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RESEARCH PAPER · Optical Materials · 2008

SbF3: A new second-order nonlinear optical material

Gang Zhang, Tao Liu, Tianxiang Zhu, Jingui Qin, Yicheng Wu, Chuangtian Chen

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SbF3: A new second-order nonlinear optical materialOriginalNaSb 3 F 10 : A new second-order nonlinear optical crystal to be used in the IR region with very high laser damage threshod70NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Recent Advances in Crystal Growth in China: Laser, Nonlinear Optical, and Ferroelectric Crystals58Research progress on mid-IR nonlinear optical crystals with high laser damage threshold in China10Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials132NaGe 3 P 3 : a new ternary germanium phosphide featuring an unusual [Ge 3 P 7 ] ring22Synthesis, crystal structure and properties of a new candidate for nonlinear optical material in the IR region: Hg 2 BrI 351Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials56A promising nonlinear optical material in the Mid-IR region: new results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl36First principles selection and design of mid-IR nonlinear optical halide crystals132Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region28HgBrI: A promising nonlinear optical material in IR region18Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption33Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response104First-principles materials applications and design of nonlinear optical crystals259A study on K 2 SbF 2 Cl 3 as a new mid-IR nonlinear optical material: new synthesis and excellent properties55Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Interrelationship of the structural and nonlinear-optical properties of the carbonate crystals2Recent achievements on middle and far-infrared second-order nonlinear optical materials433Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals16Structural Evolution in BaSn2F5X (X = Cl, Br, I): A Family of Alkaline Earth Metal Tin Mixed Halides15Nonlinear Optical Crystal Rb 4 Sn 3 Cl 2 Br 8 : Synthesis, Structure, and Characterization32Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Synthesis, crystal structures and nonlinear optical properties of polymorphism: α- and β-RbHgI3·H2O18Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Recent advances and future perspectives on infrared nonlinear optical metal halides223ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Immobilized antimony species on magnetite: a novel and highly efficient magnetically reusable nanocatalyst for direct and gram-scale reductive-coupling of nitroarenes to azoarenes7Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O8ASbF3Cl (A = Rb, Cs): Structural Evolution from Centrosymmetry to Noncentrosymmetry16Synthesis, crystal structure, and properties of new compounds [NH4]4[SbF4]2[NbOF5], K4[SbF4]2[NbOF5], and [NH4]4[SbF4]2[SnF6]5Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides114α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth24α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth211KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold42Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials30Peculiarities of ionic mobility and superionic conductivity in Thallium(I) Fluoroantimonates(III). A review2The Stibium Bond or the Antimony-Centered Pnictogen Bond: The Covalently Bound Antimony Atom in Molecular Entities in Crystal Lattices as a Pnictogen Bond Donor29Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Peculiarities of ion mobility, phase transitions, and ionic conductivity in mixed-cation tetrafluoroantimonates(iii)0Quantifying Structural Polarization by Continuous Regulation of Lone-Pair Electron Expression in Molecular Crystals52Selective dry etching of silicon with heat-mode resist GeSb for the preparation of metasurfaces5Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances18Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals72Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals8Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7A strategy to achieve giant optical anisotropy via integrating linear pseudohalogen and stereochemical active lone pair cation6Design, Hydrothermal Synthesis, Crystal Structure, and Antioxidant Properties of Non‐Centrosymmetric SbF 32Elucidating the Influence of Sodium Fluoride on the Structural and Photoelectrochemical Properties of Antimony Sulfide Thin Films2Synergistic Enhancement of Birefringence in Metal Benzoxazolium Complexes by π-Conjugated [C 9 H 10 NO] + and Triangular [HgI 3 ] − Motifs3KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. NaSb 3 F 10 : A new second-order nonlinear optical crystal to be used in the IR region with very high laser damage threshod

    Applied Physics Letters · 2009-12-28

    Gang Zhang, Jingui Qin, Tao Liu, Yanjun Li, Yicheng Wu, Chuangtian Chen

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  2. NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response

