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RESEARCH PAPER · Inorganic Chemistry · 2014

KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

Chao Zhang Huang, Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 GroupsOriginalChemInform Abstract: KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups.0(3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 513A high-performance “sweeper” for toxic cationic herbicides: an anionic metal–organic framework with a tetrapodal cage86A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups25LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges17Recherche exploratoire de nouveaux matériaux d'électrolyte pour piles à combustible et électrolyseurs à oxyde solide (SOFC et SOEC)0Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78Synthesis, Structure and Characterization of Two Borates Templated by Organic Super Base5Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Formation Mechanism of a Polyanonic Framework from Layer to Chain Explored by Adjusting Time, Temperature, and pH: Preparation and Characterization of Metal-Complex-Templated 1D Borate and 2D Nickel Borate13Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin255Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin33Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21Two novel centrosymmetric barium strontium borates with a deep-UV cut-off edge: Ba2Sr3B4O11 and Ba3Sr3B4O1213RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design51An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses224An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses42Borates: A Rich Source for Optical Materials1089An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters26Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units21BaYOBO3: A deep-ultraviolet rare-earth oxy-borate with a large second harmonic generation response45Inducing large birefringence by enhancing asymmetric electron distribution of Y–O polyhedra21Three Co-based tartratoborates with fundamental building blocks [B(C4H2O6)2]5− from facile condensation reactions2Tailoring Hybrid Aluminoborate Frameworks by Incorporating Multicomponent Cadmium–Amine Complexes with Various Conformations8Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response50Lone-pair, electron-dominated, nonlinear optical responses in sulfur clusters and electric tunability properties11Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family23SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 38A novel red emitting phosphor KSrY 1-x (BO 3 ) 2 : xRE (RE=Sm 3+ , Eu 3+ ) for white light emitting diode: synthesis and optical properties0

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  1. ChemInform Abstract: KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups.

    ChemInform · 2014-06-02

    Chao Huang, Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  2. (3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 5

    Dalton Transactions · 2015-01-01

    Dan Zhao, Ronghua Zhang, Feifei Li, Juan Yang, Bingguo Liu, Yun-Chang Fan

    Read original paper ↗ ·

  3. A high-performance “sweeper” for toxic cationic herbicides: an anionic metal–organic framework with a tetrapodal cage

    Chemical Communications · 2015-01-01

    Yanyuan Jia, Ying‐Hui Zhang, Jian Feng Xu, Rui Yun Feng, Mingshi Zhang, Xian‐He Bu

    Read original paper ↗ ·

  4. A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups

    CrystEngComm · 2016-01-01

    Dong Yan, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures

    Inorganic Chemistry · 2016-09-30

    Dong Yan, Fei‐Fei Mao, Jiang‐Gao Mao

    Read original paper ↗ ·

  6. ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

    Dalton Transactions · 2017-01-01

    Ruru Ma, Dongdong Xu, Yun Mo Yang, Xin Su, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  7. Recherche exploratoire de nouveaux matériaux d'électrolyte pour piles à combustible et électrolyseurs à oxyde solide (SOFC et SOEC)

    Unknown journal · 2017-12-08

    Jean‐Marie Doux

    Read original paper ↗ ·

  8. Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties

    Dalton Transactions · 2018-01-01

    Fangfang He, Lei Wang, Cuifang Hu, Jing Wen Zhou, Qian Li, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

    Read original paper ↗ ·

  9. Synthesis, Structure and Characterization of Two Borates Templated by Organic Super Base

    Journal of Cluster Science · 2018-02-01

    Jun-Xia Deng, Chun‐Yang Pan, Yuan Liu, Jun Li, Fenghua Zhao

    Read original paper ↗ ·

  10. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

    Fangfang He, Qian Wang, Cuifang Hu, Wen Jun He, Xueying Luo, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

