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RESEARCH PAPER · Chemistry of Materials · 2020

Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates

Geonju Park, Hye Ryung Byun, Joon Ik Jang, Kang Min Ok

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Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal IodatesOriginalBi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response63Novel enantiomorphic Pb-coordination polymers dictated by the corresponding chiral ligands, [Pb(( R , R )- TBA )(H 2 O)]·1.7H 2 O and [Pb(( S , S )- TBA )(H 2 O)]·1.7H 2 O [ TBA = 1,3,5-triazin-2(1 H )-one-4,6-bis(alanyl)]20NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units16Novel noncentrosymmetric polar coordination compounds derived from chiral histidine ligands36Third Harmonic Upconversion and Self-Trapped Excitonic Emission in 1D Pyridinium Lead Iodide29A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]4Distinct nonlinear optical responses in three pairs of 2D homochiral Ag( i ) enantiomers modulated by dicarboxylic acid ligands25Homovalent Cation Substitutions Leading to New Lithium-Containing La3cusis7 Family Members Having Chiral, Uniaxial Structures and Exhibiting Second- and Third-Harmonic Generation7Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)5Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response35NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses12Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response4Recent advances in F-containing iodate nonlinear optical materials6Two temperature-induced 1D Cu II chain enantiomeric pairs showing different magnetic properties and nonlinear optical responses14Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals1Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation30A review on the advancements in the characterization of the high-pressure properties of iodates441D Diisopropylammonium Lead Iodide Perovskite Shows Exceptional Optical Stability and Third‐Order Nonlinearity16Anion Tuned Structural Modulation and Nonlinear Optical Effects of Metal‐Ion Directed 310‐Helix Networks1Broadband Tunability of Third Harmonic Upconversion in Pyridinium Lead Halides4From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses4Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties7Two chiral lanthanide Pr III and Ho III complexes: NIR luminescence and nonlinear optical properties14Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses6Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60Impact of nuclear number on SHG and THG performances: a comparative study of chiral mono- and dinuclear Tb III complexes with identical organic ligands22D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses5Multifunctional chiral dinuclear DyIII enantiomeric pairs: showing single-molecule magnet behaviors with very strong third-harmonic generation responses5Two Chiral EuIII Enantiomeric Pairs with Significantly Enhanced Photophysical and Third-Harmonic Generation Performances through the Coordination Roles of Enantiopure Bi- and Tridentate N-Donors8Dopant‐Engineered Enhancement of Third‐Harmonic Generation in 2D Hybrid Perovskites0Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites0Tuning linear and nonlinear optical performances of two eight- and nine-coordinated chiral SmIII enantiomeric pairs by enantiopure N-donor ligands1Chiral dinuclear EuIII enantiomeric pairs: simultaneously showing photoluminescences, circularly polarized luminescences, second- and third-harmonic generations with enhanced performances0

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  1. Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2020-07-01

    Jee Yoon Chung, Hongil Jo, Seongbeom Yeon, Hye Ryung Byun, Tae‐Soo You, Joon Ik Jang, Kang Min Ok

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  2. Novel enantiomorphic Pb-coordination polymers dictated by the corresponding chiral ligands, [Pb(( R , R )- TBA )(H 2 O)]·1.7H 2 O and [Pb(( S , S )- TBA )(H 2 O)]·1.7H 2 O [ TBA = 1,3,5-triazin-2(1 H )-one-4,6-bis(alanyl)]

    Materials Chemistry Frontiers · 2020-10-09

    Yunseung Kuk, Kang Min Ok

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  3. NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units

    Dalton Transactions · 2021-01-01

    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  4. Novel noncentrosymmetric polar coordination compounds derived from chiral histidine ligands

    Inorganic Chemistry Frontiers · 2021-01-01

    Wooyoung Seo, Kang Min Ok

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  5. Third Harmonic Upconversion and Self-Trapped Excitonic Emission in 1D Pyridinium Lead Iodide

    The Journal of Physical Chemistry C · 2021-10-11

    Shabnum Maqbool, Tariq Sheikh, Ziyad Thekkayil, Swati Deswal, Ramamoorthy Boomishankar, Angshuman Nag, Pankaj K. Mandal

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  6. A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]

    CrystEngComm · 2021-11-11

    Dandan Wang, Xiaoqing Jiang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  7. Distinct nonlinear optical responses in three pairs of 2D homochiral Ag( i ) enantiomers modulated by dicarboxylic acid ligands

    Inorganic Chemistry Frontiers · 2021-11-24

    Congli Gao, Jianya Zhou, Minghui Cui, Di‐Ming Chen, Liming Zhou, Fengcai Li, Xi-Li Li

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  8. Homovalent Cation Substitutions Leading to New Lithium-Containing La3cusis7 Family Members Having Chiral, Uniaxial Structures and Exhibiting Second- and Third-Harmonic Generation

    SSRN Electronic Journal · 2022-01-01

    Andrew J. Craig, Jeong Bin Cho, Seung Han Shin, Seung Heon Ha, Stanislav S. Stoyko, Joon Ik Jang, Jennifer A. Aitken

