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RESEARCH PAPER · Chemistry of Materials · 1998

Synthesis and Characterization of Se4Nb2O13: A New Ternary Se4+−Nb5+−Oxide with Monoselenite and Diselenite Groups

P. Shiv Halasyamani, Dermot O’Hare

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Synthesis and Characterization of Se4Nb2O13: A New Ternary Se4+−Nb5+−Oxide with Monoselenite and Diselenite GroupsOriginalChemInform Abstract: Synthesis and Characterization of Se4Nb2O13: A New Ternary Se4+—Nb5+—Oxide with Monoselenite and Diselenite Groups.0Chapter 21. New compounds and structures1Synthesis and Characterization of Non-centrosymmetric TeSeO461Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses336Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)284A novel polyoxo(thio)molybdenum( V ) sulfite compound: Synthesis and crystal structure of {[Mo 2 V (μ-S) 2 O 2 ] 6 (μ 3 -SO 3 ) 4 (μ-SO 3 ) 12 } 20− anion23Polyoxovanadium( IV ) Sulfite Compounds: Synthesis, Structural, and Physical Studies34Polyoxovanadium( IV ) Sulfite Compounds: Synthesis, Structural, and Physical Studies10New alkali–metal–molybdenum(VI)–selenium(IV) oxides: syntheses, structures, and characterization of A2SeMoO6 (A=Na+, K+, or Rb+)67A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies41Selenium Oxoanion Compounds of Palladium(II)25Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O47Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O81Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines9Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O13A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O887K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H3210Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H2412A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25Bi[NC5H3(CO2)2](OH2)xF (x=1 and 2): New one-dimensional Bi-coordination materials—Reversible hydration and topotactic decomposition to α-Bi2O316UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O1013Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF622Crystal growth, physical properties and computational insights of semi-organic non-linear optical crystal diphenylguanidinium perchlorate grown by conventional solvent evaporation method26Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Spiral Graphene Nanoribbons with Azulene Defects as Potential Nonlinear Optical Materials43Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O122Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency2Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence0

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  1. ChemInform Abstract: Synthesis and Characterization of Se4Nb2O13: A New Ternary Se4+—Nb5+—Oxide with Monoselenite and Diselenite Groups.

    ChemInform · 1998-05-12

    P. Shiv Halasyamani, Dermot O’Hare

    Read original paper ↗ ·

  2. Chapter 21. New compounds and structures

    Annual Reports Section A (Inorganic Chemistry) · 1999-01-01

    William T. A. Harrison

    Read original paper ↗ ·

  3. Synthesis and Characterization of Non-centrosymmetric TeSeO4

    Inorganic Chemistry · 2001-02-10

    Yetta Porter, Nattamai S. P. Bhuvanesh, P. Shiv Halasyamani

    Read original paper ↗ ·

  4. Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses

    Journal of the American Chemical Society · 2002-02-08

    Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  5. Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)2

    Inorganic Chemistry · 2002-02-13

    Philip M. Almond, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  6. A novel polyoxo(thio)molybdenum( V ) sulfite compound: Synthesis and crystal structure of {[Mo 2 V (μ-S) 2 O 2 ] 6 (μ 3 -SO 3 ) 4 (μ-SO 3 ) 12 } 20− anion

    Dalton Transactions · 2003-01-01

    Haralampos N. Miras, J. Derek Woollins, Alexandra M. Z. Slawin, Raphael G. Raptis, P. Baran, Themistoklis A. Kabanos

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  7. Polyoxovanadium( IV ) Sulfite Compounds: Synthesis, Structural, and Physical Studies

    Angewandte Chemie International Edition · 2003-01-27

    Manolis J. Manos, Haralampos N. Miras, V. Tangoulis, J. Derek Woollins, Alexandra M. Z. Slawin, Themistoklis A. Kabanos

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  8. Polyoxovanadium( IV ) Sulfite Compounds: Synthesis, Structural, and Physical Studies

    Angewandte Chemie · 2003-01-27

    Manolis J. Manos, Haralampos N. Miras, V. Tangoulis, J. Derek Woollins, Alexandra M. Z. Slawin, Themistoklis A. Kabanos

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  9. New alkali–metal–molybdenum(VI)–selenium(IV) oxides: syntheses, structures, and characterization of A2SeMoO6 (A=Na+, K+, or Rb+)

    Journal of Solid State Chemistry · 2003-07-22

    Yetta Porter, P. Shiv Halasyamani

    Read original paper ↗ ·

  10. A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies

    Chemistry - A European Journal · 2005-02-01

    Haralampos N. Miras, Raphael G. Raptis, Nikolia Lalioti, Michael P. Sigalas, P. Baran, Themistoklis A. Kabanos

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  11. Selenium Oxoanion Compounds of Palladium(II)

    Inorganic Chemistry · 2007-06-12

    Jie Ling, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  12. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O

    Inorganic Chemistry · 2009-04-09

    Xiaoyun Fan, Shilie Pan, Xueling Hou, Gang Yu Liu, Jide Wang

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  13. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O

    Inorganic Chemistry · 2009-07-22

    Yongjiang Wang, Shilie Pan, Xuelin Tian, Zhongxiang Zhou, Gang Yu Liu, Jide Wang, Dianzeng Jia

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  14. Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines

    Inorganica Chimica Acta · 2010-06-17

    Yun Mo Yang, Shilie Pan, Xueling Hou, Jing Guo, Feng Li, Jian Wei Han, Jixi Guo, Dianzeng Jia

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  15. Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O

    Solid State Sciences · 2010-10-30

    Yi Zhao, Shilie Pan, Feng Li, Yongjiang Wang, Xiaoyun Fan, Xiaoyu Dong, Dianzeng Jia, Jixi Guo, Zhongxiang Zhou

