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RESEARCH PAPER · Inorganic Chemistry · 2010

A Series of New Phases Containing Three Different Asymmetric Building Units

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A Series of New Phases Containing Three Different Asymmetric Building UnitsOriginalExplorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23ChemInform Abstract: A Series of New Phases Containing Three Different Asymmetric Building Units.0Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides9[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Explorations of new selenites of the group IIIA and IVA metals13Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites2Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units20New 3-D polyoxovanadoborate architectures based on [V12B18O60]16− clusters38Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd10(SeO3)8Br4]·HBr·H2O6α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22A series of new 3-D boratopolyoxovanadates containing five types of [KxOy]n building units23Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Revised Bismuth Chloroselenite System: Evidence of a Noncentrosymmmetric Structure with a Giant Unit Cell23Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites18New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O813Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)232Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10A series of new silver selenites with d 0 -TM cations19Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response18Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3)22Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 108(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties30Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response63Study of the Structural Characteristics, Optical Properties and Electrical Conductivity of Doped [P(An-Mma)/Zro2]Tf Nanofiber Composite Using Experimental Data and Td-Dft/Dmol3 Computations1Study of the structural characteristics, optical properties, and electrical conductivity of doped [P(An-MMa)/ZrO2]TF nanofiber composite using experimental data and TD-DFT/DMol3 computations5[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Syntheses, Crystal Structure, and Second Harmonic Generation Response of Four Novel Noncentrosymmetric Tellurites of Quaternary A/M/Te/O (A = Ba, Sr, Ca; M = V, Nb, Ta) System: BaTa4Te3O17, BaNb4Te3O17, SrTa4Te3O17, and CaV2TeO84Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering17Transformation of Kagomé and Breathing Kagomé Lattices Induced by Ion Replacement3Synthesis of Four Isomeric Phases of CdVO(SeO3)2 and Characterization of Their Structural, Thermal, and Magnetic Properties2

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  1. Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems

    Dalton Transactions · 2010-01-01

    Pei-Xin Li, Suyun Zhang, Jiang‐Gao Mao

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  2. ChemInform Abstract: A Series of New Phases Containing Three Different Asymmetric Building Units.

    ChemInform · 2010-08-12

    Pei‐Xin Li, Fang Kong, Chun‐Li Hu, Na Zhao, Jiang‐Gao Mao

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  3. Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

    Inorganic Chemistry · 2010-11-23

    Suyun Zhang, Chun‐Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  4. A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems

    Dalton Transactions · 2011-01-01

    Qian-Hua Gu, Chun‐Li Hu, Jian‐Han Zhang, Jiang‐Gao Mao

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  5. Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides

    Dalton Transactions · 2011-01-01

    Tianxiang Zhu, Jingui Qin, P. Shiv Halasyamani

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  6. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  7. Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites

    Inorganic Chemistry · 2011-04-28

    Suyun Zhang, Jiang‐Gao Mao

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  8. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang-Hwan Kim, P. Shiv Halasyamani

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  9. Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS5

    Inorganic Chemistry · 2011-05-19

    Lei Geng, Wen‐Dan Cheng, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He

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  10. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

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  11. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  12. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

    Inorganic Chemistry · 2012-02-01

    Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  13. Explorations of new selenites of the group IIIA and IVA metals

    Journal of Solid State Chemistry · 2012-02-15

    Fang Kong, Pei-Xin Li, Suyun Zhang, Jiang‐Gao Mao

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  14. Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates

    Journal of Solid State Chemistry · 2012-04-21

    Junhui Liu, Zhangzhen He, Fang Kong, Xiang Xu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  15. Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites

    Journal of Solid State Chemistry · 2012-08-14

    Junhui Liu, Fang Kong, Yanli Gai, Jiang‐Gao Mao

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  16. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

    Inorganic Chemistry · 2012-08-23

    Sau Doan Nguyen, P. Shiv Halasyamani

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  17. A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units

    Dalton Transactions · 2012-11-30

    Jian Zhou, Xing Liu, Rong Chen, Fei-Long Hu, Hua‐Hong Zou, Meixiao Wei

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  18. New 3-D polyoxovanadoborate architectures based on [V12B18O60]16− clusters

    CrystEngComm · 2013-01-01

    Jian Zhou, Xing Liu, Rong Chen, Hong‐Ping Xiao, Fei-Long Hu, Hua‐Hong Zou, Yun Zhou, Chun Liu, Ligang Zhu

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  19. Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement

    Chemical Communications · 2013-01-01

    Xue‐Li Cao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  20. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  21. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

    Inorganic Chemistry · 2013-03-18

    Eun Pyo Lee, Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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  22. Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd10(SeO3)8Br4]·HBr·H2O

    Journal of Solid State Chemistry · 2013-06-03

    Wen‐Tong Chen, Ming‐Sheng Wang, Guan‐E Wang, Hui-Fen Chen, Guo‐Cong Guo

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  23. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  24. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

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  25. A series of new 3-D boratopolyoxovanadates containing five types of [KxOy]n building units

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  26. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

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  27. Revised Bismuth Chloroselenite System: Evidence of a Noncentrosymmmetric Structure with a Giant Unit Cell

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  28. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

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  29. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

    Dalton Transactions · 2014-05-09

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  30. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

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  31. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  32. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

    Journal of Solid State Chemistry · 2014-09-30

    Hyun Sun Ahn, Eun Pyo Lee, Hong‐Young Chang, Dong Woo Lee, Kang Min Ok

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  33. Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites

    Dalton Transactions · 2015-01-01

    Xue‐Li Cao, Fang Kong, Zhangzhen He, Jiang‐Gao Mao

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  34. pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites

    Inorganic Chemistry · 2015-02-17

    Vadim M. Kovrugin, Marie Colmont, Christine Terryn, S. Colis, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

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  35. New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O8

    Journal of Alloys and Compounds · 2015-03-05

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  36. Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2

    Journal of Alloys and Compounds · 2015-04-11

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  37. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

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  38. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

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  39. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  40. A series of new silver selenites with d 0 -TM cations

    RSC Advances · 2016-01-01

    Qian Qian, Fang Kong, Jiang‐Gao Mao

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  41. Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response

    Dalton Transactions · 2016-01-01

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  42. Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism

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  43. Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3)

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  44. Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 10

    Journal of Solid State Chemistry · 2017-02-21

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  45. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

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  46. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

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  47. New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties

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  48. Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response

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  49. Study of the Structural Characteristics, Optical Properties and Electrical Conductivity of Doped [P(An-Mma)/Zro2]Tf Nanofiber Composite Using Experimental Data and Td-Dft/Dmol3 Computations

    SSRN Electronic Journal · 2022-01-01

    El‐Refaie Kenawy, Ali A. Ibrahim, Ahmed F. Al‐Hossainy

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  50. Study of the structural characteristics, optical properties, and electrical conductivity of doped [P(An-MMa)/ZrO2]TF nanofiber composite using experimental data and TD-DFT/DMol3 computations

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