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RESEARCH PAPER · Inorganic Chemistry · 2016

Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

Hongil Jo, Kang Min Ok

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Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the CentricityOriginalSb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures9ChemInform Abstract: Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity.0Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8Na2Mg1−xZnxSiO4 (0 ≤ x ≤ 1): Noncentrosymmetric Sodium Metal Silicate Solid Solutions with Ultraviolet Nonlinear Optical Properties71Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design51Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates10Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]8NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy3Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material27Novel structural transformation in K3ReP2S8 thiophosphates originating from the rare-earth (Re) cation sizes induced local coordination asymmetry25LiKCuP2O7: Cation substitution application with mixed-alkaline copper-containing pyrophosphate and magnetic properties2{[In2S7]8–}∞ Chain and Isolated HgS4 Planar Unit Constructed One-Dimensional Pentanary Sulfide K2Ba7HgIn4S16 Exhibiting Nonlinear-Optical Activity10Mixed-valence compounds based on heterometallic-oxo-clusters containing Sb( iii , v ): crystal structures and proton conduction1Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence18[Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption5Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals1The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals0

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  1. Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures

    Dalton Transactions · 2016-01-01

    Lei Geng, Qiang Li, Hong‐Yan Lu, Kai Dai, P. Shiv Halasyamani

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  2. ChemInform Abstract: Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity.

    ChemInform · 2016-08-01

    Hongil Jo, Kang Min Ok

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  3. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie International Edition · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  4. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  5. LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures

    Inorganic Chemistry · 2016-09-30

    Dong Yan, Fei‐Fei Mao, Jiang‐Gao Mao

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  6. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  7. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

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  8. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  9. Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions

    Journal of Solid State Chemistry · 2017-05-04

    Hoyong Jung, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  10. Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups

    Journal of Materials Science · 2017-11-13

    Zhaohui Chen, Zhizhong Zhang, Ronglan Wu, Xiaoyu Dong, Yunjing Shi, Qun Jing

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  11. Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties

    Dalton Transactions · 2018-01-01

    Fangfang He, Lei Wang, Cuifang Hu, Jing Wen Zhou, Qian Li, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  12. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

    Inorganic Chemistry · 2018-03-07

    Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  13. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

    Fangfang He, Qian Wang, Cuifang Hu, Wen Jun He, Xueying Luo, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  14. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

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  15. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

    Inorganic Chemistry · 2019-01-16

    Eun Jeong Cho, Seung‐Jin Oh, Hongil Jo, Junsu Lee, Tae‐Soo You, Kang Min Ok

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  16. Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)

    Science China Materials · 2019-03-22

    Zhiqing Xie, Ying Wang, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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  17. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses

    Chemistry of Materials · 2019-03-29

    Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan

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  18. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O

    Crystal Growth & Design · 2019-04-03

    Yutong Shi, Min Luo, Chensheng Lin, Guang Peng, Ning Ye

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  19. Na2Mg1−xZnxSiO4 (0 ≤ x ≤ 1): Noncentrosymmetric Sodium Metal Silicate Solid Solutions with Ultraviolet Nonlinear Optical Properties

    Bulletin of the Korean Chemical Society · 2019-12-15

    Hyeshin Lee, Kang Min Ok

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  20. Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design

    Dalton Transactions · 2020-01-01

    Fangfang He, Yuwei Ge, Xiaoyu Zhao, Jing He, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  21. Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates

    Inorganic Chemistry · 2020-04-03

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  22. Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship

    European Journal of Inorganic Chemistry · 2020-12-22

    Hongil Jo, Xinglong Chen, Hee‐Seung Lee, Kang Min Ok

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  23. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

    Chemistry - A European Journal · 2020-12-23

    Qi Wei, Chao He, Kui Wang, Xiao‐Fang Duan, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  24. Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]

    Inorganic Chemistry Frontiers · 2021-01-01

    HeeJung Choi, Kang Min Ok

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  25. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

    Journal of Alloys and Compounds · 2021-11-24

    Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  26. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

    Dalton Transactions · 2021-12-13

    Maierhaba Abudoureheman, Juanjuan Zheng, Peng Wang, Bo Wei, Zhiyong Guo, Zhaohui Chen, Yanna Chen

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  27. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

    Inorganic Chemistry · 2021-12-15

    Mei Yang, Zhi‐Hui Shi, Wen‐Dong Yao, Sheng‐Ping Guo

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  28. ( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Jihyeon Moon, Kang Min Ok

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  29. Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material

    Inorganic Chemistry · 2022-09-06

    Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  30. Novel structural transformation in K3ReP2S8 thiophosphates originating from the rare-earth (Re) cation sizes induced local coordination asymmetry

    Materials Today Physics · 2022-10-17

    Xiaodong Tian, Yan Xiao, Bohai Zhang, D. Yang, Kui Wu

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  31. LiKCuP2O7: Cation substitution application with mixed-alkaline copper-containing pyrophosphate and magnetic properties

    Inorganica Chimica Acta · 2022-12-05

    Juanjuan Zheng, Maierhaba Abudoureheman, Peng Wang, Alimujiang Yalikun, Bo Wei, Zhaohui Chen, Lin Ning Sun, Jun Zhang

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  32. {[In2S7]8–}∞ Chain and Isolated HgS4 Planar Unit Constructed One-Dimensional Pentanary Sulfide K2Ba7HgIn4S16 Exhibiting Nonlinear-Optical Activity

    Inorganic Chemistry · 2023-05-01

    Xiao Fen Huang, Yexin Chen, Yuan Xue, Ying-Chi Wang, Qing-Hua Ren, Wenlong Liu, Jiajing Wu, Sheng‐Ping Guo

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  33. Mixed-valence compounds based on heterometallic-oxo-clusters containing Sb( iii , v ): crystal structures and proton conduction

    Dalton Transactions · 2023-12-07

    Wei‐Yang Wen, Wen Ma, Bing Hu, Hui‐Ping Xiao, Tianyu Pan, Jia-Ting Liu, Hao-Wei Lin, Xin‐Xiong Li, Xiao‐Ying Huang

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  34. Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence

    Inorganic Chemistry · 2024-01-24

    Yang Lan, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  35. [Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

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  36. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

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  37. The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2026-09-10

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  38. The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals

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