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RESEARCH PAPER · Dalton Transactions · 2003

A novel polyoxo(thio)molybdenum( V ) sulfite compound: Synthesis and crystal structure of {[Mo 2 V (μ-S) 2 O 2 ] 6 (μ 3 -SO 3 ) 4 (μ-SO 3 ) 12 } 20− anion

Haralampos N. Miras, J. Derek Woollins, Alexandra M. Z. Slawin, Raphael G. Raptis, P. Baran, Themistoklis A. Kabanos

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A novel polyoxo(thio)molybdenum( V ) sulfite compound: Synthesis and crystal structure of {[Mo 2 V (μ-S) 2 O 2 ] 6 (μ 3 -SO 3 ) 4 (μ-SO 3 ) 12 } 20− anionOriginal19 Macrocyclic and supramolecular coordination chemistry25Synthesis and Characterization of Octa- and Hexanuclear Polyoxomolybdate Wheels: Role of the Inorganic Template and of the Counterion59Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices2174Polynuclear Cobalt(II/III) Sulfites: Synthesis, Structure, and Magnetic Properties of the Octanuclear Cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])·10H2O Encapsulating a Lithium Cation28Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry242Polyoxothiomolybdenum Wheels as Anionic Receptors for Recognition of Sulfate and Sulfonate Anions14Two new cantilever-type polyoxometalates constructed from {Mo 2 O 4 } 2+ fragments and diphosphonates37Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9Solid-state 95Mo NMR of mixed-valence polyoxomolybdates (V, VI) with localized or delocalized d1 electrons8A New Molybdophosphate Constructed From {Mo 2 V O4(H2O)6}2+ and 1-Hydroxyethylidenediphosphonate13Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO 3 2 − : {Mo 12 V 12 Te 3 }, {Mo 12 V 12 Te 2 } and {Mo 17 V 8 Te}44Direct Synthesis and Mass Spectroscopic Observation of the {M40} Polyoxothiometalate Wheel29Sulfite Anions as Structure‐Directing Templates for the Engineering of Modular Polyoxometalates18Assembly of Thiometalate‐Based {Mo 16 } and {Mo 36 } Composite Clusters Combining [Mo 2 O 2 S 2 ] 2+ Cations and Selenite Anions70Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties9Organically templated linear metal sulfites2Four transition-metal-bridging risedronate-based polyoxomolybdates: Syntheses, structures, characterizations and magnetic properties14Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures12Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures7A bimetallic Co 4 Mo 8 cluster built from Mo 8 oxothiomolybdate capped by a Co 4 -thiacalix[4]arene unit: the observation of the Co–Mo synergistic effect for binder-free electrocatalysts46Recent advances in polyoxothiometalate chemistry17Synthesis and structure of {Mo2O2S2} cluster compounds with pyrazole ligands1Frontier advances in polyoxometalates templated by main group VI heteroatoms3

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  1. 19 Macrocyclic and supramolecular coordination chemistry

    Annual Reports Section A (Inorganic Chemistry) · 2004-01-01

    Leroy Cronin

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  2. Synthesis and Characterization of Octa- and Hexanuclear Polyoxomolybdate Wheels: Role of the Inorganic Template and of the Counterion

    Inorganic Chemistry · 2006-06-23

    Anne Dolbecq, Laurent Lisnard, Pierre Mialane, Jérôme Marrot, Marc Bénard, Marie‐Madeleine Rohmer, F. Sécheresse

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  3. Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices

    Chemical Society Reviews · 2006-10-30

    De‐Liang Long, Eric M. Burkholder, Leroy Cronin

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  4. Polynuclear Cobalt(II/III) Sulfites: Synthesis, Structure, and Magnetic Properties of the Octanuclear Cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])·10H2O Encapsulating a Lithium Cation

    Inorganic Chemistry · 2008-05-01

    George I. Chilas, Marios Stylianou, Maciej Kubicki, Tiverios Vaimakis, Paul Kögerler, Anastasios D. Keramidas, Themistoklis A. Kabanos

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  5. Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry

    Chemical Communications · 2009-01-01

    Haralampos N. Miras, Elizabeth F. Wilson, Leroy Cronin

    Read original paper ↗ ·

  6. Polyoxothiomolybdenum Wheels as Anionic Receptors for Recognition of Sulfate and Sulfonate Anions

    European Journal of Inorganic Chemistry · 2009-09-16

    Jean‐François Lemonnier, Sébastien Floquet, Jérôme Marrot, Emmanuel Cadot

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  7. Two new cantilever-type polyoxometalates constructed from {Mo 2 O 4 } 2+ fragments and diphosphonates

