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RESEARCH PAPER · Inorganic Chemistry · 2017

Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures

Yucheng Hao, Gabriel L. Murphy, Dirk Bosbach, Giuseppe Modolo, Thomas E. Albrecht‐Schmitt, Evgeny V. Alekseev

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Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework StructuresOriginalDivergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions19Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Synthesis and Study of the First Zeolitic Uranium Borate22Synthetic Strategies for the Synthesis of Ternary Uranium(IV) and Thorium(IV) Fluorides24Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4–x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature18Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)25Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy179High-Pressure Synthesis, Structural, and Spectroscopic Studies of the Ni–U–O System15Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation27A novel family of microporous uranyl germanates: Framework topology and complexity of the crystal structures15Controlling Oxygen Defect Formation and Its Effect on Reversible Symmetry Lowering and Disorder-to-Order Phase Transformations in Nonstoichiometric Ternary Uranium Oxides17Mg3Pt(BO3)2O2: The first platinum borate from the flux technique13Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses16Uranyl oxide hydrate frameworks with lanthanide ions25Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions13Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)13Insights into the Structural Chemistry of Anhydrous and Hydrous Hexavalent Uranium and Neptunium Dinitrato, Trinitrato, and Tetranitrato Complexes16Unusual Heterometallic Cation‐Cation Interactions in Uranyl Zinc Germanates4Structural Variations in Complex Sodium Thorium Arsenates9Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate3The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies10Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 54A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13The crystal chemistry of plutonium( iv ) borophosphate1Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions5First Potassium Fluoroaluminate Ionic Exchanger for Rapid and Selective Removal of Sr2+ with High Capacity10Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8U(V) Stabilization via Aliovalent Incorporation of Ln(III) into Oxo‐salt Framework6Approach to Enantiomer Recognition during Adsorption by Different Adsorption Rates on Zeotype Borophosphate LiCu2[BP2O8(OH)2] with Spontaneously Emerged Chirality2Advances in the Efficient Removal of the Key Radioactive Nuclide 90Sr Using Crystalline Ion‐Exchange Materials: A Review16Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates1Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate0Ultrafast and selective removal of Sr2+ by a chain-structured aluminophosphate for nuclear waste remediation3

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  1. Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions

    Crystal Growth & Design · 2017-10-20

    Yucheng Hao, Philip Kegler, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  2. Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation

    Inorganic Chemistry · 2017-11-01

    Chao Liu, Fangyuan Chen, Hong‐Rui Tian, Jing Ai, Weiting Yang, Qing‐Jiang Pan, Zhong‐Ming Sun

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  3. Synthesis and Study of the First Zeolitic Uranium Borate

    Crystal Growth & Design · 2017-11-28

    Yucheng Hao, Vladislav V. Klepov, Philip Kegler, Giuseppe Modolo, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  4. Synthetic Strategies for the Synthesis of Ternary Uranium(IV) and Thorium(IV) Fluorides

    Inorganic Chemistry · 2018-04-10

    Vladislav V. Klepov, Justin B. Felder, Hans‐Conrad zur Loye

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  5. Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4–x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature

    Inorganic Chemistry · 2018-05-01

    Gabriel L. Murphy, Chun‐Hai Wang, George Beridze, Zhaoming Zhang, Justin A. Kimpton, Maxim Avdeev, Piotr M. Kowalski, Brendan J. Kennedy

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  6. Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)2

    Inorganic Chemistry · 2018-07-31

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

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  7. Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy

    Coordination Chemistry Reviews · 2018-07-31

    Grace Lu, Amanda J. Haes, Tori Z. Forbes

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  8. High-Pressure Synthesis, Structural, and Spectroscopic Studies of the Ni–U–O System

    Inorganic Chemistry · 2018-10-24

    Gabriel L. Murphy, Philip Kegler, Yingjie Zhang, Zhaoming Zhang, Evgeny V. Alekseev, Martin D. de Jonge, Brendan J. Kennedy

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  9. Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation

    Chinese Journal of Chemistry · 2018-12-14

    Xuemiao Yin, Yaxing Wang, Xiaoyan Li, Jian Xie, Mark A. Silver, Lanhua Chen, Daopeng Sheng, Guoxun Ji, Zhifang Chai, Shuao Wang

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  10. A novel family of microporous uranyl germanates: Framework topology and complexity of the crystal structures

    Journal of Solid State Chemistry · 2018-12-24

    Fabrice Dal Bo, Sergey M. Aksenov, Peter Carman Burns

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  11. Controlling Oxygen Defect Formation and Its Effect on Reversible Symmetry Lowering and Disorder-to-Order Phase Transformations in Nonstoichiometric Ternary Uranium Oxides

    Inorganic Chemistry · 2019-04-09

    Gabriel L. Murphy, Chun‐Hai Wang, Zhaoming Zhang, Piotr M. Kowalski, George Beridze, Maxim Avdeev, Ondrej Muránsky, Helen E. A. Brand, Qinfen Gu, Brendan J. Kennedy

    Read original paper ↗ ·

  12. Mg3Pt(BO3)2O2: The first platinum borate from the flux technique

    Journal of Solid State Chemistry · 2019-11-01

    Yucheng Hao, Linbo He, Guangjie Ge, Quan-Zheng Zhang, Ningjing Luo, Shuping Huang, Haijian Li, Evgeny V. Alekseev

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  13. Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses

    CrystEngComm · 2020-01-01

    Yucheng Hao, Yang Pan, Yuan Hua Lin, Linbo He, Guangjie Ge, Yu Ruan, Haida Zhou, Yang Xue, Kisan Koirala

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  14. Uranyl oxide hydrate frameworks with lanthanide ions

    Dalton Transactions · 2020-01-01

    Gregory R. Lumpkin, Yingjie Zhang, Robert D. Aughterson, Rongkun Zheng

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  15. Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions

    European Journal of Inorganic Chemistry · 2020-01-22

    Yucheng Hao, Philip Kegler, Thomas E. Albrecht‐Schmitt, Shuao Wang, Qiang Dong, Evgeny V. Alekseev

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  16. Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)

    Inorganic Chemistry · 2020-04-10

    Kristen A. Pace, Robert J. Koch, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Theodore M. Besmann, Scott T. Misture, Hans‐Conrad zur Loye

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  17. Insights into the Structural Chemistry of Anhydrous and Hydrous Hexavalent Uranium and Neptunium Dinitrato, Trinitrato, and Tetranitrato Complexes

    Inorganic Chemistry · 2020-05-06

    Gabriel L. Murphy, Eike M. Langer, Olaf Walter, Yaxing Wang, Shuao Wang, Evgeny V. Alekseev

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  18. Unusual Heterometallic Cation‐Cation Interactions in Uranyl Zinc Germanates

    European Journal of Inorganic Chemistry · 2020-05-06

    Huangjie Lu, Jian Hung Lin, Yaxing Wang, Zi‐Jian Li, Xiaofeng Guo, Jian‐Qiang Wang, Shuao Wang

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  19. Structural Variations in Complex Sodium Thorium Arsenates

    European Journal of Inorganic Chemistry · 2020-07-28

    Yucheng Hao, Evgeny V. Alekseev, Vladislav V. Klepov, Na Yu

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  20. Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate

    Inorganics · 2021-04-06

    Kristen A. Pace, Vladislav V. Klepov, Mark D. Smith, Travis Williams, Gregory W. Morrison, Jochen A. Lauterbach, Scott T. Misture, Hans‐Conrad zur Loye

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  21. The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures

    Crystals · 2021-08-16

    Gabriel L. Murphy, Philip Kegler, Eike M. Langer, Evgeny V. Alekseev

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  22. Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies

    Dalton Transactions · 2022-01-01

    Gabriel L. Murphy, Philip Kegler, Evgeny V. Alekseev

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  23. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  24. Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 5

    Dalton Transactions · 2022-01-01

    Yucheng Hao, Gabriel L. Murphy, Philip Kegler, Yan Li, Piotr M. Kowalski, Simon Blouin, Yang Zhang, Shuao Wang, Lars Robben, Thorsten M. Gesing, Evgeny V. Alekseev

