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RESEARCH PAPER · Angewandte Chemie International Edition · 2022

Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties

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Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy PropertiesOriginalY(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity15A survey of stereoactive oxysalts for linear and nonlinear optical applications40Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions25Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies10UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Polar Layered Magnet Ba 2 Cu 3 (SeO 3 ) 4 F 2 Composed of Bitriangular Chains: Observation of 1/3-Magnetization Plateau5Toward Strong UV–Vis–NIR Second-Harmonic Generation by Dimensionality Engineering of Zinc Thiocyanates32RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6Chemical Origins of Optically Addressable Spin States in Eu 2 (P 2 S 6 ) and Eu 2 (P 2 Se 6 )2Noncollinear polar magnet Fe2(SeO3)3(H2O)3 with inequivalent Fe3+ sites1A Record-High Cryogenic Magnetocaloric Effect Discovered in EuCl2 Compound41Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Cryogenic magnetocaloric effect of rare-earth halide perovskites CsEuCl3 and CsEuBr32Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0Synthesis and Characterizations of Two-Dimensional Rare-Earth Magnetic Compounds RE2O2CN2 (RE = Nd, Dy, Gd) with a Frustrated Triangular Spin–Lattice4Supercritical hydrothermal synthesis, magnetism, and rotating magnetocaloric effect of fluorocarbonates K4RE2(CO3)3F4 (RE = Ce, Pr, Nd, Sm, Eu, Tb, and Dy) with rare-earth dimers RE2O12F40Inductive-Effect-Driven Tunability of Magnetism and Luminescence in Triangular Layers ANd(SO4)2 (A = Rb, Cs)0Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Multifunctional potassium-doped L-histidine hydrochloride crystals: optoelectronic properties and cytocompatibility studies0Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1Magnetic properties and cryogenic magnetocaloric effect in Dy2Hf2O7 ceramics1Magnetic Copper Selenite-Sulfate Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with T26-Type Non-Archimedean Lattice Featuring a Robust 1/3-Magnetization Plateau2Chiral Polar Eu 2 (SeO 3 ) 2 (SO 4 )(H 2 O) 2 : A Pathway Toward Narrow Optical Line Widths and Microsecond Lifetimes for Quantum Memory Candidates1Polar Oxalate Fluoride KMn(C 2 O 4 )F with Triangular Arrangements of Mn 2+ –F–Mn 2+ Spin Chains: Nonlinear Optical and Magnetic Properties0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0

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  1. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  2. Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity

    Chinese Chemical Letters · 2023-07-06

    Ang Li, Yanhong Wang, Haotian Tian, Alimujiang Yalikun, Yves Journaux, Min Luo, Hongcheng Lu

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  3. A survey of stereoactive oxysalts for linear and nonlinear optical applications

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  4. Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties

    Chemistry of Materials · 2023-08-14

    Zixian Jiao, Osvaldo Medina Mireles, Kevin Ensz, Fei Wang, Mingli Liang, P. Shiv Halasyamani, Bingbing Zhang, D. Paul Rillema, Jian Wang

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  5. Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

    Advanced Science · 2023-10-23

    Yun‐Xiang Ma, Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  6. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

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  7. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

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  8. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

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  9. Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies

    Journal of Materials Chemistry C · 2024-01-01

    Lili Liu, Junbo Wang, Bingchen Xiao, Xunchi Li, Yaoqing Chu, Tongqing Sun, P. Shiv Halasyamani

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  10. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

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  11. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

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  12. Polar Layered Magnet Ba 2 Cu 3 (SeO 3 ) 4 F 2 Composed of Bitriangular Chains: Observation of 1/3-Magnetization Plateau

    Chemistry of Materials · 2024-08-12

    Alimujiang Yalikun, Yanhong Wang, Nian Shi, Yiwen Chen, Hao Huang, Hyun‐Joo Koo, Zhongwen Ouyang, Zhengcai Xia, Reinhard Karl Kremer, Myung‐Hwan Whangbo, Hongcheng Lu

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  13. Toward Strong UV–Vis–NIR Second-Harmonic Generation by Dimensionality Engineering of Zinc Thiocyanates

    Journal of the American Chemical Society · 2024-10-07

    Haijun Zhang, Xingxing Jiang, Yiran Zhang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Jun Xu, Jinhu Yang, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  14. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

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    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  15. Chemical Origins of Optically Addressable Spin States in Eu 2 (P 2 S 6 ) and Eu 2 (P 2 Se 6 )

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  16. Noncollinear polar magnet Fe2(SeO3)3(H2O)3 with inequivalent Fe3+ sites

    APL Materials · 2024-12-01

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  17. A Record-High Cryogenic Magnetocaloric Effect Discovered in EuCl2 Compound

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  18. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

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  19. Cryogenic magnetocaloric effect of rare-earth halide perovskites CsEuCl3 and CsEuBr3

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  20. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

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  22. Synthesis and Characterizations of Two-Dimensional Rare-Earth Magnetic Compounds RE2O2CN2 (RE = Nd, Dy, Gd) with a Frustrated Triangular Spin–Lattice

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  23. Supercritical hydrothermal synthesis, magnetism, and rotating magnetocaloric effect of fluorocarbonates K4RE2(CO3)3F4 (RE = Ce, Pr, Nd, Sm, Eu, Tb, and Dy) with rare-earth dimers RE2O12F4

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  24. Inductive-Effect-Driven Tunability of Magnetism and Luminescence in Triangular Layers ANd(SO4)2 (A = Rb, Cs)

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  25. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

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  27. Multifunctional potassium-doped L-histidine hydrochloride crystals: optoelectronic properties and cytocompatibility studies

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