and magnetic properties74Three new zinc(II) coordination polymers: Modulation of extended structures driven by assistant ligands8A series of metal–organic coordination polymers assembled with disulfide ligand involving in situ cleavage of S–S under co-ligand intervention40A series of Zn(ii) coordination complexes derived from isomeric phenylenediacetic acid and dipyridyl ligands: syntheses, crystal structures, and characterizations112Divalent zinc and cadmium coordination polymers of a new flexible tetracarboxylate ligand: syntheses, crystal structures and properties36Four novel topological frameworks based on 4,4′-(hexafluoroisopropylidene)diphthalic acid and 1,1′-(1,4-butanediyl)bis(imidazole) ligand38pH-dependent self-assembly of divalent metals with a new ligand containing polycarboxylate: syntheses, crystal structures, luminescent and magnetic properties76Formation of Three New Silver(I) Coordination Polymers Involving 1,2-Phenylenediacetic Acid via the Modulation of Dipyridyl-Containing Ligands87Interpenetrating and Self-Penetrating Zinc(II) Complexes with Rigid Tripodal Imidazole-Containing Ligand and Benzenedicarboxylate157An Unusual Independent 1D Metal−Organic Nanotube with Mesohelical Structure and 1D → 2D Interdigitation62A new 3D coordination framework with helical chains in mixed ligands system: Preparation, crystal structure and magnetic property11Series of Ag(I) Coordination Complexes Derived from Aminopyrimidyl Ligands and Dicarboxylates: Syntheses, Crystal Structures, and Properties178Shape-controlled zinc(II) oxide nanomaterial constructed from three-dimensional zinc(II) coordination complex16Zn(II) metal-organic frameworks (MOFs) assembled from semirigid multicarboxylate ligands: Synthesis, crystal structures, and luminescent properties6Synthesis, spectroscopic, and structural characterization of two malate zinc coordination polymers with imidazole or 2,2′-bipyridine4Synthesis, crystal structures, and luminescent properties of Cd( ii ) coordination polymers assembled from asymmetric semi-rigid V-shaped multicarboxylate ligands56From Infinite One-Dimensional Helix to Discrete CuII15 Cluster along with in Situ SN2 Ring-Cleavage of cis-Epoxysuccinic Acid: pH-Controlled Assemblies, Crystal Structures, and Properties72Structural diversity, photoluminescence and magnet properties of complexes based on a V-shaped polycarboxylate10A series of complexes based on biphenyl-2,5,2′,5′-tetracarboxylic acid: syntheses, crystal structures, luminescent and magnetic properties48Metal-Involved Solvothermal Interconversions of Pyrazinyl Substituted Azole Derivatives: Controllability and Mechanism38Structural Investigation of Coordination Polymers Constructed from a Conformational Bis‐triazole Ligand and V‐Shaped Bridging Carboxylate Anions: Hydrothermal Syntheses, Crystal Structures, and Property Studies47pH-Dependent Ag( i ) coordination architectures constructed from 4-cyanopyridine and phthalic acid: from discrete structure to 2D sheet142Four new metal–organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 = dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid) ligand with guest-responsive photoluminescence35Benzoate acid-dependent formation of a series of interpenetrating metal–organic frameworks based on the cobalt∩1,4-bis(imidazolyl)benzene coordination substrate72Multi-functional metal–organic frameworks based on H4mdip: Crystal structure, photoluminescence, selective ion-exchange and catalysis22Syntheses, structures and photoluminescent properties of a series of Ag(i) coordination architectures based on 2,4-diamino-6-methyl-1,3,5-triazine and dicarboxylates: from a 0D discrete molecule to a 3D infinite network58Syntheses, structures and photoluminescent properties of a series of metal–organic frameworks based on a flexible tetracarboxylic acid and different bis(imidazole) ligands73Self-assembly of square-lattice copper sheets displaying intra-ferromagnetism17Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entanglement87Syntheses and Crystal Structures of a Series of Zn(II)/Cd(II) Coordination Polymers Constructed from a Flexible 6,6′-Dithiodinicotinic Acid57Two Cu(II) Complexes Constructed from 5-Methylisophthalic Acid with Structurally Similar Dipyridyl Ligands03D Chiral Microporous (10,3)-a Topology Metal–Organic Framework Containing Large Helical Channels21A new luminescent 3-D metal-organic framework of diamond-like network possessing 8-fold interpenetration12Synthesis, Characterization, and Luminescence of Two New Zinc(II) Coordination Polymers Constructed by 5‐(4‐Carboxybenzyloxy)Isophthalic Acid Ligand3A d10 Metal Coordination Polymer Containing a Thiodiphthalic Ligand: Crystal Structure and Luminescent Property4Cd(II) coordination polymers