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RESEARCH PAPER · Inorganic Chemistry · 2021

Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O6

Tao Han, Conggang Li, Wenli Zhao, Yuheng She, Jinmiao Jiao, Fei Liang, Zhanggui Hu, Yicheng Wu

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Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O6OriginalCs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence43Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal15Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence21Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates7Quantitative Studies on Local Structure of Molten Binary Potassium Germanates9Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering17Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency2Synthesis and Properties Study of a Germanate Mid-Infrared Nonlinear Optical Crystal0Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10Reduction of Germanium Oxides–The Mixed-Valence Germanates A2Ge4O7 (A = Na, K)4From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials9From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials50Blue pigment based on Ni-doped Zn2GeO4: Addressing structure and electronic properties by combining experiment and theory5K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window2Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units0Structure-directing synthesis of two germanate cages featuring odd-member ring windows0Stuffed Tridymites A′A″Ga 4 O 8 (A′ = Ba, Sr, Ca; A″ = Pb): Integrating Stereochemically Active Lone Pairs with A-Site Ordering to Design a Polar Structure Featuring Distinctive Ring Topology3Recovery of germanium by chlorinated distillation of high content germanium materials enhanced by ultrasonic external field and arsenic removal3A promising mid-infrared nonlinear optical crystal with well-balanced properties0K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1

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  1. Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence

    Chemistry of Materials · 2022-03-22

    Wenli Zhao, Conggang Li, Tao Han, Jinmiao Jiao, Yuheng She, Dianxing Ju, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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  2. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

    Jinmiao Jiao, Fei Liang, Conggang Li, Tao Han, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  3. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  4. Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal

    Advanced Optical Materials · 2022-09-01

    Wenli Zhao, Jinmiao Jiao, Yuheng She, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  5. Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O3

    Journal of Solid State Chemistry · 2022-10-06

    Lei Huai, Lunan Zhang, Beibei Zhang, Guangan Jia, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang

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  6. Three polar indium phosphites exhibiting diverse structural networks and SHG-activity

    Journal of Solid State Chemistry · 2022-10-10

    Gang-Xiang Liu, Yu-Long Wei, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  7. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  8. LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Yuheng She, Jinmiao Jiao, Zheng Wang, Jing Chai, Song Jie, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  9. Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

    Angewandte Chemie International Edition · 2023-01-05

    Kaichuang Chen, Chensheng Lin, Jindong Chen, Guangsai Yang, Haotian Tian, Min Luo, Tao Yan, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Ning Ye, Guang Peng

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  10. Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

    Angewandte Chemie · 2023-01-05

    Kaichuang Chen, Chensheng Lin, Jindong Chen, Guangsai Yang, Haotian Tian, Min Luo, Tao Yan, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Ning Ye, Guang Peng

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  11. Quantitative Studies on Local Structure of Molten Binary Potassium Germanates

    Inorganic Chemistry · 2023-07-04

    Y. B. Zhao, Jinglin You, Jian Wang, Min Wang, Kai Tang, Liming Lü, Qingli Zhang, Songming Wan, Xiaoye Gong, Guopeng Liu

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  12. Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering

    Inorganic Chemistry · 2023-10-12

    Tinghui Zhang, Jinmiao Jiao, Wenli Zhao, Fulei Wang, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  13. Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency

    Dalton Transactions · 2024-01-01

    Jing Chai, Yuheng She, Jinmiao Jiao, Lili Li, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  14. Synthesis and Properties Study of a Germanate Mid-Infrared Nonlinear Optical Crystal

    Material Sciences · 2024-01-01

    海彦 师

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  15. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  16. Reduction of Germanium Oxides–The Mixed-Valence Germanates A2Ge4O7 (A = Na, K)

    Inorganic Chemistry · 2024-03-07

    Thanh Chau, Stefan S. Rudel, Hannah Illner, Kristian Witthaut, Lkhamsuren Bayarjargal, Björn Winkler, Wolfgang Schnick

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  17. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  18. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  19. Blue pigment based on Ni-doped Zn2GeO4: Addressing structure and electronic properties by combining experiment and theory

    Ceramics International · 2024-06-02

    Katiana Lima Patrocinio, Gleison Neres Marques, Amanda Fernandes Gouveia, Lara Kelly Ribeiro, Nayara A. Pinheiro, Maria Inês Basso Bernardi, Lucia Helena Mascaro, Juán Andrés, E. Longo, Marcelo Assis

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  20. K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window

    Inorganic Chemistry · 2024-09-30

    Yujun Wang, Jing Chai, Jinmiao Jiao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  21. Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units

    SSRN Electronic Journal · 2025-01-01

    Baozhu Zhu, Lei Geng, You‐Zhao Lan, Shihua Ma, Chang‐Yu Meng, Qi Wu

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  22. Structure-directing synthesis of two germanate cages featuring odd-member ring windows

    Dalton Transactions · 2025-01-01

    Hao Li, Yanan Xu, Shiyue Zhang, Pengliang Gu, Qing Hu, Yu Zhang, Wenkai Wang, Zhan Shi, Xinyi Fu, Hong‐Bin Du

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  23. Stuffed Tridymites A′A″Ga 4 O 8 (A′ = Ba, Sr, Ca; A″ = Pb): Integrating Stereochemically Active Lone Pairs with A-Site Ordering to Design a Polar Structure Featuring Distinctive Ring Topology

    Chemistry of Materials · 2025-01-31

    Liyang Zhang, Zien Cheng, Guangxiang Lu, Ying Wang, Alicia Maria Manjón-Sanz, Rihong Cong, Tao Yang, Pengfei Jiang

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  24. Recovery of germanium by chlorinated distillation of high content germanium materials enhanced by ultrasonic external field and arsenic removal

    Chemical Engineering and Processing - Process Intensification · 2025-07-25

    Mingyuan Rao, Qi Zhang, Hongying Xia, Yingjie Xu, Linqing Dai, Libo Zhang

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  25. A promising mid-infrared nonlinear optical crystal with well-balanced properties

    Inorganic Chemistry Frontiers · 2026-01-01

    Yujun Wang, Yuning Qi, Yongkuan Xu, Ning Ye, Zhanggui Hu, Conggang Li

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  26. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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