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RESEARCH PAPER · Angewandte Chemie International Edition · 2008

Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties

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Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange PropertiesOriginalChemInform Abstract: Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties.0Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster48Three-Dimensional Lanthanide Anionic Metal−Organic Frameworks with Tunable Luminescent Properties Induced by Cation Exchange264Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O37From One-Dimensional Ribbon to Three-Dimensional Microporous Framework: The Syntheses, Crystal Structures, and Properties of a Series of Mercury Antimony Chalcogenides30(H2en)2Cu8Sn3S12: a trigonal CuS3-based open-framework sulfide with interesting ion-exchange properties77A three-dimensional semiconducting superlattice built up of neutral [Zn10(μ3-S)4(SPhMe-4)12(DMF)4] supertetrahedral clusters12Two new layered bimetallic sulfides: Solvothermal synthesis, crystal structure, optical and magnetic properties25Indium−Sulfur Supertetrahedral Clusters Integrated with a Metal Complex of 1,10-Phenanthroline44A Series of Novel Organically Templated Germanium Antimony Sulfides42Copper-Rich Framework Sulfides: A4Cu8Ge3S12 (A = K, Rb) with Cubic Perovskite Structure55Solvent-Mediated Central Metals Transformation from a Tetranuclear NiII Cage to a Decanuclear CuII “Pocket”38A two-dimensional layered cadmium sulfide superlattice constructed from capped-supertetrahedral C1 clusters10Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation132Two Novel Thioindate-Thioantimonate Compounds [Ni(dien)2]2In2Sb4S11 and [Ni(dien)2]3(In3Sb2S9)2·2H2O with Transition Metal Complexes40[M(dap)3]InSb3S7 (M = Co, Ni): Two Novel Open-Framework Thioindate−Thioantimonates with 8-, 12-, and 16-Ring Intersecting Channels41[(Me)2NH2]0.75[Ag1.25SnSe3]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange70A novel 3-D thioindate-thioantimonate based on the linkages of large heterometallic {In2Sb2S9} clusters and 1-D [In2Sb2S84−]n chains23Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes33Ionothermal Syntheses and Characterizations of New Open-Framework Metal Borophosphates25A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties43Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline)m]2+ (m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components50Synthesis, structure of 3D lanthanide (La(III), Pr(III)) nanoporous coordination polymers containing 1D channels as selective luminescent probes of Pb2+, Ca2+ and Cd2+ ions21Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states20Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties51Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator47Synthesis and characterization of (H2dab)2Cu8Ge4S14·2H2O: An expanded framework based on icosahedral Cu8S12 cluster24Assembly of novel organic-decorated quaternary TM–Hg–Sb–Q compounds (TM = Mn, Fe, Co; Q = S, Se) by the combination of three types of metal coordination geometries72One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties37Ion-Exchange Characteristics of a Layered Metal Sulfide for Removal of Sr2+from Aqueous Solutions16[Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes37Copper‐Rich Framework Selenoarsenates Based on Icosahedral Cu8Se13 Clusters14[Ni(dien)2]3[Ge3Sb8S21]·0.5H2O: A new 2-D layered thiogermanate–thioantimonate with metal complexes as template ions16[NH 3 CH 3 ] 4 [In 4 SbS 9 SH]: a novel methylamine-directed indium thioantimonate with Rb + ion-exchange property59A Series of 3D Lanthanide Complexes Containing (La(III), Sm(III) and Gd(III)) Metal-organic Frameworks: Synthesis, Structure, Characterization and Their Luminescent Properties3[AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye29Advances in Inorganic and Hybrid Ion Exchangers40Ba2Sb4GeS1012Changes in the Structural Dimensionality of Selenidostannates in Ionic Liquids: Formation, Structures, Stability, and Photoconductivity50Synthesis, structure and luminescent recognition properties of cerium(IV) coordination polymers based on pyridine-2,6-dicarboxylic acid19Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH]4[M3Sn4Se11(Se2)2] (M = Cd, Hg)14Synthesis, crystal structure and properties of [(dien)2Mn]Ge2S4 with mixed-valent Ge centers12Surfactant–Thermal Method to Synthesize a Novel Two‐Dimensional Oxochalcogenide79Mild Solvothermal Syntheses of Thioargentates A–Ag–S (A = K, Rb, Cs) and A–Ag–Ge–S (A = Na, Rb): Crucial Role of Excess Sulfur32[TM(en)3][SnSb4S9] (TM = Ni, Co): 3D Chiral Framework of Mixed Main-Group Metals and [Mn(dien)2]2Sb4S9: 1D Chains with Mixed-Valent Sb Centers54[(Me)2NH2][BiGeS4]: the first organically directed bismuth thiogermanate with Rb+ ion exchange property16New strategies to prepare crystalline chalcogenides165Novel thioarsenates {[Mn(2,2′-bipy) 2 (SCN)][Mn(2,2′-bipy)](As V S 4 )} 2 and {[Mn(2,2′-bipy) 2 (SCN)] 2 [As III 2 (S 2 ) 2 S 2 ]}: introducing an anionic second ligand to modify Mn II complex cations of 2,2′-bipyridine20Two