    Chemistry of Materials · 2010-01-12

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chuan‐Fu Sun, Jian‐Han Zhang, Jiang‐Gao Mao

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  3. Recent Advances in Crystal Growth in China: Laser, Nonlinear Optical, and Ferroelectric Crystals

    Crystal Growth & Design · 2010-10-06

    Ning Ye, Chaoyang Tu, Xifa Long, Maochun Hong

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  4. Research progress on mid-IR nonlinear optical crystals with high laser damage threshold in China

    Frontiers of Chemistry in China · 2011-01-10

    Tianxiang Zhu, Xingguo Chen, Jingui Qin

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  5. Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials

    Journal of the American Chemical Society · 2011-02-22

    Xiao‐Ming Jiang, Ming‐Jian Zhang, Hui‐Yi Zeng, Guo‐Cong Guo, Jin‐Shun Huang

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  6. NaGe 3 P 3 : a new ternary germanium phosphide featuring an unusual [Ge 3 P 7 ] ring

    Dalton Transactions · 2011-10-31

    Kai Feng, Wenlong Yin, Ran He, Zheshuai Lin, Shifeng Jin, Jiyong Yao, Peizhen Fu, Yicheng Wu

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  7. Synthesis, crystal structure and properties of a new candidate for nonlinear optical material in the IR region: Hg 2 BrI 3

    Dalton Transactions · 2011-11-03

    Yanjun Li, Meng Wang, Tianxiang Zhu, Xiang‐Gao Meng, Cheng Zhong, Xingguo Chen, Jingui Qin

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  8. Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials

    Structure and bonding · 2012-01-01

    Xiao‐Ming Jiang, Sheng‐Ping Guo, Hui‐Yi Zeng, Ming‐Jian Zhang, Guo‐Cong Guo

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  9. A promising nonlinear optical material in the Mid-IR region: new results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl

    Dalton Transactions · 2013-01-01

    Yangyang Dang, Xiang‐Gao Meng, Kui Jiang, Cheng Zhong, Xingguo Chen, Jingui Qin

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  10. First principles selection and design of mid-IR nonlinear optical halide crystals

    Journal of Materials Chemistry C · 2013-01-01

    Lei Kang, David Muñoz Ramo, Zheshuai Lin, Paul D. Bristowe, Jingui Qin, Chuangtian Chen

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  11. Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region

    CrystEngComm · 2013-01-01

    Yin Huang, Xiang‐Gao Meng, Lei Kang, Yanjun Li, Cheng Zhong, Zheshuai Lin, Xingguo Chen, Jingui Qin

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  12. HgBrI: A promising nonlinear optical material in IR region

    Inorganic Chemistry Communications · 2013-05-04

    Qi Wu, Yanjun Li, Huaichuan Chen, Kui Jiang, Hua Li, Cheng Zhong, Xingguo Chen, Jingui Qin

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  13. Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption

    Inorganic Chemistry · 2013-07-09

    Xiao‐Ming Jiang, Guan‐E Wang, Zhi‐Fa Liu, Ming‐Jian Zhang, Guo‐Cong Guo

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  14. Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response

    Journal of Materials Chemistry C · 2014-01-01

    Kai Feng, Lei Kang, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  15. First-principles materials applications and design of nonlinear optical crystals

    Journal of Physics D Applied Physics · 2014-05-23

    Zheshuai Lin, Xingxing Jiang, Lei Kang, Pifu Gong, Siyang Luo, Ming‐Hsien Lee

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  16. A study on K 2 SbF 2 Cl 3 as a new mid-IR nonlinear optical material: new synthesis and excellent properties

    Journal of Materials Chemistry C · 2015-01-01

    Yin Huang, Xiang‐Gao Meng, Pifu Gong, Zheshuai Lin, Xingguo Chen, Jingui Qin

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  17. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

    Journal of the American Chemical Society · 2015-09-23

    Lei Kang, Molin Zhou, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  18. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  19. Interrelationship of the structural and nonlinear-optical properties of the carbonate crystals