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  9. Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)

    Solid State Sciences · 2022-01-01

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  10. Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures

    Chemistry - A European Journal · 2022-01-27

    Yunseung Kuk, Joonhyuk Kee, Kang Min Ok

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  11. Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response

    Inorganic Chemistry · 2022-06-03

    Xi-Li Li, Ailing Wang, Minghui Cui, Congli Gao, Xiaojing Yu, Bing Su, Liming Zhou, Cai‐Ming Liu, Hong‐Ping Xiao, Yi‐Quan Zhang

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  12. NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps

    Inorganic Chemistry · 2022-07-21

    Jianlong Huang, Fengjiao Guo, Zhiyong Guo, Jianbang Chen, Bin Dai, Feng Yu

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  13. A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Congli Gao, Zhiqiang Zhang, Bing Su, Xi-Li Li

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  14. Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response

    Journal of Materials Chemistry C · 2023-01-01

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  15. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  16. Two temperature-induced 1D Cu II chain enantiomeric pairs showing different magnetic properties and nonlinear optical responses

    Dalton Transactions · 2023-01-01

    Xi-Li Li, Yanan Li, Ailing Wang, Congli Gao, Minghui Cui, Cai‐Ming Liu, Liming Zhou

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  17. Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals

    Crystal Growth & Design · 2023-02-13

    Jingcheng Feng, Lei Bai, Guochun Zhang

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  18. Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation

    Inorganic Chemistry · 2023-02-27

    Xi-Li Li, Ailing Wang, Yanan Li, Congli Gao, Minghui Cui, Hong‐Ping Xiao, Liming Zhou

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  19. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

    Akun Liang, Robin Turnbull, Daniel Errandonea

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  20. 1D Diisopropylammonium Lead Iodide Perovskite Shows Exceptional Optical Stability and Third‐Order Nonlinearity

    Advanced Optical Materials · 2023-05-01

    Shabnum Maqbool, Ziyad Thekkayil, Pankaj K. Mandal

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  21. Anion Tuned Structural Modulation and Nonlinear Optical Effects of Metal‐Ion Directed 310‐Helix Networks

    Chemistry - A European Journal · 2023-10-22

    Souvik Roy, Aman Chaturvedi, Sanjit Dey, DRGKoppalu R. Puneeth Kumar, Saikat Pahan, Souvik Panda Mahapatra, Pankaj K. Mandal, Hosahudya N. Gopi

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  22. Broadband Tunability of Third Harmonic Upconversion in Pyridinium Lead Halides

    ACS Photonics · 2023-12-15

    Ziyad Thekkayil, Shabnum Maqbool, Riteeka Tanwar, Pankaj K. Mandal

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  23. From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates

    Inorganic Chemistry · 2024-01-01

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  24. Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses

    New Journal of Chemistry · 2024-01-01

    Taoyu Wang, Yanhong Peng, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  25. Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties

    CrystEngComm · 2024-01-01

    Jinliang Zhang, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  26. Two chiral lanthanide Pr III and Ho III complexes: NIR luminescence and nonlinear optical properties

    CrystEngComm · 2024-01-01

    Yanhong Peng, Taoyu Wang, Congli Gao, Fengcai Li, Xi-Li Li

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  27. Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)6

    Crystallography Reports · 2024-08-01

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  28. Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses

    Journal of Molecular Structure · 2024-09-14

    Xiaodi Du, Chunyang Li, Chunyang Li, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  29. Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

    Кристаллография · 2024-09-25

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  30. Impact of nuclear number on SHG and THG performances: a comparative study of chiral mono- and dinuclear Tb III complexes with identical organic ligands

    CrystEngComm · 2025-01-01

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  31. 2D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses

    Inorganic Chemistry · 2025-01-10

    Congli Gao, Xiaoyu Cai, Jinying Huang, Qianrong Li, Huajie Kong, Jimei Yao, Yang Wang, Xi-Li Li

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  32. Multifunctional chiral dinuclear DyIII enantiomeric pairs: showing single-molecule magnet behaviors with very strong third-harmonic generation responses

    Journal of Molecular Structure · 2025-04-19

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  33. Two Chiral EuIII Enantiomeric Pairs with Significantly Enhanced Photophysical and Third-Harmonic Generation Performances through the Coordination Roles of Enantiopure Bi- and Tridentate N-Donors

    Inorganic Chemistry · 2025-06-03

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  34. Dopant‐Engineered Enhancement of Third‐Harmonic Generation in 2D Hybrid Perovskites

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  35. Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites

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  36. Tuning linear and nonlinear optical performances of two eight- and nine-coordinated chiral SmIII enantiomeric pairs by enantiopure N-donor ligands

    Journal of Molecular Structure · 2026-05-19

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  37. Chiral dinuclear EuIII enantiomeric pairs: simultaneously showing photoluminescences, circularly polarized luminescences, second- and third-harmonic generations with enhanced performances

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