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RESEARCH PAPER · Coordination Chemistry Reviews · 2023

Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulationOriginalNitride Wide-Bandgap Semiconductors for UV Nonlinear Optics3Birefringent Dispersion Optimization to Achieve Superior Nonlinear Optical Phase Matching in Deeper Solar‐Blind UV Band from KH 2 PO 4 to BeH 3 PO 516A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies14(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance311D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction6Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence6UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16Phase Matching of Infrared Nonlinear Optical Salt-Inclusion Chalcogenides Achieved by the Modulation of the Fractal Dimension of Anionic Motifs18Optical and mechanical stability of Tutton’s salt crystal of Cu2+ doped ammonium cobalt(II) sulfate hexahydrate15Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy6The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region14(C 3 H 5 N 2 ) 3 [Be 2 F 7 ]: the first imidazolium fluoroberyllate with a non-centrosymmetric structure based on linear tetrahedral [Be 2 F 7 ] 3− anions2Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 252D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses5Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Multifunctional characterization of L-tartaric acid influenced potassium aluminium sulfate crystal for photonic device integration0π-Conjugated unit bridge for giant second-harmonic generation and birefringence in hybrid materials with dual heteroleptic polyhedra5Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1Thermal, Structural, and Phase Evolution of the Y2(SO4)3*8H2O–Eu2(SO4)3*8H2O System via Dehydration and Volatilization to Y2(SO4)3–Eu2(SO4)3 and Y2O2(SO4)–Eu2O2(SO4) and Its Thermal Expansion0Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution0Simultaneously switching both the magnetic behaviors and nonlinear optical processes in mononuclear DyIII complexes0An UV Transparent Metal‐Free Sulfate With Giant Birefringence Enabled by Optimal Structural Anisotropy4Simultaneously switching both the magnetic behavior and nonlinear optical process in mononuclear DyIII complexes via the coordination role of enantiopure N3-pincers2Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention1The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4Hydrogen-Bond-Directed Assembly of an Intramolecular Charge-Transfer Compound for Second-Order Nonlinear Optics1First Principles Calculations of Structures, Mechanical and Vibrational Properties of Nonlinear Optical LiZnCO3(OH) and NaZnCO3(OH) Crystals0The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates1Tuning linear and nonlinear optical performances of two eight- and nine-coordinated chiral SmIII enantiomeric pairs by enantiopure N-donor ligands1Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations0Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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  2. Birefringent Dispersion Optimization to Achieve Superior Nonlinear Optical Phase Matching in Deeper Solar‐Blind UV Band from KH 2 PO 4 to BeH 3 PO 5

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  3. A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies

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  4. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

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  14. Optical and mechanical stability of Tutton’s salt crystal of Cu2+ doped ammonium cobalt(II) sulfate hexahydrate

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  15. Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

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  16. The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region

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