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RESEARCH PAPER · Chemistry - A European Journal · 2005

A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies

Haralampos N. Miras, Raphael G. Raptis, Nikolia Lalioti, Michael P. Sigalas, P. Baran, Themistoklis A. Kabanos

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A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical StudiesOriginalA novel compound with a 1D network structure constructed by [(VIVO)6(μ4-O)2(μ3-OH)2(μ3-SO3)4]2–/SO32– and 4,4′-bipyridine components: its synthesis, characterization, and magnetic behavior18A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies.1Polyoxomolybdenum(V/VI)−Sulfite Compounds: Synthesis, Structural, and Physical Studies26New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand17Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−53Polynuclear Cobalt(II/III) Sulfites: Synthesis, Structure, and Magnetic Properties of the Octanuclear Cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])·10H2O Encapsulating a Lithium Cation28X-ray characterization of HnacnacR and the first vanadium β-diiminate dimer (R = mesityl)1New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides13Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry242Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites10Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}37Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9The Highest-Nuclearity Manganese/Oximate Complex: An Unusual MnII/III15 Cluster with an S = 6 Ground State37Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO 3 2 − : {Mo 12 V 12 Te 3 }, {Mo 12 V 12 Te 2 } and {Mo 17 V 8 Te}44Expanding molecular transition metal cubane clusters of the form [M4(μ3-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = VV and WV12THE CRYSTAL STRUCTURE OF THE ELUSIVE HUEMULITE23Controlling the Self‐Assembly of a Mixed‐Metal Mo/V–Selenite Family of Polyoxometalates34Sulfite Anions as Structure‐Directing Templates for the Engineering of Modular Polyoxometalates18Synthesis and characterizations of the first [V16O39Cl]6− (V16O39) polyanion13Two new 3-D boratopolyoxovanadate architectures based on the [V12B16O50(OH)8]12− cluster with different metal linkers26Assembly of Thiometalate‐Based {Mo 16 } and {Mo 36 } Composite Clusters Combining [Mo 2 O 2 S 2 ] 2+ Cations and Selenite Anions70A series of new 3-D boratopolyoxovanadates containing five types of [KxOy]n building units23Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties9pH-Controlled and Sulfite Anion-Directed Assembly of a Family of Cerium(III)-Containing Polyoxotungstates Clusters44Assembly of inorganic [Mo 2 S 2 O 2 ] 2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters29Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II138Preparation, structure and characterization of a series of vanadates17Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters22Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures7Does anion-cation organization in Na+-containing X-ray crystal structures relate to solution interactions in inhomogeneous nanoscale environments: Sodium-decavanadate in solid state materials, minerals, and microemulsions31Coding the Assembly of Polyoxotungstates with a Programmable Reaction System9Organic free decavanadate based materials: Inorganic linkers to obtain extended structures11Directed Self‐Assembly, Symmetry Breaking, and Electronic Modulation of Metal Oxide Clusters by Pyramidal Heteroanions11Multicomponent halide templating: The effect of structure-directing agents on the assembly of molecular and extended coordination compounds10Coordination Chemistry in Polyoxometalates and Metal Clusters2Polyoxometalate/metal–organic framework hybrids and their derivatives for hydrogen and oxygen evolution electrocatalysis87Electrochemical, Electrocatalytic, and Magnetic Properties of Vanadium-Containing Polyoxometalates2Non‐Covalent and Covalent Binding of New Mixed‐Valence Cage‐like Polyoxidovanadate Clusters to Lysozyme0Non‐Covalent and Covalent Binding of New Mixed‐Valence Cage‐like Polyoxidovanadate Clusters to Lysozyme20Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters0Tetragonal symmetric-shaped {VIV4O 8 } cubane-encasing vanado-phosphate derivative: prototype liquid-configured device-grade supercapacitor with enhanced performance2

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  1. A novel compound with a 1D network structure constructed by [(VIVO)6(μ4-O)2(μ3-OH)2(μ3-SO3)4]2–/SO32– and 4,4′-bipyridine components: its synthesis, characterization, and magnetic behavior