constructed from flexible disulfide ligand: Solvothermal syntheses, structures and luminescent properties23A New 5-Connected Cu(II) Complex with 5-Bromoisophthalic Acid: Synthesis, Crystal Structure, and Properties1Novel Cobalt(II) Coordination Polymers Constructed from 3,3′,4,4′-Oxydiphthalic Acid and N-Donor Ligands: Syntheses, Crystal Structures, and Magnetic Properties109Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands8Stoichiometry of N-Donor Ligand Mediated Assembly in the ZnII-Hfipbb System: From a 2-Fold Interpenetrating Pillared-Network to Unique (3,4)-Connected Isomeric Nets60Synthesis, crystal structures, thermal, and spectroscopic properties of four new metal(II) (M = Co, Ni, Cu, Hg) complexes of 2-benzoylbenzoate with 3-picoline17Synthesis, Characterization, and Crystal Structures of a Novel [Zn3(bba)6(3-pic)2] Complex (bba = 2-Benzoylbenzoat, 3-pic = 3-Picoline)6Synthesis, structures and luminescent properties of Co(II) and Ni(II) metal-organic frameworks with semirigid diphthalic ligands2pH variation induced construction of a series of entangled frameworks based on bi- and tri-metallic cores as nodes24A series of coordination polymers based on 5,5′-(ethane-1,2-diyl)-bis(oxy)diisophthalic acid and structurally related N-donor ligands: syntheses, structures and properties36Synthesis and Magnetic Properties of Two New Cobalt Complexes Constructed by Semirigid V‐shaped 5‐(4‐Carboxyphenoxy)‐pyridine‐2‐carboxylic Acid7Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005pH Influence on the Structural Variations of 4,4′-Oxydiphthalate Coordination Polymers128Effect of metal ions on the structures of metal–organic frameworks based on mixed ligands11Self-assembly and structures of new transition metal complexes with phenyl substituted pyrazole carboxylic acid and N-donor co-ligands20Synthesis, structural characterization and anion-sensing studies of metal( ii ) complexes based on 3,3′,4,4′-oxydiphthalate and N-donor ligands21A series of coordination polymers based on 5-(2-carboxybenzyloxy) isophthalic acid and bis(imidazole) ligands: syntheses, topological structures and photoluminescent properties66A series of coordination polymers based on flexible 5-carboxy-1-(4′-carboxybenzyl)-2-oxidopyridinium and structurally related N-donor ligands: syntheses, structures and photoluminescent properties20Effect of organic anions on the self-assembly of Zn(ii)-containing coordination polymers based on trigonal N-donor ligands25High structural diversity controlled by temperature and induction agent45Synthesis and characterization of two self-catenated networks and one case of pcu topology based on the mixed ligands23Two dual-emissive Zn(ii) coordination polymers with tunable photoluminescence properties35Two enantiomorphic 3D Zn(ii)–carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding23Divalent Zinc, Cobalt, and Cadmium Coordination Polymers of a New Flexible Trifunctional Ligand: Syntheses, Crystal Structures, and Properties33Synthesis and Characterization of Metal Complexes with Mixed 4-Imidazole-Containing Tripodal Ligand and Varied Dicarboxylic Acid54Syntheses, Structures, and Photoluminescent Properties of 12 New Metal–Organic Frameworks Constructed by a Flexible Dicarboxylate and Various N-Donor Ligands136Structural Diversity of Four Metal–Organic Frameworks Based on Linear Homo/Heterotrinuclear Nodes with Furan-2,5-dicarboxylic Acid: Crystal Structures and Luminescent and Magnetic Properties62Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework9Acyclic water tetramer and discrete (H2O)28 cluster with a novel topknot-shaped (H2O)24 cluster coexist in the voids of a Ag(I) polymeric solid4Fluorescence intensity decay of silver(I) coordination compound assembled from 4-(2′,3′-dicarboxylphenoxy)benzoic acid with decarboxylation-2′ via in situ5Three 3D complexes constructed from azelaic aci and rigid bis(imidazole) ligand: Syntheses, structures, thermal and photoluminescent properties13Synthesis, crystal structures and properties of lanthanide-organic frameworks based benzene carboxylates with two/three-dimensional structure24Silver(I)/cobalt(II) complexes with mixed V-shaped polycarboxylate and rod-like N-donor ligands: Syntheses, structures and properties8Auxiliary ligand-directed structural variation of the Zn(II)–1,4-bis(imidazol-1-yl)benzene net: synthesis, characterization, and luminescence6Assembly of a New Three-Dimensional Metal-Organic Framework With V-Shaped Carboxylate Ligand and Rigid N-Donor Ligand7A Coordination Polymer With a (3,4)-Connected (62.8)2(62.84) 3D Network: Synthesis, Crystal Structure and Luminescent Properties0A Crystallographic, Spectroscopic, Thermal, and DFT Investigation of Mixed Ligand Cu(II) Complexes of 2-benzoylbenzoate3Series