manganese–amine complexes incorporating thioantimonates and exhibiting diversiform roles of amine ligands20Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes69Hydrothermal syntheses and characterization of two tetramethylammonium templated indium sulfides2Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks5Syntheses, crystal and band structures, and optical properties of a selenidoantimonate and an iron polyselenide7{[M(NH3)6][Ag4M4Sn3Se13]}∞ (M=Zn, Mn): Three-dimensional chalcogenide frameworks constructed from quaternary metal selenide clusters with two different transition metals23Achieve to easier opening of channels in anionic nanoporous metal–organic framework by cation exchange process23Solvothermal syntheses of lanthanide thiogermanates displaying three new structural moieties17Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications32Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides45Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M–S bonding for MS 4 2− (M = Cr, Mo, W) dianions18Threading Chalcogenide Layers with Polymer Chains209Threading Chalcogenide Layers with Polymer Chains31New Members of the Family of In–Sb–S Compounds: Different Roles of Organic Amines20A two-dimensionally microporous thiostannate with superior Cs + and Sr 2+ ion-exchange property177Chiral nematic porous germania and germanium/carbon films30Open-framework beryllium phosphates with a zeolitic CrB 4 topology and their structural analogues containing 12-ring channels13Varied forms of lamellar [Sn 3 Se 7 ] n 2n− anion: the competitive and synergistic structure-directing effects of metal–amine complex and imidazolium cations37Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu8Sn6S24]z− Clusters34Supercubooctahedron (Cs6Cl)2Cs5[Ga15Ge9Se48] Exhibiting Both Cation and Anion Exchange13Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials315Tenside als Reaktionsmedien zur Synthese von kristallinen anorganischen Materialien14Syntheses, Crystal Structures, Ion-Exchange, and Photocatalytic Properties of Two Amine-Directed Ge–Sb–S Compounds55Hydrazine-Hydrothermal Synthesis and Characterization of the Two New Quaternary Thioantimonates(III) BaAgSbS3 and BaAgSbS3·H2O40Preparation of Porous Three‐Dimensional Quaternary Thioantimonates(III) ACuSb2S4 (A=Rb, Cs) through a Surfactant‐Thermal Method29Facile surfactant-thermal syntheses and characterization of quaternary copper thioantimonates(III) ACu 2 SbS 3 (A = K, Rb, Cs)23Synthese kristalliner Chalkogenide in ionischen Flüssigkeiten43Synthesis of Crystalline Chalcogenides in Ionic Liquids150Efficient and selective heavy metal sequestration from water by using layered sulfide K 2x Sn 4−x S 8−x (x = 0.65–1; KTS-3)82Lanthanide complexes with pyridine-2,6-dicarboxylic acid: synthesis, crystal structure, thermal and magnetic properties of [LnPDA)2(PDAH2)] · (DMAH2)2(DMAH0.5)24Large Metal Chalcogenide Clusters and Their Ordered Superstructures via Solvothermal and Ionothermal Syntheses8Metal sulfide ion exchangers: superior sorbents for the capture of toxic and nuclear waste-related metal ions334Combination of Metal Coordination Tetrahedra and Asymmetric Coordination Geometries of Sb(III) in the Organically Directed Chalcogenidometalates: Structural Diversity and Ion-exchange Properties25Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements94Ionothermal synthesis and electrochemical properties of a selenidostannate containing the mixed cations of Na+ and enH+4Open-Framework Oxysulfide Based on the Supertetrahedral [In4Sn16O10S34]12– Cluster and Efficient Sequestration of Heavy Metals107Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg4As2S6⋅2 H2O and One‐Dimensional BaAgAsS320Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)68Synthesis, Structure, Band Gap, and Near-Infrared Photosensitivity of a New Chalcogenide Crystal, (NH4)4Ag12Sn7Se2215Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method13Efficient Removal and Recovery of Uranium by a Layered Organic–Inorganic Hybrid Thiostannate397Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine59Syntheses, structures, and properties of sulfides constructed by SbS 4 teeter-totter polyhedra: Ba 3 La 4 Ga 2 Sb 2 S 15 and BaLa 3 GaSb 2 S 1013Synthesis of a Ternary Thiostannate with 3D Channel Decorated by Hydronium for High Proton Conductivity17Multitopic ligand directed assembly of low-dimensional metal-chalcogenide organic frameworks5A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior8Post-synthetic ion-exchange process in nanoporous metal–organic frameworks; an effective way for modulating their structures and properties170Syntheses, Crystal Structures, and Optical and Photocatalytic Properties of Four Small-Amine-Molecule-Directed M–Sn–Q (M = Zn, Ag; Q = S, Se) Compounds49Lanthanide(III) complexes with μ-SnSe4 and μ-Sn2Se6 linkers: solvothermal syntheses and properties of new Ln(III) selenidostannates decorated with linear polyamine3Two new 3D heterometallic chalcogenides based on copper-rich selenogermanate clusters7An easily synthesized microporous framework material for the selective capture of radioactive