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RESEARCH PAPER · Journal of the American Chemical Society · 2010

Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals

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Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical CrystalsOriginalBiosynthesis and biological activity of enniatins49ChemInform Abstract: Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A: K, Rb) as UV Nonlinear Optical Crystals.0A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials132K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H3210New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O20Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal318A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group369NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group67Novel Trumpet-Shaped Conjugation Bridge (Carbon Nanocone) for Nonlinear Optical Materials31Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57Synthesis, structural characterization and optical properties of a new cesium aluminum borate, Cs2Al2B2O725Alkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials525Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)199A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65K6Li3Sc2B15O30: A new nonlinear optical crystal with a short absorption edge50Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structure Design and Crystal Growth of UV Nonlinear Borate Materials14Crystal structures and second-order NLO properties of borogermanates59UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O1014Synthesis, crystal structure and characterization of a new compound, Li3NaBaB6O1226Exploratory Investigation of New SHG Materials Based on Galloborates46Structure and optical properties of a noncentrosymmetric borate RbSr4(BO3)333Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer29A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl11Growth, optical and electrical properties of a nonlinear optical crystal NaBa4Al2B8O18Cl315LaBeB3O7: a new phase-matchable nonlinear optical crystal exclusively containing the tetrahedral XO4 (X = B and Be) anionic groups30New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)29Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42Growth, crystal structure and optical properties of a new layered fluorine beryllium borate, Sr0.23Ca0.77Na2Be2B2O6F25Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)313Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M=Mn, Fe, Zn)12Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response597Two novel nonlinear optical carbonates in the deep-ultraviolet region: KBeCO3F and RbAlCO3F284Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O105Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units8Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer38Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block22Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)27Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal139Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br19Synthesis and Structure of KPbBP 2 O 8 – A Congruent Melting Borophosphate with Nonlinear Optical Properties35Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O14Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92Sr8MgB18O36: a New Alkaline-Earth Borate with a Novel Zero-Dimensional (B18O36)18– Anion Ring49Na8Lu2(CO3)6F2 and Na3Lu(CO3)2F2: Rare Earth Fluoride Carbonates as Deep-UV Nonlinear Optical Materials139Preparation, Structure, and Second‐order Nonlinear Optical Properties of a Borate‐Carboxylic Acid Compound: NH4B[ d‐ (+)‐C4H4O5]2·H2O3New alkali-metal bidentate borate–malate NaB(DL-C4H4O5)2 and CsB(DL-C4H4O5)2⋅H2O: Effect of cations on the framework structures and macroscopic centricities10Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain28Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains20SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures50Prospects for Fluoride Carbonate Nonlinear Optical Crystals in the UV and Deep-UV Regions116Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33249Synthesis, structure, and characterization of a new rubidium cadmium borate: RbCdB3O68CsPbCO3F: A Strong Second-Harmonic Generation Material Derived from Enhancement via p−π Interaction272Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Probe the accumulation modes of the Au–C22H14dimer on the structure and NLO properties4Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)459New type of complex alkali and alkaline earth metal borates with isolated (B12O24)12− anionic group35A new alkaline beryllium borate KBe 4 B 3 O 9 with ribbon alveolate [Be 2 BO 5 ] ∞ layers and the structural evolution of ABe 4 B 3 O 9 (A = K, Rb and Cs)12Area negative thermal expansion in a beryllium borate LiBeBO 3 with edge sharing tetrahedra43Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions11Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency100K 3 MoPO 7 : the first molybdenum phosphate with edge-sharing MoO 6 octahedra and PO 4 tetrahedra10Sodium–rare earth carbonates with shorite structure and large second harmonic generation response44Synthesis and characterization of Cd 4 YbO(BO 3 ) 3 – a congruent melting cadmium–ytterbium oxyborate with large nonlinear optical properties11β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters26Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361SrBeB2O5: Growth, crystal structure and optical properties13Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials50Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO363A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121A New Cesium Pentaborate with New B10O19 Building Blocks13Three New Alkaline Beryllium Borates LiBeBO3, Li6Be3B4O12, and Li8Be5B6O18 in the Ternary Phase Diagrams Li2O–BeO–B2O314Analysis of Deep‐UV Nonlinear Optical Borates: Approaching the End213A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes69Synthesis, Structural Characterization and Properties of Two Strontium Borates Constructed from Oxo Boron Clusters4KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36Beryllium mineral evolution67Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems32First-principles materials applications and design of nonlinear optical crystals259Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications462Deep-Ultraviolet Transparent Phosphates RbBa 2 (PO 3 ) 5 and Rb 2 Ba 3 (P 2 O 7 ) 2 Show Nonlinear Optical Activity from Condensation of [PO 4 ] 3– Units354PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 217Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials65Syntheses, characterization and nonlinear optical properties of sodium–scandium carbonate Na 5 Sc(CO 3 ) 4 ·2H 2 O9Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups20Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Development of nonlinear optical materials promoted by density functional theory simulations32Lanthanum Lead Oxide Hydroxide Nitrates with a Nonlinear Optical Effect30Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures39Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Synthesis, crystal structure and properties of a new barium calcium borate, Ba2Ca2(B2O5)25Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 541(3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 513A facile strategy to adjust the density of planar triangle units in lead borate–nitrates16ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Sr 2 (OH) 3 NO 3 : the first nitrate as a deep UV nonlinear optical material with large SHG responses166Simulated pressure-induced blue-shift of phase-matching region and nonlinear optical mechanism for K3B6O10X (X = Cl, Br)167Recent advances on second-order NLO materials based on metal iodates328Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal270Alkali-metal/alkaline-earth-metal fluorine beryllium borate NaSr3Be3B3O9F4 with large nonlinear optical properties in the deep-ultraviolet region32Two New Mixed Metal Borates Made of Mg(B6O7(OH)6)2 and B8O14(OH)4 Cluster Units3Two Borate Supramolecular Frameworks Based on B4O5(OH)4 Cluster Units2Pb17O8Cl18: A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System223Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications131Synthesis, crystal structures and properties of lead phosphite compounds27Disorder, pseudo symmetry and photoluminescence properties of a new diphosphate K2Ba3(P2O7)23Design and Synthesis of the Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4300Structural Modulation of Anionic Group Architectures by Cations to Optimize SHG Effects: A Facile Route to New NLO Materials in the ATCO3F (A = K, Rb; T = Zn, Cd) Series114K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42First-Principles Design of a Deep-Ultraviolet Nonlinear-Optical Crystal from KBe2BO3F2 to NH4Be2BO3F2106Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure54Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340“XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)19Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 474Hierarchized band gap and enhanced optical responses of trivalent rare-earth metal nitrates due to (d–p)π conjugation interactions22KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers10New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7

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  1. Biosynthesis and biological activity of enniatins

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    S Firáková, Bohumil Proksa, M. Šturdíková

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  2. ChemInform Abstract: Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A: K, Rb) as UV Nonlinear Optical Crystals.

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  3. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

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  4. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

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  5. New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study

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  6. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

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  7. Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials

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  9. Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32

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  10. New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O

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  11. Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal

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  12. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

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  13. NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group

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  15. Novel Trumpet-Shaped Conjugation Bridge (Carbon Nanocone) for Nonlinear Optical Materials

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  16. Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl

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  17. Synthesis, structural characterization and optical properties of a new cesium aluminum borate, Cs2Al2B2O7

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  19. Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)

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  20. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

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  22. Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses

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  24. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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  33. Structure and optical properties of a noncentrosymmetric borate RbSr4(BO3)3

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  34. Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units

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  35. M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer

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  36. A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl

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  43. Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)3

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  45. Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response

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  46. Two novel nonlinear optical carbonates in the deep-ultraviolet region: KBeCO3F and RbAlCO3F2

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  47. Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O10

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  48. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

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  49. Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units

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  50. Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer

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