    Read original paper ↗ ·

  11. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

    Inorganic Chemistry Frontiers · 2019-01-01

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Yan Chen, Jiang‐Gao Mao

    Read original paper ↗ ·

  12. Formation Mechanism of a Polyanonic Framework from Layer to Chain Explored by Adjusting Time, Temperature, and pH: Preparation and Characterization of Metal-Complex-Templated 1D Borate and 2D Nickel Borate

    Inorganic Chemistry · 2019-01-18

    Jun-Xia Deng, Zhi‐Qiang Liu, Chun‐Yang Pan, Yuan Liu, Jun Li, Fenghua Zhao, Ling Lin

    Read original paper ↗ ·

  13. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

    Read original paper ↗ ·

  14. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

    Angewandte Chemie International Edition · 2019-09-17

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  15. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

    Angewandte Chemie · 2019-09-17

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  16. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  17. Two novel centrosymmetric barium strontium borates with a deep-UV cut-off edge: Ba2Sr3B4O11 and Ba3Sr3B4O12

    Journal of Solid State Chemistry · 2019-11-05

    Sergey N. Volkov, Р. С. Бубнова, Alexey V. Povolotskiy, В. Л. Уголков, M. Yu. Arsent’ev

    Read original paper ↗ ·

  18. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  19. Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design

    Dalton Transactions · 2020-01-01

    Fangfang He, Yuwei Ge, Xiaoyu Zhao, Jing He, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

    Read original paper ↗ ·

  20. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie International Edition · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

    Read original paper ↗ ·

  21. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

    Read original paper ↗ ·

  22. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

    Read original paper ↗ ·

  23. An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters

    Inorganic Chemistry Frontiers · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  24. Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units

    Chemical Communications · 2021-01-01

    Jiazheng Zhou, Yu Chu, Junjie Li, Shilie Pan

    Read original paper ↗ ·

  25. BaYOBO3: A deep-ultraviolet rare-earth oxy-borate with a large second harmonic generation response

    Science China Chemistry · 2021-06-18

    Mengen Gao, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  26. Inducing large birefringence by enhancing asymmetric electron distribution of Y–O polyhedra

    Inorganic Chemistry Frontiers · 2022-01-01

    Mengen Gao, Qiang Bian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  27. Three Co-based tartratoborates with fundamental building blocks [B(C4H2O6)2]5− from facile condensation reactions

    Journal of Solid State Chemistry · 2022-06-05

    Dong Yan, Yao Ma, Fei‐Fei Mao, Liang Hu, Jie Zheng, Xiu‐Du Zhang, Wen‐Tong Chen, Shu‐Fang Li

    Read original paper ↗ ·

  28. Tailoring Hybrid Aluminoborate Frameworks by Incorporating Multicomponent Cadmium–Amine Complexes with Various Conformations

    Inorganic Chemistry · 2022-07-18

    Lin Cheng, Xiao-Yun Xiong, Yi‐Ming Zhao, Ying Wang, Qiu-Ying Wu, Kai‐Yao Wang

    Read original paper ↗ ·

  29. Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response

    Chemistry of Materials · 2022-08-22

    Binqian Yuan, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  30. Lone-pair, electron-dominated, nonlinear optical responses in sulfur clusters and electric tunability properties

    Physical Chemistry Chemical Physics · 2023-01-01

    Quanjie Zhong

    Read original paper ↗ ·

  31. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

    Read original paper ↗ ·

  32. New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

    Chemical Communications · 2024-01-01

    Chenhui Hu, Mengfan Wu, Jian Wei Han, Zhihua Yang, Shujuan Han, Shilie Pan

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  33. Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

    Advanced Functional Materials · 2024-10-10

    Fanlu Bu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  34. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

    Small · 2024-10-27

    Mengya Ji, Yilin Li, Chun‐Li Hu, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  35. Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 3

    Inorganic Chemistry · 2025-10-20

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu

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  36. A novel red emitting phosphor KSrY 1-x (BO 3 ) 2 : xRE (RE=Sm 3+ , Eu 3+ ) for white light emitting diode: synthesis and optical properties

    Canadian Metallurgical Quarterly · 2026-08-27

    Rupesh N Patil, J.T. Ingle

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