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  16. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

    Journal of Materials Chemistry · 2011-01-01

    Yun Mo Yang, Shilie Pan, Xueling Hou, Chuanyi Wang, Kenneth Reinhard Poeppelmeier, Zhaohui Chen, Hongping Wu, Zhongxiang Zhou

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  17. A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems

    Dalton Transactions · 2011-01-01

    Qian-Hua Gu, Chun‐Li Hu, Jian‐Han Zhang, Jiang‐Gao Mao

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  18. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

    Inorganic Chemistry · 2011-02-21

    Yun Mo Yang, Shilie Pan, Hongyi Li, Jian Wei Han, Zhaohui Chen, Wenwu Zhao, Zhongxiang Zhou

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  19. New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8

    Inorganic Chemistry · 2011-04-12

    Dong Woo Lee, Seung‐Jin Oh, P. Shiv Halasyamani, Kang Min Ok

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  20. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

    Journal of the American Chemical Society · 2011-05-02

    Hongping Wu, Shilie Pan, Kenneth Reinhard Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Mo Yang, James M. Rondinelli, Haosu Luo

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  21. Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32

    Materials Chemistry and Physics · 2011-05-11

    Hongyi Li, Shilie Pan, Hongping Wu, Zhihua Yang

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  22. Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24

    Journal of Materials Science · 2011-06-20

    Jiang Luo, Shilie Pan, Hongyi Li, Zhongxiang Zhou, Zhihua Yang

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  23. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

    Crystal Growth & Design · 2011-07-15

    Yun Mo Yang, Shilie Pan, Jian Wei Han, Xueling Hou, Zhongxiang Zhou, Wenwu Zhao, Zhaohui Chen, Min Zhang

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  24. Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl

    CrystEngComm · 2011-10-19

    Hongping Wu, Shilie Pan, Hongwei Yu, Dianzeng Jia, Aiming Chang, Hongyi Li, Fangfang Zhang, Xia Huang

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  25. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

    Journal of Materials Chemistry · 2011-12-13

    Hongwei Yu, Shilie Pan, Hongping Wu, Wenwu Zhao, Fangfang Zhang, Hongyi Li, Zhihua Yang

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  26. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group

    Journal of Materials Chemistry · 2012-01-01

    Hongwei Yu, Hongping Wu, Shilie Pan, Zhihua Yang, Xin Su, Fangfang Zhang

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  27. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

    CrystEngComm · 2012-01-01

    Yun Mo Yang, Shilie Pan, Xueling Hou, Xiaoyu Dong, Xin Su, Zhihua Yang, Min Zhang, Wenwu Zhao, Zhaohui Chen

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  28. Bi[NC5H3(CO2)2](OH2)xF (x=1 and 2): New one-dimensional Bi-coordination materials—Reversible hydration and topotactic decomposition to α-Bi2O3

    Journal of Solid State Chemistry · 2012-01-09

    Hye Rim Jeon, Dong Woo Lee, Kang Min Ok

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  29. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units

    Inorganic Chemistry · 2012-01-19

    Li Wang, Shilie Pan, Li‐Xian Chang, Jianyang Hu, Hongwei Yu

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  30. Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations

    Journal of Solid State Chemistry · 2012-09-25

    Zhihua Yang, Shilie Pan, Hongwei Yu, Ming‐Hsien Lee

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  31. Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O10

    CrystEngComm · 2013-12-18

    Yun Mo Yang, Xin Su, Shilie Pan, Min Zhang, Ying Wang, Jian Wei Han, Zhihua Yang

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  32. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

    Journal of Materials Chemistry C · 2014-01-01

    Xiaoxia Nina Lin, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Hongwei Yu, Fangyuan Zhang, Fangyuan Zhang, Xiaoyu Dong, Shujuan Han, Lingyun Dong, Chunyan Bai, Zheng Wang

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  33. Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response

    Journal of the American Chemical Society · 2014-01-06

    Hongwei Yu, Hongping Wu, Shilie Pan, Zhihua Yang, Xueling Hou, Xin Su, Qun Jing, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  34. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  35. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  36. Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF6

    Zeitschrift für anorganische und allgemeine Chemie · 2017-09-29

    Wenyao Zhang, Qun Jing, Yuan Fang, Zhaohui Chen

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  37. Crystal growth, physical properties and computational insights of semi-organic non-linear optical crystal diphenylguanidinium perchlorate grown by conventional solvent evaporation method

    Journal of Crystal Growth · 2017-11-06

    M.S. Kajamuhideen, K. Sethuraman, Kandasamy Ramamurthi, P. Ramasamy

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  38. Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals

    International Scientific-Technical Conference on Actual Problems of Electronic Instrument Engineering (APEIE) · 2018-10-01

    Boris I. Kidyarov, Vladimir K. Makukha

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  39. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019-01-01

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

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  40. Spiral Graphene Nanoribbons with Azulene Defects as Potential Nonlinear Optical Materials

    ACS Applied Nano Materials · 2019-02-27

    Yuanyuan He, Jiu Chen, Xue-Lian Zheng, Xiaodong Xu, Weiqi Li, Ling Yang, Wei Quan Tian

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  41. Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O12

    Journal of Physics and Chemistry of Solids · 2019-07-18

    Kun Chai, Hongyi Li

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  42. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

    Dalton Transactions · 2020-01-01

    Huanke Zhao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  43. Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency

    Dalton Transactions · 2024-01-01

    Jing Chai, Yuheng She, Jinmiao Jiao, Lili Li, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  44. Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Xize Zhan, Gangji Yi, Xuan Zou, Gen Li, Lu Liu, Jiarong Lv, Hongmei Zeng, Zhien Lin, Guohong Zou

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