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  25. A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures

    CrystEngComm · 2023-01-01

    Yucheng Hao, Yang Zhang, Yuying Zhang, Zixiang Fu, Chunyang Heng, Junjie Li, Jiatian You, Kunhong Hu, Yuan Hua Lin, Haijian Li

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  26. The crystal chemistry of plutonium( iv ) borophosphate

    Dalton Transactions · 2023-01-01

    Ginger E. Sigmon, Nicole A. DiBlasi, Amy E. Hixon

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  27. Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions

    Frontiers in Chemistry · 2023-03-10

    Yucheng Hao, Eike M. Langer, Bin Xiao, Philip Kegler, Xin Cao, Kunhong Hu, Rüdiger‐A. Eichel, Shuao Wang, Evgeny V. Alekseev

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  28. First Potassium Fluoroaluminate Ionic Exchanger for Rapid and Selective Removal of Sr2+ with High Capacity

    Chemistry - A European Journal · 2024-03-04

    Yucheng Hao, Yongjian Chen, Xin Cao, Chang-Lin Chen, Min Hua Xu, Yuan Hua Lin, Haijian Li, Kunhong Hu

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  29. Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

    Inorganic Chemistry · 2024-05-08

    Yucheng Hao, Jian Qiu Deng, Chang-Lin Chen, Yuan Hua Lin, Haijian Li, Guangchao Qin, Kunhong Hu

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  30. U(V) Stabilization via Aliovalent Incorporation of Ln(III) into Oxo‐salt Framework

    Chemistry - A European Journal · 2024-05-22

    Yi Yu, Yucheng Hao, Bin Xiao, Eike M. Langer, Sergei A. Novikov, Harry Ramanantoanina, Ivan N. Pidchenko, Dieter Schild, Thomas E. Albrecht‐Schoenzart, Rüdiger‐A. Eichel, Tonya Vitova, Evgeny V. Alekseev

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  31. Approach to Enantiomer Recognition during Adsorption by Different Adsorption Rates on Zeotype Borophosphate LiCu2[BP2O8(OH)2] with Spontaneously Emerged Chirality

    Langmuir · 2025-02-02

    Zhanna Dmitrievna Uteeva, Elina R. Mansurova, Yuliya F. Sharafutdinova, Diana O. Bagdanova, Marat Radikovich Agliullin, Timur Anvarovich Mukhametzyanov, V. Yu. Gus’kov

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  32. Advances in the Efficient Removal of the Key Radioactive Nuclide 90Sr Using Crystalline Ion‐Exchange Materials: A Review

    Chemistry - An Asian Journal · 2025-02-13

    Yucheng Hao, Cheng Hou, Chang-Lin Chen, Hao Zhou, Yinan Liu, Yuan Hua Lin, Haijian Li, Kunhong Hu

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  33. Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University

    Crystallography Reports · 2025-04-01

    Vladislav V. Gurzhiy, Еvgeny V. Nazarchuk, Yana G. Tagirova, Sergey V. Krivovichev

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  34. Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates

    Journal of Solid State Chemistry · 2025-08-19

    Yang Pan, Jian Qiu Deng, Yucheng Hao, Xi Zhao, Yuanyuan Bao, Zixuan Fang, Chonghai Deng, Kunhong Hu, Wei Cheng, Yuan Hua Lin

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  35. Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate

    Inorganic Chemistry · 2025-12-09

    Yucheng Hao, Jingli Xu, Thomas E. Albrecht‐Schmitt, Shuao Wang, Rüdiger‐A. Eichel, Evgeny V. Alekseev

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  36. Ultrafast and selective removal of Sr2+ by a chain-structured aluminophosphate for nuclear waste remediation

    Desalination · 2026-03-03

    Yucheng Hao, Cheng Hou, Changlin Chen, M. H. CAO, Xicheng Zhang, Xinnan Li, Guangyu Zhang, Fengshan Yu, Hongping Bian

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