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RESEARCH PAPER · Inorganic Chemistry · 2013

SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures

Yucheng Hao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic ArchitecturesOriginalChemInform Abstract: SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three‐Dimensional and Layered Anionic Architectures.0KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Synthesis and Characterization of the New Strontium Borogermanate Sr3–x/2B2–xGe4+xO14 (x = 0.32)16Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra11Na2RE2TeO4(BO3)2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates51Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups25Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)14Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions26Synthesis and structural characterization of Ca12Ge17B8O583Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates23LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15Synthesis and structural characterization of BaSr2Ge3O94Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet50Synthesis and crystal structure of the rare earth borogermanate EuGeBO 55Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures36Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions19Synthesis and Study of the First Zeolitic Uranium Borate22Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+6NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters2Mg3Pt(BO3)2O2: The first platinum borate from the flux technique13Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses16Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions13Borates: A Rich Source for Optical Materials1089M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate3Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 54Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units38Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O82A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions5Order-disorder transition and thermal behavior of paracelsian-type MGa2Ge2O8 (M = Sr, Ba) compounds1Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution21Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution6Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate0K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1

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  1. ChemInform Abstract: SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three‐Dimensional and Layered Anionic Architectures.

    ChemInform · 2014-01-23

    Yucheng Hao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  2. KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

    Inorganic Chemistry · 2014-03-25

    Chao Zhang Huang, Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  3. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

    CrystEngComm · 2014-06-12

    Yucheng Hao, Xiang Xu, Fang Kong, Jun‐Ling Song, Jiang‐Gao Mao

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  4. Synthesis and Characterization of the New Strontium Borogermanate Sr3–x/2B2–xGe4+xO14 (x = 0.32)

    Inorganic Chemistry · 2014-08-27

    Benedikt Petermüller, Lucas L. Petschnig, Klaus Wurst, Günter Heymann, Hubert Huppertz

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  5. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  6. Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra

    RSC Advances · 2015-01-01

    Ming Wen, Zhipeng Lian, Hongping Wu, Xin Su, Qingfeng Yan, Juanjuan Lu, Zhihua Yang, Shilie Pan

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  7. Na2RE2TeO4(BO3)2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates

    Inorganic Chemistry · 2015-02-18

    Jiang-He Feng, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  8. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  9. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

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  10. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  11. A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups

    CrystEngComm · 2016-01-01

    Dong Yan, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  12. Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2016-02-29

    Zhengyang Zhou, Xiang Xu, Rao Fei, Jiang‐Gao Mao, Junliang Sun

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  13. Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions

    Inorganic Chemistry · 2016-06-06

    Hui Yang, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  14. Synthesis and structural characterization of Ca12Ge17B8O58

    Zeitschrift für Naturforschung B · 2016-08-12

    Sebastian Bräuchle, Klaus Wurst, Hubert Huppertz

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  15. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

    Journal of Alloys and Compounds · 2016-08-20

    Maierhaba Abudoureheman, Shujuan Han, Xiaoyu Dong, Bing‐Hua Lei, Ying Wang, Zhihua Yang, Xifa Long, Shilie Pan

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  16. Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates

    Crystal Growth & Design · 2016-09-08

    Yucheng Hao, Vladislav V. Klepov, Gabriel L. Murphy, Giuseppe Modolo, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Brendan J. Kennedy, Shuao Wang, Evgeny V. Alekseev

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  17. LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures

    Inorganic Chemistry · 2016-09-30

    Dong Yan, Fei‐Fei Mao, Jiang‐Gao Mao

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  18. Synthesis and structural characterization of BaSr2Ge3O9

    Zeitschrift für Naturforschung B · 2016-10-14

    Sebastian Bräuchle, Clivia Hejny, Hubert Huppertz

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  19. Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet

    Inorganic Chemistry · 2017-01-11

    Chao Wu, Longhua Li, Jun‐Ling Song, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  20. Synthesis and crystal structure of the rare earth borogermanate EuGeBO 5

    Zeitschrift für Naturforschung B · 2017-01-20

    Yang Chi, Yan Zhuang, Sheng‐Ping Guo

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  21. Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures

    Inorganic Chemistry · 2017-07-18

    Yucheng Hao, Gabriel L. Murphy, Dirk Bosbach, Giuseppe Modolo, Thomas E. Albrecht‐Schmitt, Evgeny V. Alekseev

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  22. Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

    Inorganic Chemistry · 2017-10-18

    Sujuan Yu, Xiang-Yu Gu, Tingting Deng, Jianhao Huang, Jian‐Wen Cheng, Guo‐Yu Yang

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  23. Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions

    Crystal Growth & Design · 2017-10-20

    Yucheng Hao, Philip Kegler, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  24. Synthesis and Study of the First Zeolitic Uranium Borate