    Dalton Transactions · 2009-11-23

    Huaqiao Tan, Weilin Chen, Ding Liu, Yangguang Li, Enbo Wang

    Read original paper ↗ ·

  8. Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers

    Dalton Transactions · 2010-01-01

    George I. Chilas, Nikolia Lalioti, Tiverios Vaimakis, Maciej Kubicki, Themistoklis A. Kabanos

    Read original paper ↗ ·

  9. Solid-state 95Mo NMR of mixed-valence polyoxomolybdates (V, VI) with localized or delocalized d1 electrons

    Chemical Physics Letters · 2010-01-26

    Takahiro Iijima, Toshihiro Yamase, Masataka Tansho, Tadashi Shimizu, Katsuyuki Nishimura

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  10. A New Molybdophosphate Constructed From {Mo 2 V O4(H2O)6}2+ and 1-Hydroxyethylidenediphosphonate

    Journal of Cluster Science · 2010-04-28

    Huaqiao Tan, Weilin Chen, Ding Liu, Enbo Wang

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  11. Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO 3 2 − : {Mo 12 V 12 Te 3 }, {Mo 12 V 12 Te 2 } and {Mo 17 V 8 Te}

    Chemical Communications · 2011-01-01

    M. Nieves Corella‐Ochoa, Haralampos N. Miras, Alastair Kidd, De‐Liang Long, Leroy Cronin

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  12. Direct Synthesis and Mass Spectroscopic Observation of the {M40} Polyoxothiometalate Wheel

    European Journal of Inorganic Chemistry · 2011-10-18

    Haralampos N. Miras, Hong‐Ying Zang, De‐Liang Long, Leroy Cronin

    Read original paper ↗ ·

  13. Sulfite Anions as Structure‐Directing Templates for the Engineering of Modular Polyoxometalates

    European Journal of Inorganic Chemistry · 2012-12-04

    Haralampos N. Miras, George I. Chilas, Leroy Cronin, Themistoklis A. Kabanos

    Read original paper ↗ ·

  14. Assembly of Thiometalate‐Based {Mo 16 } and {Mo 36 } Composite Clusters Combining [Mo 2 O 2 S 2 ] 2+ Cations and Selenite Anions

    Advanced Materials · 2013-08-23

    Hong‐Ying Zang, Jiajia Chen, De‐Liang Long, Leroy Cronin, Haralampos N. Miras

    Read original paper ↗ ·

  15. Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties

    Chemistry - A European Journal · 2014-05-07

    Haralampos N. Miras

    Read original paper ↗ ·

  16. Organically templated linear metal sulfites

    RSC Advances · 2015-01-01

    Ranjay K. Tiwari, Jitendra Kumar, J. N. Behera

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  17. Four transition-metal-bridging risedronate-based polyoxomolybdates: Syntheses, structures, characterizations and magnetic properties

    Synthetic Metals · 2016-12-01

    Xiaopeng Sun, Ran Ban, Pengtao Ma, Jia‐Wei Wang, Jia‐Wei Wang, Dongdi Zhang, Jingyang Niu, Jingping Wang, Jingping Wang

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  18. Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures

    Dalton Transactions · 2017-01-01

    Ranjay K. Tiwari, J. N. Behera

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  19. Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures

    Dalton Transactions · 2017-01-01

    Ranjay K. Tiwari, Jitendra Kumar, J. N. Behera

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  20. A bimetallic Co 4 Mo 8 cluster built from Mo 8 oxothiomolybdate capped by a Co 4 -thiacalix[4]arene unit: the observation of the Co–Mo synergistic effect for binder-free electrocatalysts

    Journal of Materials Chemistry A · 2019-01-01

    Min Zhang, Mengwei Chen, Yanfeng Bi, Liangliang Huang, Kun Zhou, Zhiping Zheng

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  21. Recent advances in polyoxothiometalate chemistry

    Journal of Coordination Chemistry · 2022-06-14

    Alexander Elliott, Haralampos N. Miras

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  22. Synthesis and structure of {Mo2O2S2} cluster compounds with pyrazole ligands

    Polyhedron · 2025-03-07

    Anna V. Konkova, Darya V. Evtushok, Michael A. Shestopalov, Anton A. Ivanov

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  23. Frontier advances in polyoxometalates templated by main group VI heteroatoms

    Coordination Chemistry Reviews · 2026-03-31

    Zhigang Tang, Jiaxin Li, Dan Wang, Lijuan Chen, Junwei Zhao

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