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RESEARCH PAPER · Inorganic Chemistry · 2021

Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence

Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced BirefringenceOriginalSn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate212Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate22Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates22Ba 2 Bi 2 [Zn(PO 4 ) 4 ]: ionic-isolation-activated first barium bismuth zincophosphate with unprecedented ∞ [Zn(PO 4 ) 4 ] 10− chains and balanced overall performance4K6Bi13(PO4)15, K5Bi(P2O7)2, A5Bi5(PO4)4(P2O7)2 (A=K, Rb): New bismuth phosphates with different condensed phosphate groups8NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates46RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks11Synthesis, crystal structures and luminescent properties of three layered zinc complexes: Zn(1,10-phen) I2 (m = 1, 2) and Zn2(1,10-phen)2C2O4Br2 (phen = phenanthroline)4Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance26Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture1Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30(NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal9A survey of stereoactive oxysalts for linear and nonlinear optical applications40Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials11Novel antimony phosphates with enlarged birefringence induced by lone pair cations4RbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence11Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence18HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound6Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability4Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8The different response in band structures and optical properties induced by spin-orbit coupling in Ba3X2(PO4)4 (X = Sb and Bi): A first-principles investigation0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie International Edition · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  2. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates

    Inorganic Chemistry · 2021-09-27

    Mengya Ji, Chun‐Li Hu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  4. Ba 2 Bi 2 [Zn(PO 4 ) 4 ]: ionic-isolation-activated first barium bismuth zincophosphate with unprecedented ∞ [Zn(PO 4 ) 4 ] 10− chains and balanced overall performance

    Inorganic Chemistry Frontiers · 2021-11-23

    Yuxin Li, Meihong Duan, Peixin Ma, Xu-Kui Yang, Wenhua Ma, Baichuan Wang, Zhi Gang Fang

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  5. K6Bi13(PO4)15, K5Bi(P2O7)2, A5Bi5(PO4)4(P2O7)2 (A=K, Rb): New bismuth phosphates with different condensed phosphate groups

    Journal of Alloys and Compounds · 2021-12-01

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  6. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

    Crystal Growth & Design · 2021-12-09

    Kui Wang, Xiao-Fei Li, Chao He, Jinhua Li, Xing‐Tao An, Li Wei, Qi Wei, Guo‐Ming Wang

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  7. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

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  8. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

    Journal of Materials Chemistry C · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  9. Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates

    Chemistry of Materials · 2022-04-29

    Chenhui Hu, Xintong Cai, Mengfan Wu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  10. RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks

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    Yu-Long Wei, Gang-Xiang Liu, Da-Li Chen, Wen‐Dong Yao, Xin Lian, Wenlong Liu, Ru‐Ling Tang

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  11. Synthesis, crystal structures and luminescent properties of three layered zinc complexes: Zn(1,10-phen) I2 (m = 1, 2) and Zn2(1,10-phen)2C2O4Br2 (phen = phenanthroline)

    Journal of Molecular Structure · 2022-06-09

    Yingling Zhong, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  12. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

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  13. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  14. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  15. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  16. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

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  17. Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance

    Advanced Optical Materials · 2023-01-17

    Die Zhang, Qiang Wang, Han Luo, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  18. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

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    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  19. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

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  20. Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture

    Chemistry - A European Journal · 2023-04-10

    Hongyu Huang, Na Li, Ruixin Zhang, Xinmei Wang, Xianmeng He, Lei Wu, Lili Liu, Qun Jing, Zhaohui Chen

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  21. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

    Inorganic Chemistry · 2023-04-21

    Xiao-Fei Li, Kui Wang, Chao He, Jinhua Li, Xing‐Tao An, Jie Pan, Qi Wei, Guo‐Ming Wang, Guo‐Yu Yang

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  22. (NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal

    Journal of Solid State Chemistry · 2023-06-22

    Yueling Sun, Gang-Xiang Liu, Yi‐Lei Lv, Liang Ma, Wen‐Dong Yao, Ru‐Ling Tang

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  23. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

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  24. Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials

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  25. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

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  26. RbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence

    Journal of Materials Chemistry C · 2024-01-01

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  27. Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence

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  28. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

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  29. The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound

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    Xudong Leng, Mei Hu, Qun Jing, Haiming Duan, Henglei Chen, Zhaohui Chen

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  30. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

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  31. Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability

    Inorganic Chemistry · 2024-09-25

    Zhi Gang Fang, Chao-Qian Li, Bing‐Ping Yang, Meihong Duan

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  32. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

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  33. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

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  34. The different response in band structures and optical properties induced by spin-orbit coupling in Ba3X2(PO4)4 (X = Sb and Bi): A first-principles investigation

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  35. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

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  36. Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition

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  37. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

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