of Inorganic–Organic Hybrid Materials Constructed From Octamolybdates and Metal–Organic Frameworks: Syntheses, Structures, and Physical Properties101Construction of four new coordination polymers based on sulfone-4,4′-biphenyldicarboxylic acid ligand: Synthesis, structures and properties13Synthesis, crystal structure, spectroscopic, thermal, catechol oxidase and catalase-like studies: New copper(II) complexes of 2-benzoylbenzoate and 2-pyridilpropanol ligands121-D helical chain, 2-D layered network and 3-D porous lanthanide–organic frameworks based on multiple coordination sites of benzimidazole-5,6-dicarboxylic acid: synthesis, crystal structure, photoluminescence and thermal stability55A series of Cu(ii) and Cd(ii) coordination polymers constructed by 3,5-dinitrosalicylic acid and flexible bis(triazole) ligands containing different spacers34Entangled Zn(ii)/Cd(ii) coordination complexes based on a flexible bis(methylbenzimidazole) ligand and different dicarboxylates48Host–guest key–lock hydrogen-bonding interactions: a rare case in the design of a V-shaped polycarboxylate Ni(ii)-based chiral coordination polymer18New metal–organic frameworks based on 2,5-thiophenedicarboxylate and pyridine- or imidazole-based spacers: syntheses, topological structures, and properties62Nonlinear Optical Properties of Coordination and Organometallic Complexes28Syntheses, structures, and photoluminescent properties of a series of coordination polymers based on a new 2′-carboxybiphenyl-4-ylmethylaminodiacetic acid and different N-donor ligands18Two-/three-dimensional open lanthanide–organic frameworks containing rigid/flexible dicarboxylate ligands: synthesis, crystal structure and photoluminescent properties87Topological evolution and photoluminescent properties of a series of divalent zinc-based metal–organic frameworks tuned via ancillary ligating spacers22Three new Ag(I) coordination architectures based on mixed ligands: Syntheses, structures and photoluminescent properties12pH-Dependent Assembly of Two Zinc(II) Complexes With 3,4,7,8-Tetramethyl-1,10-Phenanthroline and 4,4′-Oxydiphthalic Acid: Synthesis, Characterization, and Crystal Structures2Syntheses, Supramolecular Structures and Antibacterial Activities of Five Helical Transition Complexes with 5‐Chloro‐1‐phenyl‐1H‐pyrazole‐3,4‐dicarboxylic Acid2Syntheses and structures of three Mn(II) coordination polymers assembled from a dithiocarboxylic acid and N-donor ligands5Synthesis, Crystal Structures and Properties of Two Metal–Organic Frameworks Constructed from Pyridine Dicarboxylate and Flexible Bis(imidazole) Ligand8An intriguing 4d–4f heterometallic coordination polymer with 1D pseudo-nanotube architectures10A Series of Coordination Polymers Constructed from a Multidentate N-Donor Ligand and Varied Carboxylate Anions: Syntheses, Structures, and Luminescent Properties64Five bis(imidazole)-based Coordination Polymers Tuned by Central Metal Ions and S-containing Dicarboxylates: Syntheses, Structures, and Properties6Two Novel Benzenedicarboxylate-Metal Complexes: Synthesis, Crystal Structures, and Properties2Two new zinc(II) metal-organic frameworks based on 1,4-bis(2-methyl-imidazol-1-yl)butane: synthesis, structures, and properties5Crystal Structure, Multiplex Photoluminescence, and Magnetic Properties of a Series of Lanthanide Coordination Polymers Based on Quinoline Carboxylate Ligand80A series of metal–organic frameworks containing diverse secondary building units derived from a flexible triazine-based tetracarboxylic ligand12Copper(II) 2-Benzoylbenzoate Complexes Containing 2-Pyridilmethanol and 2-Pyridilethanol: Synthesis, Crystal Structures, Spectroscopic, and Thermal Properties3Seven dicarboxylate-based coordination polymers with structural varieties and different solvent resistance properties derived from the introduction of small organic linkers18A microporous Zn(ii)–MOF with open metal sites: structure and selective adsorption properties35A new 3D four-fold interpenetrated dia -like polymer: gas sorption and computational analyses2Charge-transfer metal–organic frameworks based on CuCN architecture units: crystal structures, luminescence properties and theoretical investigations7Positional isomerism of unsymmetrical semirigid ligands toward the construction of discrete and infinite coordination architectures of zinc(ii) and cadmium(ii) complexes19Solvents and auxiliary ligands co-regulate three antiferromagnetic Co( ii ) MOFs based on a semi-rigid carboxylate ligand44Structure versatility of coordination polymers constructed from a semirigid ligand and polynuclear metal clusters47Syntheses, structures, and properties of six new coordination polymers constructed from N-heterocyclic multicarboxylic acids10Tuning Different