Cs + and Sr 2+ ions119Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework8A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture10[CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property19A new 3-D cuprous thiogermanate with rare 3-D [Cu-S-Cu]n network7An MOF-like Interpenetrated 2D Plus 2D to 3D Inorganic Grid Assembled by Linear Inorganic Pillars, Structures, and Properties in Supercapacitance13Synergy between Zeolite Framework and Encapsulated Sulfur for Enhanced Ion-Exchange Selectivity to Radioactive Cesium71Efficient Removal of [UO2]2+, Cs+, and Sr2+ Ions by Radiation-Resistant Gallium Thioantimonates207Unusual Flexibility of Microporous Sulfides during Ion Exchange52A series of new vanadium( iii ) chalcogenido-antimonates: an unusual seven-coordinate nitro-selenidovanadium( iii ) complex8A stable anionic metal–organic framework with open coordinated sites: selective separation toward cationic dyes and sensing properties49Alkylammonium thiostannate inorganic/organic hybrids as high-performance photocatalysts with a decoupled adsorption–photodegradation mechanism8Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles38Fast and Selective Removal of Aqueous Uranium by a K+-Activated Robust Zeolitic Sulfide with Wide pH Resistance40Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)21Highly Selective Recovery of Lanthanides by Using a Layered Vanadate with Acid and Radiation Resistance56Highly Selective Recovery of Lanthanides by Using a Layered Vanadate with Acid and Radiation Resistance5Selective Capture of Ba2+, Ni2+, and Co2+ by a Robust Layered Metal Sulfide43Synthesis, structure, and characterization of a mixed amines thiogermanate [NH4]2[NH2(CH3)2]2Ge2S61Fabrication of hypercrosslinked hydroxyl-rich solid phase extractants for cesium separation from the salt lake brine76A review on emerging composite materials for cesium adsorption and environmental remediation on the latest decade180Novel montmorillonite-sulfur composite for enhancement of selective adsorption toward cesium32Antimony-Assisted Assembly of Basic Supertetrahedral Clusters into Heterometallic Chalcogenide Supraclusters6Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10Robust and Flexible Thioantimonate Materials for Cs+ Remediation with Distinctive Structural Transformation: A Clear Insight into the Ion-Exchange Mechanism28Layered Thiostannates with Distinct Arrangements of Mixed Cations for the Selective Capture of Cs+, Sr2+, and Eu3+ Ions63Efficient Removal of Cs+ and Sr2+ Ions by Granulous (Me2NH2)4/3(Me3NH)2/3Sn3S7·1.25H2O/Polyacrylonitrile Composite40Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Highly efficient, rapid, and concurrent removal of toxic heavy metals by the novel 2D hybrid LDH–[Sn2S6]64Novel One-Pot Solvothermal Synthesis of High-Performance Copper Hexacyanoferrate for Cs+ Removal from Wastewater21Rapid and Selective Uptake of Cs+ and Sr2+ Ions by a Layered Thiostannate with Acid–Base and Irradiation Resistances29Synthesis of Zeolitic Ti, Zr-Substituted Vanadotungstates and Investigation of Their Catalytic Activities for Low Temperature NH3-SCR18A strategy of synergistically using ether oxygen and phenolic hydroxyl groups for Ultra-High selective and fast Cs+ isolation13Mild solvothermal syntheses and characterizations of five Nb-containing quaternary sulfides6Crystalline chalcogenidometalate-based compounds from uncommon reaction media12The Aminated Covalent Organic Polymers for Reversible Removal of Concurrent Perfluorooctane Sulfonate and Dichromate1Two new metal-chalcogenide-cluster-based frameworks with single metal ions of Zn 2+ (/Sb 3+ ) serving as inter-cluster linkers4Highly Efficient Uptake of Cs + by Robust Layered Metal–Organic Frameworks with a Distinctive Ion Exchange Mechanism49Highly selective cesium(I) capture under acidic conditions by a layered sulfide145Novel layered iron antimony thiostannate adsorbent of K1.61Fe0.04Sb0.03Sn3.1S7 for cesium green recovery from geothermal water35High-capacity recovery of Cs+ ions by facilely synthesized layered vanadyl oxalatophosphates with the clear insight into remediation mechanism25Rapid and selective removal of Cs+ and Sr2+ ions by two zeolite-type sulfides via ion exchange method114The aminated covalent organic polymers for reversible removal of concurrent perfluorooctane sulfonate and dichromate27Solvothermal Synthesis and Characterization of One-Dimensional [Mn(en)3]CdSb2Se54Novel Zr-Doped Thiostannate Spinning Fiber (Fiber-KZrTS) for Highly Efficient and Renewable Recovery of Cesium and Strontium from Geothermal Water23Syntheses, crystal structure and properties of two chalcogenidoantimonates Mn(en)3Sb2S4 and Co(en)3Sb2Se48Rapid and Selective Uptake of Radioactive Cesium from Water by a Microporous Zeolitic-like Sulfide23Metal chalcogenides as ion-exchange materials for the efficient removal of key radionuclides: A review34Highly selective capture of cesium using an electrochemically renewable molybdenum-based crystalline adsorbent6An innovative method for effective rubidium recovery from wastewater using tungsten-doped microsphere magnetic tin sulfide11