    Comptes Rendus Chimie · 2005-02-26

    Haralampos N. Miras, Raphael G. Raptis, P. Baran, Nikolia Lalioti, Andrew Harrison, Themistoklis A. Kabanos

    Read original paper ↗ ·

  2. A Novel Series of Vanadium‐Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies.

    ChemInform · 2006-01-19

    Haralampos N. Miras, Raphael G. Raptis, Nikolia Lalioti, Michael P. Sigalas, P. Baran, Themistoklis A. Kabanos

    Read original paper ↗ ·

  3. Polyoxomolybdenum(V/VI)−Sulfite Compounds: Synthesis, Structural, and Physical Studies

    Inorganic Chemistry · 2007-06-26

    Nikolaos I. Kapakoglou, Betzios I. Panagiotis, Spiros E. Kazianis, Constantine E. Kosmidis, Chryssoula Drouza, Manolis J. Manos, Michael P. Sigalas, Anastasios D. Keramidas, Themistoklis A. Kabanos

    Read original paper ↗ ·

  4. New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand

    Inorganic Chemistry · 2007-08-25

    Pei-Xin Li, Hai‐Long Jiang, Mei‐Ling Feng, Jiang‐Gao Mao

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  5. Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−

    Chemical Communications · 2008-01-01

    Haralampos N. Miras, D.J. Stone, Eric J. L. McInnes, Raphael G. Raptis, P. Baran, George I. Chilas, Michael P. Sigalas, Themistoklis A. Kabanos, Leroy Cronin

    Read original paper ↗ ·

  6. Polynuclear Cobalt(II/III) Sulfites: Synthesis, Structure, and Magnetic Properties of the Octanuclear Cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])·10H2O Encapsulating a Lithium Cation

    Inorganic Chemistry · 2008-05-01

    George I. Chilas, Marios Stylianou, Maciej Kubicki, Tiverios Vaimakis, Paul Kögerler, Anastasios D. Keramidas, Themistoklis A. Kabanos

    Read original paper ↗ ·

  7. X-ray characterization of HnacnacR and the first vanadium β-diiminate dimer (R = mesityl)

    Journal of Coordination Chemistry · 2008-07-02

    M.P. Weberski, C.C. McLauchlan

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  8. New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides

    Crystal Growth & Design · 2008-07-18

    Pei-Xin Li, Jiang‐Gao Mao

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  9. Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry

    Chemical Communications · 2009-01-01

    Haralampos N. Miras, Elizabeth F. Wilson, Leroy Cronin

    Read original paper ↗ ·

  10. Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites

    Dalton Transactions · 2009-11-02

    Pei-Xin Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}

    Chemical Communications · 2010-01-01

    Haralampos N. Miras, M.N.C. Ochoa, De‐Liang Long, Leroy Cronin

    Read original paper ↗ ·

  12. Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers

    Dalton Transactions · 2010-01-01

    George I. Chilas, Nikolia Lalioti, Tiverios Vaimakis, Maciej Kubicki, Themistoklis A. Kabanos

    Read original paper ↗ ·

  13. The Highest-Nuclearity Manganese/Oximate Complex: An Unusual MnII/III15 Cluster with an S = 6 Ground State

    Inorganic Chemistry · 2010-04-08

    Dimitris I. Alexandropoulos, Constantina Papatriantafyllopoulou, Guillem Aromı́, Olivier Roubeau, Simon J. Teat, Spyros P. Perlepes, George Christou, Theocharis C. Stamatatos

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  14. Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO 3 2 − : {Mo 12 V 12 Te 3 }, {Mo 12 V 12 Te 2 } and {Mo 17 V 8 Te}

    Chemical Communications · 2011-01-01

    M. Nieves Corella‐Ochoa, Haralampos N. Miras, Alastair Kidd, De‐Liang Long, Leroy Cronin

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  15. Expanding molecular transition metal cubane clusters of the form [M4(μ3-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = VV and WV