    Crystal Growth & Design · 2017-11-28

    Yucheng Hao, Vladislav V. Klepov, Philip Kegler, Giuseppe Modolo, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  25. Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations

    Inorganic Chemistry Frontiers · 2018-01-01

    Yanna Chen, Min Zhang, Cong Hu, Zhihua Yang, Shilie Pan

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  26. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

    Inorganic Chemistry Frontiers · 2019-01-01

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Yan Chen, Jiang‐Gao Mao

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  27. Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+

    RSC Advances · 2019-01-01

    Pan Liang

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  28. NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

    Inorganic Chemistry · 2019-03-04

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu, Shilie Pan

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  29. Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters

    ChemistrySelect · 2019-04-02

    Hui Yang, Chun‐Li Hu, Bei Lv, Ru‐Ling Tang, Cuixia Xu

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  30. Mg3Pt(BO3)2O2: The first platinum borate from the flux technique

    Journal of Solid State Chemistry · 2019-11-01

    Yucheng Hao, Linbo He, Guangjie Ge, Quan-Zheng Zhang, Ningjing Luo, Shuping Huang, Haijian Li, Evgeny V. Alekseev

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  31. Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

    Dalton Transactions · 2019-12-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  32. Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses

    CrystEngComm · 2020-01-01

    Yucheng Hao, Yang Pan, Yuan Hua Lin, Linbo He, Guangjie Ge, Yu Ruan, Haida Zhou, Yang Xue, Kisan Koirala

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  33. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

    Dalton Transactions · 2020-01-01

    Jun Sun, Miriding Mutailipu, Shichao Cheng, Zhihua Yang, Shilie Pan

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  34. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  35. Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions

    European Journal of Inorganic Chemistry · 2020-01-22

    Yucheng Hao, Philip Kegler, Thomas E. Albrecht‐Schmitt, Shuao Wang, Qiang Dong, Evgeny V. Alekseev

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  36. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  37. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

    European Journal of Inorganic Chemistry · 2021-02-13

    Qiqi Zhang, Fangfang Zhang, Fuming Li, Shujuan Han, Zhihua Yang, Shilie Pan

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  38. Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate

    Inorganics · 2021-04-06

    Kristen A. Pace, Vladislav V. Klepov, Mark D. Smith, Travis Williams, Gregory W. Morrison, Jochen A. Lauterbach, Scott T. Misture, Hans‐Conrad zur Loye

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  39. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  40. Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 5

    Dalton Transactions · 2022-01-01

    Yucheng Hao, Gabriel L. Murphy, Philip Kegler, Yan Li, Piotr M. Kowalski, Simon Blouin, Yang Zhang, Shuao Wang, Lars Robben, Thorsten M. Gesing, Evgeny V. Alekseev

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  41. Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units

    Chemistry of Materials · 2022-07-26

    Congcong Jin, Fuming Li, Xingqi Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  42. Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O8

    Journal of Alloys and Compounds · 2022-12-28

    Liudmila A. Gorelova, Saiana Khandarkhaeva, Valentina A. Yukhno, Maria Georgievna Krzhizhanovskaya, Олег Сергеевич Верещагин, Leonid Dubrovinsky

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  43. A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures

    CrystEngComm · 2023-01-01

    Yucheng Hao, Yang Zhang, Yuying Zhang, Zixiang Fu, Chunyang Heng, Junjie Li, Jiatian You, Kunhong Hu, Yuan Hua Lin, Haijian Li

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  44. Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions

    Frontiers in Chemistry · 2023-03-10

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  45. Order-disorder transition and thermal behavior of paracelsian-type MGa2Ge2O8 (M = Sr, Ba) compounds

    Journal of Solid State Chemistry · 2023-10-31

    Liudmila A. Gorelova, Valentina A. Yukhno, Maria Georgievna Krzhizhanovskaya, Олег Сергеевич Верещагин

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  46. Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

    Inorganic Chemistry · 2024-05-08

    Yucheng Hao, Jian Qiu Deng, Chang-Lin Chen, Yuan Hua Lin, Haijian Li, Guangchao Qin, Kunhong Hu

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  47. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

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    Lingli Wu, Chensheng Lin, Haotian Tian, Yan Xin Tao, Bingxuan Li, Huixin Fan, Yujie Fan, Shunda Yang, Min Luo

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  48. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

    Angewandte Chemie · 2025-03-17

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  49. Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate

    Inorganic Chemistry · 2025-12-09

    Yucheng Hao, Jingli Xu, Thomas E. Albrecht‐Schmitt, Shuao Wang, Rüdiger‐A. Eichel, Evgeny V. Alekseev

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  50. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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