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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2021

M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

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M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric StructuresOriginalA new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices8Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate0The First High‐Pressure Chromium Oxonitridoborate CrB 4 O 6 N—an Unexpected Link to Nitridosilicate Chemistry13Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide15High-pressure synthesis of borate-nitrates: crystal structure of M 3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)0An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9From Layered Borate to Porous-Layered Aluminoborate7Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Non-centrosymmetric ZnSO4·Zn(OH)2: synthesis, crystal structure, and its applications towards photocatalytic methylene blue degradation and solvent-free Knoevenagel condensation reaction1F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance0Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals2The First Silver Lead Borate, AgPb[B5O9]0Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance0Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties0

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  1. A new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices

    Dalton Transactions · 2021-01-01

    Zilong Chen, Chengfa Wu, Hao Zeng, Feng Yu

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  2. Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

    Angewandte Chemie · 2021-08-12

    Birgit Fuchs, Dirk Johrendt, Lkhamsuren Bayarjargal, Hubert Huppertz

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  3. The First High‐Pressure Chromium Oxonitridoborate CrB 4 O 6 N—an Unexpected Link to Nitridosilicate Chemistry

    Angewandte Chemie International Edition · 2021-08-12

    Birgit Fuchs, Dirk Johrendt, Lkhamsuren Bayarjargal, Hubert Huppertz

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  4. Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

    Dalton Transactions · 2021-12-20

    Huaiyu Hu, Junben Huang, Zhiyong Guo, Min Zhang, Zhihua Yang, Shilie Pan

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  5. Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence

    Dalton Transactions · 2022-01-01

    Shuo Bai, Daqing Yang, Bingbing Zhang, Ling Li, Ying Wang

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  6. Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide

    CrystEngComm · 2022-01-01

    Sergey N. Volkov, Dmitri O. Charkin, M. Yu. Arsent’ev, Sergey M. Aksenov, Lev S. Manelis, Maria Georgievna Krzhizhanovskaya, O. Yu. Sinel’shchikova, В. Л. Уголков, Alexey V. Povolotskiy, Vladimir Vladimirovich Shilovskikh, Andrey A. Antonov, Р. С. Бубнова

    Read original paper ↗ ·
  7. High-pressure synthesis of borate-nitrates: crystal structure of M 3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)

    Zeitschrift für Naturforschung B · 2022-08-27

    Leonard C. Pasqualini, Hubert Huppertz

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  8. An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles

    Journal of Materials Chemistry C · 2023-01-01

    Zhaowei Hu, Lili Liu, Ruixin Zhang, Qun Jing, Huan Wang, Jindan Tian, Jiayue Xu, P. Shiv Halasyamani

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  9. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

    Dalton Transactions · 2023-01-01

    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  10. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

    Solid State Sciences · 2023-10-04

    Sergey N. Volkov, Dmitri O. Charkin, Vadim E. Kireev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Nikita Sergeyevich Tsvetov, Yulia A. Vaitieva, Sergey M. Aksenov, Р. С. Бубнова

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  11. From Layered Borate to Porous-Layered Aluminoborate

    Crystal Growth & Design · 2023-10-04

    Xuyan Li, Chong‐An Chen, Guo‐Yu Yang

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  12. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

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  13. NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission

    Crystal Research and Technology · 2024-07-19

    Luyong Zhang, Shibin Wang, Zhencheng Wu, Xueling Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  14. Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices

    New Journal of Chemistry · 2024-11-20

    Changyou Liu, Xu Liu, Qiuyuan Feng, Ketian Hou, Bei Zhang, Juanjuan Lu

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  15. Non-centrosymmetric ZnSO4·Zn(OH)2: synthesis, crystal structure, and its applications towards photocatalytic methylene blue degradation and solvent-free Knoevenagel condensation reaction

    Inorganic Chemistry Communications · 2025-08-08

    Sangita Das, S. Ali

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  16. F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance

    Materials Today Chemistry · 2026-05-06

    Dahong Peng, Hongkang Su, Ziting Yan, chenxu li, Shilie Pan, Min Zhang

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  17. Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals

    Advanced Science · 2026-05-11

    Lingli Wu, Chensheng Lin, Bo Li, Huixin Fan, Lingfei Lv, Shunda Yang, Tao Yan, Min Luo

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  18. The First Silver Lead Borate, AgPb[B5O9]

    Journal of Chemical Crystallography · 2026-07-30

    V. E. Kireev, D. O. Charkin, Yu.O. Kopylova, A. N. Gosteva, M. Yu. Arsent’ev, Kompanchenko A.A., M.G. Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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  19. Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance

    Journal of the American Chemical Society · 2026-09-11

    Wenbin Zhang, Ruonan Zhang, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  20. Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties

    Science China Chemistry · 2026-09-22

    Juan Chen, Guo-Yu Yang

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