    Dalton Transactions · 2011-01-01

    J.S. Maass, Zhichao Chen, Mat­thias Zeller, Rudy Lin Luck

    Read original paper ↗ ·

  16. THE CRYSTAL STRUCTURE OF THE ELUSIVE HUEMULITE

    The Canadian Mineralogist · 2011-06-01

    Fernando Colombo, Ricardo Baggio, Anthony R. Kampf

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  17. Controlling the Self‐Assembly of a Mixed‐Metal Mo/V–Selenite Family of Polyoxometalates

    Chemistry - A European Journal · 2012-09-20

    M. Nieves Corella‐Ochoa, Haralampos N. Miras, De‐Liang Long, Leroy Cronin

    Read original paper ↗ ·

  18. Sulfite Anions as Structure‐Directing Templates for the Engineering of Modular Polyoxometalates

    European Journal of Inorganic Chemistry · 2012-12-04

    Haralampos N. Miras, George I. Chilas, Leroy Cronin, Themistoklis A. Kabanos

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  19. Synthesis and characterizations of the first [V16O39Cl]6− (V16O39) polyanion

    Dalton Transactions · 2013-01-01

    Li‐Na Xiao, Jianing Xu, Jianing Xu, Yang‐Yang Hu, La-Mei Wang, Yan Wang, Hong Yan Ding, Xiao‐Bing Cui, Ji‐Qing Xu, Ji‐Qing Xu

    Read original paper ↗ ·

  20. Two new 3-D boratopolyoxovanadate architectures based on the [V12B16O50(OH)8]12− cluster with different metal linkers

    New Journal of Chemistry · 2013-01-01

    Xing Liu, Jian Zhou, Hong‐Ping Xiao, Chunyang Kong, Hua‐Hong Zou, Qiuling Tang, Jianhui Li

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  21. Assembly of Thiometalate‐Based {Mo 16 } and {Mo 36 } Composite Clusters Combining [Mo 2 O 2 S 2 ] 2+ Cations and Selenite Anions

    Advanced Materials · 2013-08-23

    Hong‐Ying Zang, Jiajia Chen, De‐Liang Long, Leroy Cronin, Haralampos N. Miras

    Read original paper ↗ ·

  22. A series of new 3-D boratopolyoxovanadates containing five types of [KxOy]n building units

    CrystEngComm · 2014-01-01

    Litao An, Jian Zhou, Hong‐Ping Xiao, Xing Liu, Hua‐Hong Zou, Chun‐Yang Pan, Meihua Liu, Jianhui Li

    Read original paper ↗ ·

  23. Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties

    Chemistry - A European Journal · 2014-05-07

    Haralampos N. Miras

    Read original paper ↗ ·

  24. pH-Controlled and Sulfite Anion-Directed Assembly of a Family of Cerium(III)-Containing Polyoxotungstates Clusters

    Inorganic Chemistry · 2014-08-25

    Wei‐Chao Chen, Xinlong Wang, Yanqing Jiao, Peng Huang, En‐Long Zhou, Zhong‐Min Su, Kui‐Zhan Shao

    Read original paper ↗ ·

  25. Assembly of inorganic [Mo 2 S 2 O 2 ] 2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters

    Chemical Science · 2016-01-01

    Hong‐Ying Zang, Jiajia Chen, De‐Liang Long, Leroy Cronin, Haralampos N. Miras

    Read original paper ↗ ·

  26. Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II

    Coordination Chemistry Reviews · 2016-01-29

    Zhujun Liu, Xinlong Wang, Chao Qin, Zhiming Zhang, Yangguang Li, Weilin Chen, Enbo Wang

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  27. Preparation, structure and characterization of a series of vanadates

    CrystEngComm · 2016-11-22

    Hai‐Yang Guo, Tingting Zhang, Po‐Han Lin, Xiao-Zhang Xiao-Zhang, Xiao‐Bing Cui, Qisheng Huo, Ji‐Qing Xu

