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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical propertiesOriginalFrom CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap21Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF42A survey of stereoactive oxysalts for linear and nonlinear optical applications40Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22Synthesis and structure-dependent optical properties of two new organic–inorganic hybrid antimony( iii ) chlorides191D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance2Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters48Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap16Unearthing Superior Inorganic UV Second‐Order Nonlinear Optical Materials: A Mineral‐Inspired Method Integrating First‐Principles High‐Throughput Screening and Crystal Engineering124Unearthing Superior Inorganic UV Second‐Order Nonlinear Optical Materials: A Mineral‐Inspired Method Integrating First‐Principles High‐Throughput Screening and Crystal Engineering4Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System7Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units18Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence18[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence4K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection1Pb2ScOF5: A Rare Oxyfluoride with Ultrawide Transparency Enabled by a Differentiated Fluorination Strategy0

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  1. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

    Inorganic Chemistry Frontiers · 2023-01-01

    Pengfei Li, Chun‐Li Hu, Bing-Xuan Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  2. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  3. AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2023-05-24

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF4

    Inorganic Chemistry · 2023-06-14

    Tong Su, Meiqiao Wei, Hanqing Liu, Yun-Shan Fang, Qiong Wu, Zhehui Weng, Jie Ling, Renjie Chen, Yulan Wang, Xiusha Zhao, Haidong Ju

    Read original paper ↗ ·

  5. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  6. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

    Advanced Optical Materials · 2023-09-01

    Pengfei Li, Ya-Ping Gong, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  7. Synthesis and structure-dependent optical properties of two new organic–inorganic hybrid antimony( iii ) chlorides

    Dalton Transactions · 2023-11-23

    Xuemei Wen, Juan Cheng, Peiqi Qian, Zhizhuan Zhang, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin

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  8. 1D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence

    Dalton Transactions · 2024-01-01

    Zhiyuan Wu, Muxin Yu, Ziqing Zhang, Jiaxin Jiang, Ting Liu, Feilong Jiang, Lian Chen, Maochun Hong

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  9. A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

    Materials Horizons · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  10. Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance

    Journal of Materials Chemistry C · 2024-01-01

    Wenjing Tan, Xuefan Wang, Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  11. Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters

    Chemical Science · 2024-01-01

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  12. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  13. Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

    Chemical Science · 2024-01-01

    Dandan Zhou, Chun‐Li Hu, Xinwei Zhang, Jiang‐Gao Mao, Fang Kong

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  14. Unearthing Superior Inorganic UV Second‐Order Nonlinear Optical Materials: A Mineral‐Inspired Method Integrating First‐Principles High‐Throughput Screening and Crystal Engineering

    Angewandte Chemie International Edition · 2024-01-23

    Xuehua Dong, Hongbo Huang, Ling Huang, Yuqiao Zhou, Bingbing Zhang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  15. Unearthing Superior Inorganic UV Second‐Order Nonlinear Optical Materials: A Mineral‐Inspired Method Integrating First‐Principles High‐Throughput Screening and Crystal Engineering

    Angewandte Chemie · 2024-01-23

    Xuehua Dong, Hongbo Huang, Ling Huang, Yuqiao Zhou, Bingbing Zhang, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  16. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  17. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  18. Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System

    Inorganic Chemistry · 2024-11-12

    Qingwen Zhu, Yong Tao, Can Yang, Jie Gou, Yaolong Zhu, Xuefei Wang, Qi Wu

    Read original paper ↗ ·

  19. Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties

    Dalton Transactions · 2025-01-01

    Maqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie Li

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  20. Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units

    Chemical Science · 2025-01-01

    Bo Zhang, Sheng-Hua Zhou, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  21. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

    Read original paper ↗ ·

  22. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·

  23. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie International Edition · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  24. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  25. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  26. Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection

    Inorganic Chemistry · 2025-12-03

    Wei Chen, Zi-Xuan Zhao, Chao He, Mengjiao Xu, Hui‐Yan Zhao, Qi Wei, Guo‐Ming Wang

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  27. Pb2ScOF5: A Rare Oxyfluoride with Ultrawide Transparency Enabled by a Differentiated Fluorination Strategy

    Inorganic Chemistry · 2026-10-13

    Zelong Liu, Conggang Li, Huijian Zhao, Ning Jia, Ning Ye, Zhanggui Hu

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