    International Scientific-Technical Conference on Actual Problems of Electronics Instrument Engineering (APEIE) · 2016-10-01

    Boris I. Kidyarov, Макуха Владимир Карпович

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  20. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  21. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

    Pengfei Liu, Yanyan Li, Yujun Zheng, Ju‐Song Yu, Ruihuan Duan, Hong Chen, Hua Lin, Ling Chen, Li‐Ming Wu

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  22. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

    Chemistry of Materials · 2017-01-30

    Shu‐Fang Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Dong Yan, Chensheng Lin, Hui‐Yi Zeng, Guo‐Cong Guo

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  23. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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  24. Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals

    Crystals · 2017-04-12

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  25. Structural Evolution in BaSn2F5X (X = Cl, Br, I): A Family of Alkaline Earth Metal Tin Mixed Halides

    Inorganic Chemistry · 2017-10-24

    Zheshuai Lin, Pifu Gong, Yi Jin Yang, Siyang Luo, Fei Liang, Xingxing Jiang

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  26. Nonlinear Optical Crystal Rb 4 Sn 3 Cl 2 Br 8 : Synthesis, Structure, and Characterization

    Crystal Growth & Design · 2017-11-20

    Pifu Gong, Siyang Luo, Yi Jin Yang, Fei Liang, Shengzi Zhang, Sangen Zhao, Junhua Luo, Zheshuai Lin

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  27. Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy

    Dalton Transactions · 2018-01-01

    Xiaoxiao Wang, Xingxing Jiang, Hongming Liu, Lei Yang, Zheshuai Lin, Zhanggui Hu, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  28. Synthesis, crystal structures and nonlinear optical properties of polymorphism: α- and β-RbHgI3·H2O

    Journal of Alloys and Compounds · 2018-09-04

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  29. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

    Fangfang He, Qian Wang, Cuifang Hu, Wen Jun He, Xueying Luo, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  30. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  31. ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

    Chemical Communications · 2019-01-01

    Ailijiang Abudurusuli, Kui Wu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  32. Immobilized antimony species on magnetite: a novel and highly efficient magnetically reusable nanocatalyst for direct and gram-scale reductive-coupling of nitroarenes to azoarenes

    RSC Advances · 2019-01-01

    Behzad Zeynizadeh, Fariba Faraji

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  33. Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Fei Liang, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Zheshuai Lin, Yanjun Li

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  34. Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Yanjun Li

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  35. ASbF3Cl (A = Rb, Cs): Structural Evolution from Centrosymmetry to Noncentrosymmetry

    Crystal Growth & Design · 2019-01-24

    Pifu Gong, Yi Jin Yang, Fengguang You, Xinyuan Zhang, Gaomin Song, Shengzi Zhang, Qian Huang, Zheshuai Lin

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  36. Synthesis, crystal structure, and properties of new compounds [NH4]4[SbF4]2[NbOF5], K4[SbF4]2[NbOF5], and [NH4]4[SbF4]2[SnF6]

    Journal of Fluorine Chemistry · 2019-08-08

    Evgeniy B. Merkulov, E. I. Voĭt, А.В. Герасименко

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  37. Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides

    Coordination Chemistry Reviews · 2020-07-13

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  38. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

    Angewandte Chemie · 2020-11-10

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  39. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

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  40. KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold

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  41. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

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  42. Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)

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  43. Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials

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  44. Peculiarities of ionic mobility and superionic conductivity in Thallium(I) Fluoroantimonates(III). A review

    Journal of Solid State Chemistry · 2021-12-23

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  45. The Stibium Bond or the Antimony-Centered Pnictogen Bond: The Covalently Bound Antimony Atom in Molecular Entities in Crystal Lattices as a Pnictogen Bond Donor

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  46. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

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  47. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

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  48. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

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  49. Peculiarities of ion mobility, phase transitions, and ionic conductivity in mixed-cation tetrafluoroantimonates(iii)

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  50. Quantifying Structural Polarization by Continuous Regulation of Lone-Pair Electron Expression in Molecular Crystals

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