    Read original paper ↗ ·

  28. Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters

    Advances in inorganic chemistry · 2017-01-01

    Haralampos N. Miras, De‐Liang Long, Leroy Cronin

    Read original paper ↗ ·

  29. Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures

    Dalton Transactions · 2017-01-01

    Ranjay K. Tiwari, Jitendra Kumar, J. N. Behera

    Read original paper ↗ ·

  30. Does anion-cation organization in Na+-containing X-ray crystal structures relate to solution interactions in inhomogeneous nanoscale environments: Sodium-decavanadate in solid state materials, minerals, and microemulsions

    Coordination Chemistry Reviews · 2017-03-24

    Debbie C. Crans, Benjamin Peters, Xiao Wu, C.C. McLauchlan

    Read original paper ↗ ·

  31. Coding the Assembly of Polyoxotungstates with a Programmable Reaction System

    Inorganic Chemistry · 2017-04-17

    Andreu Ruiz de la Oliva, Víctor Sans, Haralampos N. Miras, De‐Liang Long, Leroy Cronin

    Read original paper ↗ ·

  32. Organic free decavanadate based materials: Inorganic linkers to obtain extended structures

    Journal of Molecular Structure · 2017-05-22

    Sridevi Yerra, Samar K. Das

    Read original paper ↗ ·

  33. Directed Self‐Assembly, Symmetry Breaking, and Electronic Modulation of Metal Oxide Clusters by Pyramidal Heteroanions

    Chemistry - A European Journal · 2018-01-10

    Harikleia Sartzi, De‐Liang Long, Stephen A. Sproules, Leroy Cronin, Haralampos N. Miras

    Read original paper ↗ ·

  34. Multicomponent halide templating: The effect of structure-directing agents on the assembly of molecular and extended coordination compounds

    Coordination Chemistry Reviews · 2018-06-07

    Colm Healy, Wolfgang Schmitt

    Read original paper ↗ ·

  35. Coordination Chemistry in Polyoxometalates and Metal Clusters

    Elsevier eBooks · 2020-05-28

    Laia Vilà‐Nadal, Haralampos N. Miras

    Read original paper ↗ ·

  36. Polyoxometalate/metal–organic framework hybrids and their derivatives for hydrogen and oxygen evolution electrocatalysis

    Materials Today Energy · 2020-12-08

    Ziheng Wang, X.-F. Wang, Zhenquan Tan, Xue‐Zhi Song

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  37. Electrochemical, Electrocatalytic, and Magnetic Properties of Vanadium-Containing Polyoxometalates

    Magnetochemistry · 2021-12-03

    Joseph Dika Manga, Anne‐Lucie Teillout, Éric Rivière, Pedro de Oliveira, Israel Martyr Mbomekalle

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  38. Non‐Covalent and Covalent Binding of New Mixed‐Valence Cage‐like Polyoxidovanadate Clusters to Lysozyme

    Angewandte Chemie · 2024-06-06

    Gabriella Tito, Giarita Ferraro, Federico Pisanu, Eugenio Garribba, Antonello Merlino

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  39. Non‐Covalent and Covalent Binding of New Mixed‐Valence Cage‐like Polyoxidovanadate Clusters to Lysozyme

    Angewandte Chemie International Edition · 2024-06-06

    Gabriella Tito, Giarita Ferraro, Federico Pisanu, Eugenio Garribba, Antonello Merlino

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  40. Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters

    Advances in inorganic chemistry · 2025-01-01

    H.N. Miras, D.-L. Long, L. Cronin

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  41. Tetragonal symmetric-shaped {VIV4O 8 } cubane-encasing vanado-phosphate derivative: prototype liquid-configured device-grade supercapacitor with enhanced performance

    Journal of Materials Chemistry A · 2026-01-01

    Shikha Singh, T. Kedara Shivasharma, Subuhan Ahamed, Saurav Ghosh, Kartik Chandra Mondal, Babasaheb Raghunath Sankapal, Abhishek Banerjee

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