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  1. ChemInform Abstract: Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties.

    ChemInform · 2008-12-18

    Mei‐Ling Feng, De‐Nian Kong, Zailai Xie, Xiao‐Ying Huang

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  2. Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster

    Inorganic Chemistry · 2009-03-30

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  3. Three-Dimensional Lanthanide Anionic Metal−Organic Frameworks with Tunable Luminescent Properties Induced by Cation Exchange

    Inorganic Chemistry · 2009-07-01

    Wen‐Guan Lu, Long Jiang, Xiao‐Long Feng, Tong‐Bu Lu

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  4. Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O

    Inorganic Chemistry · 2009-07-30

    Mei‐Ling Feng, Dong Ye, Xiao‐Ying Huang

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  5. From One-Dimensional Ribbon to Three-Dimensional Microporous Framework: The Syntheses, Crystal Structures, and Properties of a Series of Mercury Antimony Chalcogenides

    Crystal Growth & Design · 2009-12-29

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  6. (H2en)2Cu8Sn3S12: a trigonal CuS3-based open-framework sulfide with interesting ion-exchange properties

    Chemical Communications · 2010-01-01

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  7. A three-dimensional semiconducting superlattice built up of neutral [Zn10(μ3-S)4(SPhMe-4)12(DMF)4] supertetrahedral clusters

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  8. Two new layered bimetallic sulfides: Solvothermal synthesis, crystal structure, optical and magnetic properties

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  9. Indium−Sulfur Supertetrahedral Clusters Integrated with a Metal Complex of 1,10-Phenanthroline

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  10. A Series of Novel Organically Templated Germanium Antimony Sulfides

    Chemistry - An Asian Journal · 2010-06-10

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  11. Copper-Rich Framework Sulfides: A4Cu8Ge3S12 (A = K, Rb) with Cubic Perovskite Structure

    Inorganic Chemistry · 2010-06-21

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  12. Solvent-Mediated Central Metals Transformation from a Tetranuclear NiII Cage to a Decanuclear CuII “Pocket”

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  13. A two-dimensional layered cadmium sulfide superlattice constructed from capped-supertetrahedral C1 clusters

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  14. Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation

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  15. Two Novel Thioindate-Thioantimonate Compounds [Ni(dien)2]2In2Sb4S11 and [Ni(dien)2]3(In3Sb2S9)2·2H2O with Transition Metal Complexes

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  16. [M(dap)3]InSb3S7 (M = Co, Ni): Two Novel Open-Framework Thioindate−Thioantimonates with 8-, 12-, and 16-Ring Intersecting Channels

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  17. [(Me)2NH2]0.75[Ag1.25SnSe3]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange

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  18. A novel 3-D thioindate-thioantimonate based on the linkages of large heterometallic {In2Sb2S9} clusters and 1-D [In2Sb2S84−]n chains

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  19. Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes

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  20. Ionothermal Syntheses and Characterizations of New Open-Framework Metal Borophosphates

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  21. A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties

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  22. Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline)m]2+ (m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components

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  23. Synthesis, structure of 3D lanthanide (La(III), Pr(III)) nanoporous coordination polymers containing 1D channels as selective luminescent probes of Pb2+, Ca2+ and Cd2+ ions

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  24. Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states

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  25. Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties

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  26. Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator

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  27. Synthesis and characterization of (H2dab)2Cu8Ge4S14·2H2O: An expanded framework based on icosahedral Cu8S12 cluster

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  28. Assembly of novel organic-decorated quaternary TM–Hg–Sb–Q compounds (TM = Mn, Fe, Co; Q = S, Se) by the combination of three types of metal coordination geometries

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  29. One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties

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  30. Ion-Exchange Characteristics of a Layered Metal Sulfide for Removal of Sr2+from Aqueous Solutions

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  31. [Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes

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  32. Copper‐Rich Framework Selenoarsenates Based on Icosahedral Cu8Se13 Clusters

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