Kinds of Entangled Networks by Varying N-Donor Ligands: From Self-Penetrating to Multi-interpenetrating70Syntheses, crystal structures, and antibacterial activities of helical M(II) phenyl substituted pyrazole carboxylate complexes10Imidazole-based zinc(II) complexes: Highly selective fluorescent probes for acetone detection18Ten Coordination Polymers Constructed Using an Unprecedented Azamacrocyclic Octacarboxylate Ligand 1,4,8,11-Tetrazacyclododecane-N,N′,N″,N‴-Tetra-Methylene-Isophthalic Acid: Syntheses, Structures, and Photoluminescent Properties70Synthesis, characterization, crystal structures, enzyme inhibition, DNA binding, and electrochemical studies of zinc(II) complexes24A Highly Stable 3D Acentric Zinc Metal–Organic Framework Based on Two Symmetrical Flexible Ligands: High Second-Harmonic-Generation Efficiency and Tunable Photoluminescence32A Novel Aqua Ligand Assisted Water Octamer Confinement in the Hydrophilic Channels of a Zn(II) Supramolecular Architecture4Hydrothermal synthesis and structure characterization of two six-connected metal–organic frameworks based on the mixed ligands1Structures, photoluminescence and heterogeneous catalysis of five metal complexes constructed by a flexible tricarboxylate ligand11Syntheses, structures and fluorescent properties of cadmium coordination polymers based on 2,3′,5,5′-biphenyl tetracarboxylate and N-donor ancillary ligands19Three mixed-ligand coordination networks modulated by flexible N-donor ligands: syntheses, topological structures, and temperature-sensitive luminescence properties35Influence of the steric effect of flexible isomeric phenylenediacetic acids on the resultant lead(II) coordination polymers7Two Coordination Polymers Based on 3‐(Carboxymethoxy)benzene‐1,2‐dioic Acid and N‐donor Ancillary Ligands: Synthesis, Crystal structures, and Magnetic Properties2Synthesis and structures of copper(II) and cadmium(II) compounds based on pyridazine derivative ligands3Three resorcin[4]arene-based complexes with Cu( ii )-exchange characteristics and fluorescence sensing of polyoxometalates in aqueous solutions8Distinct 3D CdII Coordination Polymers with 1,2-Naphthalenedicarboxylate Regulated by Dipyridyl Co-Ligands with Different Spacers0Ag(I) and Cu(II) Coordination Polymers of Pyridylmethyl-Benzimidazole Ligand: Syntheses, Crystal Structure, and Influence of Metal Ion0New examples of d10 metal–organic frameworks based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Synthesis, crystal structure and luminescence10A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO 2 adsorption properties12Amide-containing zinc( ii ) metal–organic layered networks: a structure–CO 2 capture relationship16Structural diversification and photocatalytic properties of zinc( ii ) polymers modified by auxiliary N-containing ligands35Zinc( ii )– and cadmium( ii )–organic frameworks with 1-imidazole-containing and 1-imidazole-carboxylate ligands76Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands8A Cationic Two-Dimensional Zn(II) Coordination Polymer, Crystal Structure and Fluorescence Emission2

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  30. Interpenetrating and Self-Penetrating Zinc(II) Complexes with Rigid Tripodal Imidazole-Containing Ligand and Benzenedicarboxylate

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  31. An Unusual Independent 1D Metal−Organic Nanotube with Mesohelical Structure and 1D → 2D Interdigitation

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  42. Structural Investigation of Coordination Polymers Constructed from a Conformational Bis‐triazole Ligand and V‐Shaped Bridging Carboxylate Anions: Hydrothermal Syntheses, Crystal Structures, and Property Studies

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  43. pH-Dependent Ag( i ) coordination architectures constructed from 4-cyanopyridine and phthalic acid: from discrete structure to 2D sheet

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  44. Four new metal–organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 = dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid) ligand with guest-responsive photoluminescence

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  45. Benzoate acid-dependent formation of a series of interpenetrating metal–organic frameworks based on the cobalt∩1,4-bis(imidazolyl)benzene coordination substrate

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  46. Multi-functional metal–organic frameworks based on H4mdip: Crystal structure, photoluminescence, selective ion-exchange and catalysis

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  49. Self-assembly of square-lattice copper sheets displaying intra-ferromagnetism

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